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Modulating the band gap of a pyrazinoquinoxaline-based metal–organic framework through orbital hybridization for enhanced visible light-driven CN bond construction

J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper
Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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A matter of design and coupling: high indoor charging efficiencies with organic solar modules directly coupled to a sodium ion battery

J. Mater. Chem. A, 2024, 12,30862-30871
DOI: 10.1039/D4TA04729J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Li-Chung Kin, Andreas Distler, Oleksandr Astakhov, Bakary Kone, Hans Kungl, André Karl, Tsvetelina Merdzhanova, Rüdiger-A. Eichel, Christoph J. Brabec, Uwe Rau
Generalized framework for the design of indoor power units for autonomous Internet of Things (IOT) devices results in record efficiency combination of organic PV and sodium ion battery.
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Efficient organic solar cells based on low-cost pentacyclic fused-ring small molecule acceptors with a fill factor over 80%

J. Mater. Chem. A, 2024, 12,30558-30566
DOI: 10.1039/D4TA06146B, Paper
Qingya Wei, Yuanyuan Li, Weikun Chen, Qinhao Shi, Shaofeng Zhu, Wensheng Yan, Yingping Zou
A low-cost pentacyclic fused-ring SMA, BZ4F-ch1, was designed with a cyclohexyl side-chain, which achieved a high device efficiency over 16% with an FF over 80%. Besides, the highest PCE/MOC value of 3.56 revealed remarkable cost-effectiveness.
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Unsaturated coordination modulation and enlarged pore size in nanoflower-like metal organic frameworks for enhanced lithium–oxygen battery performance

J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper
Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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organ

One-pot spatial engineering of multi-enzymes in metal–organic frameworks for enhanced cascade activity

J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper
Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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Recent Advances p-type Polymeric Electrode Materials towards High-Voltage 4.0 V-class Organic Lithium-ion Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06028H, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Febri Baskoro, Santosh U. Sharma, Andre Lammiduk Lubis, Hung-Ju Yen
Lithium-ion batteries stand at the forefront of energy storage technologies, facilitating the transition towards sustainable and electrified systems. To meet the increasing demands for energy density, safety, and longevity, the...
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organ

A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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organ

Organization Analytics Online Courses

As info drives an increasing number of decisions around industries, a lot more jobs require specialists with organization analytics skills. While this field requires a mix of bureaucratic and discursive thinking, in addition, it needs knowledge of statistics and computer science. This mix of domains allows business analysts to bridge the gap among management and […]




organ

Commercial Property Data Organizing

Organizing business property info enables organization users to get the observations needed to generate defendable short and long term commercial proper property decisions. While it might sound like an arduous process, CRE specialists can streamline the procedure with the help of data platforms that provide foundational data sets in a single easy-to-navigate dashboard. These types […]




organ

Groupon willing to look at inorganic growth in India




organ

Say cheese, says the organised dairy sector

And it has every reason to smile. Covid-19 has triggered a consumer shift towards branded products as against vending in loose. Rutam Vora and Vishwanath Kulkarni report




organ

Greenhouse gas emissions surge to new record in 2023: World Meteorological Organization report

The globally averaged surface concentration of carbon dioxide reached 420 parts per million (ppm), methane 1934 parts per billion and nitrous oxide 336.9 parts per billion (ppb) in 2023.




organ

Organs of 20-year-old accident victim from Mysuru donated




organ

Government organisations take ‘Integrity Pledge’




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Organic kitchen garden inaugurated at government school in Puducherry




organ

Efficient and easily repeatable organic solar cells in a high boiling point solvent by introducing a highly mixed tolerant guest acceptor

J. Mater. Chem. C, 2024, 12,17403-17410
DOI: 10.1039/D4TC03192J, Paper
Open Access
Xiangyu Shen, Xiaoning Wang, Jianxiao Wang, Rulin Wang, Yonghai Li, Fuzhen Bi, Xichang Bao
Efficient and easily repeatable organic solar cells were fabricated based on a highly mixed tolerant acceptor in a high boiling point solvent.
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Melt-preparation of organic–inorganic Mn-based halide transparent ceramic scintillators for high-resolution X-ray imaging

J. Mater. Chem. C, 2024, 12,17411-17418
DOI: 10.1039/D4TC03459G, Paper
Zhi-Zhong Zhang, Zi-Lin He, Qing-Peng Peng, Jing-Hua Chen, Bang Lan, Dai-Bin Kuang
A large size TBP2MnBr4 transparent ceramic is prepared by the melt processing method, which shows a high transmittance of >80% in the wavelength range of 350 nm to 800 nm, for realizing a high-resolution (16 lp mm−1) X-ray imaging.
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Modulation of photophysical properties in o-carborane derivatives and their application in white organic light-emitting diode devices

