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Integrating electrocatalysis with biocatalysis for asymmetric synthesis

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01899K, Highlight
Yuqi Lin, Jiage Yu, Ke-Yin Ye
This highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.
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Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00984C, Research Article
Guolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming Ma
Chiral diphenylprolinol silyl ethers have been successfully identified for the enantioselective allenation reaction of terminal alkynes and 2-alkynals, delivering a diverse set of chiral allenynes with high efficiency.
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Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01794C, Research Article
Xiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan Yu
The mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.
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Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01810A, Research Article
Ángel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-Castells
Cyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...
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Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
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Reflection On America’s Great Loop: A Baby Boomer Couple’s Year-Long Boating Odyssey

By atlanticpub.wordpress.com
Published On :: Tue, 31 Jul 2012 19:57:08 +0000

Adventure is not just for the young! Though “I own a boat!” was the opening phrase to their courtship and eventual married life, little did Baby Boomer couple George and Pat Hospodar know then that those words would lead to their making a year-long “journey of a lifetime” aboard their boat, Reflection, almost forty years […]


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Strain-affected ferroelastic domain walls in RbMnFe charge-transfer materials undergoing collective Jahn–Teller distortion

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35081-35089
DOI: 10.1039/D4RA06397J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marius Hervé, Shintaro Akagi, Laurent Guérin, Leland B. Gee, Ryan D. Ribson, Matthieu Chollet, Marco Cammarata, Shuntaro Nagashima, Shin-ichi Ohkoshi, Hiroko Tokoro, Eric Collet
This X-ray diffraction study of RbMnFe materials reveals the ferroelastic domains walls resulting from collective Jahn–Teller distortion coupled to intermetallic charge-transfer and the spatial extension of the strain around the walls.
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Investigation of the titanium-mediated catalytic enantioselective oxidation of aryl benzyl sulfides containing heterocyclic groups

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35105-35113
DOI: 10.1039/D4RA07088G, Paper
Open Access
Maria Annunziata M. Capozzi, Angel Alvarez-Larena, Joan F. Piniella Febrer, Cosimo Cardellicchio
Enantiopure benzyl heteroaryl sulfoxides were obtained by asymmetric oxidation. However, two benzimidazolyl sulfoxides were found to be conglomerates.
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An electrochemiluminescence device for visualized detection of lead in practical samples

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35232-35238
DOI: 10.1039/D4RA05742B, Paper
Open Access
Huaanzi Hu, Cheng Wang, Chen Qian, Chengqi Li, Yulin Li, Jianbin Pan, Xinye Ni
An up-response ECL imaging system is designed for visualized Pb2+ detection with high selectivity.
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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
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Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper
Open Access
Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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Synthesis, optical, electrochemical, and computational study of benzene/thiophene based D–π–A chromophores

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35424-35437
DOI: 10.1039/D4RA02668C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michaela Babejová, Iveta Třísková, Libuše Trnková, Hugo Semrád, Markéta Munzarová, Dominik Heger, Dana Nachtigallová, Milan Potáček
Synthesis of novel (D–π–A) chromophores with one electron-donating + withdrawing group at opposite ends of terphenyl, terthiophene, or 2,5-diphenylthiophene, analysed upon results of HOMO–LUMO gaps, determined via CV and in terms of MO via DFT.
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N-doped carbon quantum dots for the selective detection of OCl− ions, bioimaging, and the production of Fe3O4 nanoparticles utilized in the synthesis of substituted imidazole

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35448-35459
DOI: 10.1039/D4RA06474G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Namrata Priyadarshini Hota, Sathiyanarayanan Kulathu Iyer
Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using o-phenylenediamine and L-tartaric acid.
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Superior low temperature activity over α-MnO2/β-MnOOH catalyst for selective catalytic reduction of NOx with ammonia

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35498-35504
DOI: 10.1039/D4RA05934D, Paper
Open Access
Masanori Takemoto, Haruko Fujinuma, Yoshihiro Sugawara, Yukichi Sasaki, Kenta Iyoki, Tatsuya Okubo, Kazuya Yamaguchi, Toru Wakihara
α-MnO2/β-MnOOH catalysts were synthesized by post-synthetic planetary ball milling for OMS-2, enhancing catalytic activity in low-temperature NH3-SCR.
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Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
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High-performance, high energy density symmetric supercapacitors based on δ-MnO2 nanoflower electrodes incorporated with an ion-conducting polymer

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35657-35670
DOI: 10.1039/D4RA05670A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shrishti Sharma, Gurpreet Kaur, Bhargab Sharma, Buddu Nagasiva Saiteja, Anshuman Dalvi
The present work investigates liquid-based and liquid-free supercapacitors assembled using δ-MnO2-nanoflower-based electrodes.
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Electromagnetic wave effects on Mn-doped superparamagnetic iron oxide nanofluids: applications in enhanced oil recovery

