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Charge Transfer Complex Enabled Mechanochemical Synthesis of Chalcogenoacetylenes via Alkynyl Radicals

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01827C, Research Article
Open Access
Fang Tan, Chang-Zhen Fang, Bing-Sheng Qiu, He Sheng, Yong-Liang Tu, Xiang-Yu Chen
Mechanochemistry has become an appealing strategy to enable numerous organic transformations. While significant advances have been achieved, the radical coupling reaction under mechanochemical conditions is still in its infancy. In...
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Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01875C, Research Article
Xi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min Liang
A nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.
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Gamchhas transformed into saris

Textile revivalist Jaya Jaitly talks about her gamchha project



  • History & Culture

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Strain-affected ferroelastic domain walls in RbMnFe charge-transfer materials undergoing collective Jahn–Teller distortion

RSC Adv., 2024, 14,35081-35089
DOI: 10.1039/D4RA06397J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marius Hervé, Shintaro Akagi, Laurent Guérin, Leland B. Gee, Ryan D. Ribson, Matthieu Chollet, Marco Cammarata, Shuntaro Nagashima, Shin-ichi Ohkoshi, Hiroko Tokoro, Eric Collet
This X-ray diffraction study of RbMnFe materials reveals the ferroelastic domains walls resulting from collective Jahn–Teller distortion coupled to intermetallic charge-transfer and the spatial extension of the strain around the walls.
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Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications

RSC Adv., 2024, 14,35490-35497
DOI: 10.1039/D4RA06404F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lili Xie, Haiyan Qiu, Yuxin Chen, Yingxue Lu, Yanyan Chen, Lanlan Chen, Shanwen Hu
A zero-dimensional halide perovskite in micron scale is constructed to gain a deeper understanding of phase transformation mechanism and better fluorescence applications.
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Chronological effects of oxygen on the structural transformations of polyacrylonitrile fibers during the rapid thermal stabilization process

RSC Adv., 2024, 14,35560-35567
DOI: 10.1039/D4RA06327A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shiyang Li, Liang Chen, Jie Liu, Yixin Li, Jian Tang, Rongchao Jiang, Xiaoxu Wang
The effects of oxygen on the structure changes of PAN fibers during the rapid thermal stabilization are chronological, including thermal-driven dehydrogenation, oxidation and cyclization in the shorter, intermediate and longer periods, respectively.
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Paris Olympics 2024 | Inside the radical transformation in Indian sports and the making of a medal-winning champion

Over the last decade, not-for-profit organisations as well as private academies and training centres have come forward to train Indian athletes, bringing them on a par with global standards




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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
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Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation

Environ. Sci.: Water Res. Technol., 2024, 10,2646-2654
DOI: 10.1039/D4EW00496E, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
D. Boglaienko, M. E. Bowden, N. M. Escobedo, Q. M. Collins, A. R. Lawter, T. G. Levitskaia, C. I. Pearce
Removal of pertechnetate 99TcO4 and perrhenate ReO4 during mineral transformation of the non-toxic basic bismuth subnitrate for subsurface remediation.
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Digital University Kerala presents report on digital transformation study of judicial systems to Kerala High Court

DUK Vice-Chancellor emphasises the report’s focus on harnessing cutting-edge technology to streamline the judicial process, reduce case pendency and optimise case management workflows.




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Kerala digital varsity’s Centre for Digital Transformation in Culture to get a website




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Jharkhand Polls: As Phase-1 Campaigning Ends, Amit Shah Pitches 'Committee' Against Infiltrators, Legislation To Ban Land Transfer

Jharkhand Vidhansabha Chunav: Amit Shah said that legislation will be brought to prevent the transfer of land to infiltrators on their marrying tribal women. 




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IIT Madras unveils plans to transform India into a global chess powerhouse

The initiative is aimed at enhancing fan engagement, providing solutions for federations to flag cheating and chess training programmes to further grow the sports at the grassroots level




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Nemetschek India and ICT Academy sign MoU to boost digital transformation in education

The partnership aims to upskill students and professionals for the AEC industry through workshops, seminars, and certifications




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Weakened hydrogen bond connectivity promotes interfacial mass transfer for industrial level scalable biomass electrooxidation