J. Mater. Chem. C, 2024, 12,17554-17562
DOI: 10.1039/D4TC03085K, Paper
Jina Lee, Yeonju Jeong, Sunhee Lee, Yi Sak Lee, Bubae Park, Taekyung Kim, Won-Sik Han
Two derivatives of o-carborane, CAPCb and CAMCb, were synthesized and utilized in the fabrication of white OLED devices that exhibit cool white emission and specific CIE coordinates.
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Application of a NADH-modified ZnO electron transport layer in high performance organic solar cells

J. Mater. Chem. C, 2024, 12,17429-17438
DOI: 10.1039/D4TC03144J, Paper
Hongye Li, Song Yang, Huangzhong Yu
A novel ZnO:NADH composite electron transport layer is constructed, and the efficiency of organic solar cells (OSCs) with PM6:L8-BO as the active layer has improved from 17.43% to 18.21%.
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Additive-induced intermolecular interaction enhancement enables highly efficient organic solar cells

J. Mater. Chem. C, 2024, 12,17668-17675
DOI: 10.1039/D4TC03277B, Paper
Chen Chen, Dingqin Hu, Peihao Huang, Chun Hong Mak, Heng Liu, Hongliang Lei, Xue Jiang, Yulu Li, Fengyi Yu, Kaihuai Tu, Hsien-Yi Hsu, Xinhui Lu, Haiyan Chen, Zeyun Xiao
We developed a pyridine-based solvent additive targeting the acceptor moiety. This additive fine-tunes the aggregation, crystallinity, and stacking of the active layer through stronger non-covalent interactions with the acceptor.
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Pressure-Induced Tunable Emission Colors and Irreversible Bandgap Narrowing in Organic–Inorganic Manganese Bromide Hybrid

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03814B, Paper
Ruijing Fu, Junpeng Gao, Pinsen Zhang, Lingrui Wang, Bo Wang, Guangxia Wang, Xiaoshuang Li, youchao Kong, Qingguang Zeng, Guanjun Xiao
Manganese (Mn)-based organic-inorganic metal halides (OIMHs) are extensively employed in various optical applications due to their non-toxicity, superior optical properties, and tunable emission advantages. Developing effective strategies to enhance the...
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Silver-incorporated NiCo metal–organic frameworks with controlled morphology for enhanced cycling in flexible supercapacitor applications

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC02970D, Paper
Chu Chu, Wenjing Zhang, Xuehua Yan, Yingnan Yan, Jianmei Pan, Zohreh Shahnavaz, Jamile Mohammadi Moradian
The specific capacitance of NCA15-MOF/NF was 1317 F g−1, which was significantly higher compared to the NCA0-MOF/NF. After 15 000 charge–discharge cycles, the NCA15-MOF/NF retained 89% of its initial specific capacitance.
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Application of metal organic frameworks (MOFs) and their derivatives in the cathode materials of aqueous zinc-ion batteries

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03273J, Review Article
Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu, Yanxiang Wang
Metal–organic frameworks (MOFs) are regarded as potential candidate materials for the cathodes of aqueous zinc-ion batteries. This review presents the applications of MOFs and their derivatives in the cathodes of aqueous zinc-ion batteries.
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A metal–organic framework enhanced single network organohydrogel with superior low-temperature adaptability and UV-blocking capability towards human-motion sensing

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper
Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH2 nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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Organic agriculture, a stop to climate change



  • Solutions & Co

organ

PILI, the "organic" ink pioneer

A French biotech company is developing fully biodegradable ink, using pigments made from bacteria. Is this the next revolution for our ballpoint pens?



  • Solutions & Co

organ

Enhancing electrochemical reactions in organic synthesis: the impact of flow chemistry

Chem. Soc. Rev., 2024, 53,10741-10760
DOI: 10.1039/D4CS00539B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Morgan Regnier, Clara Vega, Dimitris I. Ioannou, Timothy Noël
Utilizing electrons directly offers significant potential for advancing organic synthesis by facilitating novel reactivity and enhancing selectivity under mild conditions.
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A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00521J, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu, Jianchun Jiang
Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement.
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Recent synthetic strategies for the functionalization of fused bicyclic heteroaromatics using organo-Li, -Mg and -Zn reagents

Chem. Soc. Rev., 2024, 53,11045-11099
DOI: 10.1039/D4CS00369A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vasudevan Dhayalan, Vishal S. Dodke, Marappan Pradeep Kumar, Hatice Seher Korkmaz, Anja Hoffmann-Röder, Pitchamuthu Amaladass, Rambabu Dandela, Ragupathy Dhanusuraman, Paul Knochel
This review presents various new strategies for the functionalization of 5 and 6-membered fused heteroaromatics. These synthetic strategies enable rapid access to complex heterocyclic compounds.
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Reactive oxygen species-mediated organic long-persistent luminophores light up biomedicine: from two-component separated nano-systems to integrated uni-luminophores