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35671-35678
DOI: 10.1039/D4RA04500A, Paper
Open Access
Mohamad Amin Bin Hamid, Beh Hoe Guan, Chan Kar Tim, Hassan Soleimani
This study reveals that both direct current (DC) and alternating current (AC) electromagnetic fields can effectively reduce the interfacial tension (IFT) of Mn-doped Fe3O4 nanofluids, with AC fields showing more predictable and pronounced effects.
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Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
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Tailoring dual cross-linked polymer-ionic liquid composites by blending co-crystallizable polymers for stretchable electronics

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36022-36030
DOI: 10.1039/D4RA05968A, Paper
Open Access
Minjun Kim, Moonsung Park, Hobin Seon, Sohyun Choi, Hee Joong Kim, Sangwon Kim
A dual cross-linked polymer-ionic liquid composite exhibits self-healing capabilities and is ideal for wearable strain sensor applications.
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From e-waste to eco-sensors: synthesis of reduced graphene oxide/ZnO from discarded batteries for a rapid electrochemical bisphenol A sensor

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36073-36083
DOI: 10.1039/D4RA04046E, Paper
Open Access
Md Humayun Kabir, Md Yeasin Pabel, Nishat Tasnim Bristy, Md. Abdus Salam, Muhammad Shahriar Bashar, Sabina Yasmin
E-waste-derived reduced graphene oxide/ZnO forfast electrochemical detection of bisphenol A (BPA).
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Upconversion nanoparticles incorporated with three-dimensional graphene composites for electrochemical sensing of baicalin from natural plants

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36084-36092
DOI: 10.1039/D4RA06540A, Paper
Open Access
Na Zhang, Yilin Wu, Tian Liang, Yongxiang Su, Xusheng Xie, Tianren Zhang, Hongyan Wang, Keying Zhang, Rongli Jiang
The fabrication of UCNP-3DG and its application in electrochemical detection of Bn in natural plant samples.
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Polyether-based polyurethane electrolyte for lithium metal battery: a perspective

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36152-36160
DOI: 10.1039/D4RA06863G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peng Cui, Yifan Li, YuXing Liu, Siqi Wang, Xingyu Tang, Yihong Ye, Hance Su, Chun Sun
Mechanism of increasing ionic conductivity of polyether-based polyurethane electrolyte.
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Investigation of variable range hopping and dielectric relaxation in GdCrO3 orthochromite perovskites

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36161-36172
DOI: 10.1039/D4RA06104G, Paper
Open Access
Mohamed Youssef Gneber, Imen Elhamdi, Jalel Messoudi, Radhia Dhahri, Foudil Sahnoune, Mosbah Jemmali, Magdy Hussein, Essebti Dhahri, Benilde Faria Oliveira Costa
This study investigates the structural, electrical, and dielectric properties of GdCrO3 (GCO) compounds. X-ray diffraction analysis confirmed the formation of the perovskite phase of GCO, crystallizing with the Pbnm space group.
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In silico molecular docking and ADMET prediction of biogenic zinc oxide nanoparticles: characterization, and in vitro antimicrobial and photocatalytic activity

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36209-36225
DOI: 10.1039/D4RA06890D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajara Akhter, Susmita Sarker Ritu, Shahariar Siddique, Fariha Chowdhury, Rehnuma Tasmiyah Chowdhury, Samina Akhter, Mahmuda Hakim
A facile green route to synthesize zinc oxide nanoparticles using watermelon rind extract with antimicrobial and photocatalytic potential.
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Cs2ZnCl4: a lead-free all-inorganic perovskite with a large dielectric permittivity

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36253-36263
DOI: 10.1039/D4RA04755A, Paper
Open Access
Imen Romdhane, Asma Ajmi, Mohamed Ben Bechir, Regis Barille, Abdallah Ben Rhaiem
In recent years, inorganic perovskite materials based on metallic halides have attracted significant attention due to their non-toxicity and ease of synthesis, making them suitable for various applications.
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Physicochemical properties and mechanism of action of a new copper(II) pyrazine-based complex with high anticancer activity and selectivity towards cancer cells

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36295-36307
DOI: 10.1039/D4RA06874B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
B. Rogalewicz, T. Sierański, M. Szczesio, A. Olczak, K. Gobis, C. Orlewska, I. Korona-Głowniak, A. Korga-Plewko, M. Iwan, M. Michalczuk, J. Kubik, G. Adamczuk, M. Korga, N. Rutkowska, T. Boruta, K. Gas, M. Sawicki, E. Poleszak, W. Maniukiewicz, M. Świątkowski, A. Czylkowska
The presented work underlines the importance of coordination compounds in the development of new anticancer agents that are safer and more efficient.
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Farmers in Rajasthan set to get electricity for irrigation of crops during day time

By www.thehindu.com
Published On :: Sat, 10 Aug 2024 21:53:36 +0530

A memorandum of understanding was signed for two gas-based power plants in Jaipur, says Minister Nagar


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Who is carrying the Olympic torch through Paris? A BTS star, a garbage collector and more

By www.thehindu.com
Published On :: Tue, 16 Jul 2024 14:58:04 +0530

Hundreds of people have carried the Olympic torch through the French capital for two days of celebrations before the Summer Games kick off at the end of the month


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Shift in Hindi cinema’s portrayal of doctors reflects society’s evolving perception: Expert

By www.thehindu.com
Published On :: Sat, 09 Nov 2024 18:59:37 +0530


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How much can US president-elect Donald Trump derail global climate action?

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 16:03:45 +0530

Trump is a climate change denier who has promised to increase fossil fuel production and withdraw the US from the Paris climate deal, among other worrying pledges.


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FACTBOX-Who are the candidates running in the US presidential election?

By www.thehindubusinessline.com
Published On :: Tue, 01 Oct 2024 09:56:12 +0530

The upcoming elections in the United States on November 5 have the world on the edge of their seats as they heat up, here is a brief overview of who they are


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Japan’s government in turmoil as election leaves no party majority, hits Yen

By www.thehindubusinessline.com
Published On :: Mon, 28 Oct 2024 06:48:56 +0530

With mounting voter dissatisfaction over scandals and economic pressures, Ishiba’s position as prime minister is now in jeopardy, facing calls for new leadership.


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Robot collects melted fuel from Fukushima nuclear reactor

By www.thehindubusinessline.com
Published On :: Sat, 02 Nov 2024 19:41:39 +0530

Operated by Tokyo Electric Power Company Holdings, the robot collected a fragment measuring approximately 5 millimetres in size


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Trump takes early electoral lead as race with Harris takes shape

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 09:34:30 +0530

Polls have closed in key swing states of Georgia, North Carolina, Pennsylvania and Michigan


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US will be more isolationist whoever wins election, Jaishankar says

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 10:06:31 +0530

"President Trump may be more articulate and expressive in that regard," he said during a panel discussion with the foreign ministers of Australia and New Zealand


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Voters sue Musk for fraud over $1 million election sweepstakes

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 10:35:10 +0530

A day after surviving a legal challenge in Pennsylvania, Musk’s daily sweepstakes was hit Tuesday with fresh claims in federal courts in Texas and Michigan


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Trump wins Pennsylvania, leaving him 3 electoral votes shy of clinching White House

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 13:32:00 +0530

Pennsylvania was carried by Trump when he first won the White House in 2016 and then flipped back to Democrats in 2020. Trump also took Georgia, which had voted for Democrats four years ago


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Narendra Modi congratulates Donald Trump on US election victory, says looking forward to renewing collaboration

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 17:43:06 +0530

‘Let’s work for the betterment of our people and to promote global peace, stability and prosperity,’ Modi says in a post on X


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Three Indian footballers selected for training at Old Trafford in Manchester

By www.thehindu.com
Published On :: Sat, 19 Oct 2024 11:21:23 +0530

PC Lalchhuanawma (Mizoram), Shreejal Kisku (Bhubaneswar), and Mohd Ayan (Lucknow) were selected to visit the Old Trafford alongside Nepal’s Bhakta Bahadur Pariyar and Chanason Chaiyatham from Bangkok


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Serie A leader Napoli scores late to beat struggling Lecce and Atalanta routs Verona

By www.thehindu.com
Published On :: Sun, 27 Oct 2024 05:15:00 +0530

Serie A leader Napoli has needed a late score from captain Giovanni Di Lorenzo to secure a 1-0 victory over struggling Lecce


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Recipe Collecting Shípǔ 食谱

By www.berkshirepublishing.com
Published On :: Mon, 18 Jan 2021 04:01:12 +0000

Abstract: In Chinese history, the practice of collecting recipes evolved along two parallel but interacting trends. The first placed food within a medical context in order to nourish the body and heal different ailments. The second was concerned with technical aspects as well as the aesthetic enjoyments of food. Beginning with twenty recipes found

The post Recipe Collecting Shípǔ 食谱 appeared first on Berkshire Publishing.


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Bulk photovoltaic effect in a zero-dimensional room-temperature molecular ferroelectric [C8N2H22]1.5[Bi2I9]

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02698E, Paper
Zhibo Chen, Tianhong Luo, Jinrong Wen, Zhanqiang Liu, Jingshan Hou, Yongzheng Fang, Ganghua Zhang
Non-toxic molecular ferroelectrics have attracted significant interest due to their unique flexibility, low costs, and environmental friendliness. However, the variety of such materials with narrow bandgaps and above room temperature...
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Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02469A, Paper
Zhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei Qin
Heteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.
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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
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Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02514H, Paper
Khalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique Lorcy
Multinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.
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One-pot facile synthesis of rod-like Bi2S3 particles in deep eutectic solvent and their ppb-level selective H2S gas detection

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT03006K, Communication
Reiko Furukawa, Takuya Hasegawa, Ayahisa Okawa, Shu Yin
Rod-like Bi2S3 particles were synthesized by one-pot reactions with choline chloride-based DESs, and showed sub-ppm level selective H2S gas detection. Acetamide-based DES yielded uniform particles with excellent gas sensitivity.
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Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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