Chem. Soc. Rev., 2024, 53,11207-11227
DOI: 10.1039/D4CS00443D, Review Article
Zhe Li, Hongwen Liu, Xiao-Bing Zhang
An overview of the recent advances in reactive oxygen species-mediated organic long-persistent luminophores, including their history, working mechanisms, design strategies, and biomedical applications.
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Light/X-ray/ultrasound activated delayed photon emission of organic molecular probes for optical imaging: mechanisms, design strategies, and biomedical applications

Chem. Soc. Rev., 2024, 53,10970-11003
DOI: 10.1039/D4CS00599F, Review Article
Rui Qu, Xiqun Jiang, Xu Zhen
Versatile energy inputs, including light, X-ray and ultrasound, activate organic molecular probes to undergo different delay mechanisms, including charge separation, triplet exciton stabilization and chemical trap, for delayed photon emission.
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Conjugated polymers for organic electronics [electronic resource] : design and synthesis / Andrew Grimsdale and Paul Dastoor.

Cambridge, United Kingdom ; New York : Cambridge University Press, 2024.




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Multiple organs harvested from accident victim from Tiruppur




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Those who feel the fire burning (2014) / written and directed by Morgan Knibbe [DVD].

[Amsterdam] : Cinema Delicatessen, [2015]




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Unrecognized volatile and semi-volatile organic compounds from brake wear

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00024B, Paper
V. Perraud, D. R. Blake, L. M. Wingen, B. Barletta, P. S. Bauer, J. Campos, M. J. Ezell, A. Guenther, K. N. Johnson, M. Lee, S. Meinardi, J. Patterson, E. S. Saltzman, A. E. Thomas, J. N. Smith, B. J. Finlayson-Pitts
This study shows that volatile and semi-volatile organic gases are emitted during light and heavy braking. These emissions will remain as we transition to zero exhaust emission vehicles and must be included in air pollution and climate assessments.
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Design, development, and evaluation of the organic chemistry representational competence assessment (ORCA)

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D3RP00188A, Paper
Lyniesha Ward, Fridah Rotich, Jeffrey R. Raker, Regis Komperda, Sachin Nedungadi, Maia Popova
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Investigating students' expectations and engagement in general and organic chemistry laboratory courses

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D4RP00277F, Paper
Elizabeth B. Vaughan, Saraswathi Tummuru, Jack Barbera
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Enhanced photocatalysis of metal/covalent organic frameworks by plasmonic nanoparticles and homo/hetero-junctions

Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article
Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
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organ

A bioactive calcium silicate nanowire-containing hydrogel for organoid formation and functionalization

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00228H, Communication
Wenping Ma, Yi Zheng, Guangzhen Yang, Hongjian Zhang, Mingxia Lu, Hongshi Ma, Chengtie Wu, Hongxu Lu
An optimized CS/GelMA composite hydrogel is designed for organoid development, which can be used as a substrate for supporting intestinal and liver organoid formation and functionalization.
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Heterointerface regulation of covalent organic framework-anchored graphene via a solvent-free strategy for high-performance supercapacitor and hybrid capacitive deionization electrodes

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00161C, Communication
Liming Xu, Yong Liu, Xiaoyang Xuan, Xingtao Xu, Yuquan Li, Ting Lu, Likun Pan
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
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Biphenyl Tetracarboxylic Acid based Metal-Organic Frameworks: A Case of Topology-Dependent Thermal Expansion

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication
Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
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Aggregation-induced emission organic metal halide complex for X-ray scintillation

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication
Open Access
Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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A reflection on ‘The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA)2KBiCl6 (MA = methylammonium)’

Mater. Horiz., 2024, 11,1832-1837
DOI: 10.1039/D4MH90029D, Commentary
Anthony K. Cheetham, Paul D. Bristowe, Satoshi Tominaka, Fengxia Wei
Cheetham et al. reflect on one of their first Materials Horizons papers (Mater. Horiz., 2016, https://doi.org/10.1039/C6MH00053C) published in the journal and discuss how their work may have influenced the research field.
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organ

How we Organize Figma Projects and Files On Our Design Team

Organizing Figma projects & files differs from team to team, depends on size of your team, the make up of your team & products. Consistency & teaching people how to quickly navigate these files so they aren’t relearning each time is important.

This is how we organize Figma…

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How we Organize Design Files and Cover Pages in Figma

Not everyone on your team knows how to navigate Figma the way you do. Other designers have different methods. Engineers and PMs may not know where to start.

This is how we organize our project files and pages in Figma…

Read on Twitter or Read on Medium