Energy Environ. Sci., 2024, 17,8801-8809
DOI: 10.1039/D4EE03482A, Paper
Zhaohui Yang, Lan Chen, Yijun Yin, Chenyang Wei, Zhimin Xue, Tiancheng Mu
The inhomogeneous valence distribution due to in the intrinsic electric field of a material can weaken the interfacial H-bonding connectivity under the bias potential, which promotes the mass transfer of HMF during the HMF electrooxidation reaction.
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Deep ion mass transfer addressing the capacity shrink challenge of aqueous Zn‖MnO2 batteries during the cathode scaleup

Energy Environ. Sci., 2024, 17,8904-8914
DOI: 10.1039/D4EE02871F, Paper
Na Jiang, You Zeng, Qi Yang, Puda Lu, Keqi Qu, Lihang Ye, Xuejun Lu, Ziqiang Liu, Xixian Li, Yongchao Tang, Jinchao Cao, Shimou Chen, Chunyi Zhi, Jieshan Qiu
This work shows that the introduction of interstitial carbon into the MnO2 lattice could reduce the affinity toward SO42− and OH, thus suppressing the surface coverage of ZHS and improving the Zn||MnO2 battery performance under large loading mass.
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Ministerial staff urge Chief Secretary to ensure compliance with transfer policy norms

The staff body accuses Department of Personnel and Administrative Reforms of failing to follow the norms for its own department, and of violating transfer policy norms prevailing in the government for more than 15 years in the matters of transfer, promotion, recruitment rules, regularisation of services, of an estimated 3,000 ministerial employees




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A decade of India’s transformative sanitation mission

The sanitation revolution, the Swachh Bharat Mission, is not just India’s achievement but is also a global one




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Mediated electron transfer in a photo-bioreactor: continuous flow hydroxylation using cytochrome P450 BM3 in NADPH-free conditions

React. Chem. Eng., 2024, 9,803-815
DOI: 10.1039/D3RE00569K, Paper
Ali Fendri, Donya Valikhani, Joelle N. Pelletier
We designed a proof-of-concept photo-bioreactor enabling continuous flow NADPH-free activation of cytochrome P450 BM3 via mediated electron transfer.
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Experimental Investigation of Mass Transfer in NH3 SCR Over Self-Supporting Cu-ZSM-5 Foam

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D3RE00533J, Paper
Risha Raju, Kuruvilla Joseph, K. Prabhakaran, A. Salih
Selective catalytic reduction of NOx by NH3 is an emerging technology for emission control applications worldwide. The development of structured catalysts for process intensification is of growing interest in catalytic...
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Wheelocity secures $15 million to transform e-commerce in semi-urban India 

Originally a B2B platform, Wheelocity has transitioned to a B2C model, now serving over 1 million households across 3,500 towns and villages




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Transformers One Review

If you're a fan of the Transformer films already, you will be delighted with a hearty dose of nostalgia here but... Mayur Sanap adds a caveat.




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Directed evolution of C-methyltransferase PsmD for enantioselective pyrroloindole derivative production

Catal. Sci. Technol., 2024, 14,6298-6306
DOI: 10.1039/D4CY00657G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Diana A. Amariei, Julia Tenhaef, Thomas Classen, Benoit David, Tobias M. Rosch, Holger Gohlke, Stephan Noack, Jörg Pietruszka
The engineering of stereoselective C-methyltransferase PsmD through saturation mutagenesis led to improved activity for larger substrates. An automated process was designed and successfully applied for the mutant library production and screening.
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Broadening the substrate range of serine palmitoyltransferase by protein engineering and applications to 3-keto-dihydrosphingosine analogs

Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper
Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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Electrostatic interactions and structural transformations in viral shells

Nanoscale, 2024, 16,20182-20193
DOI: 10.1039/D4NR02612H, Paper
Open Access
Ivan Yu. Golushko, Daria S. Roshal, Olga V. Konevtsova, Sergei B. Rochal, Rudolf Podgornik
Considering the simplest energy of electrostatic interactions between proteins together with the mechanical energy of the continuum shell, one can model various structural transformations possible in viral capsids.
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Size effect on the structural and magnetic phase transformations of iron nanoparticles

Nanoscale, 2024, 16,20304-20311
DOI: 10.1039/D4NR02488E, Paper
Alexis Front, Georg Daniel Förster, Chu Chun Fu, Cyrille Barreteau, Hakim Amara
(a) Magnetic (top) and structural (bottom) phase transformation of an iron nanoparticle. (b) Size dependence on magnetic and structural transition temperatures on iron nanoparticles.
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A place of transformation

Sujatha Shankar Kumar on how a derelict building became the new InKo centre.




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Budget 2024 | An action-oriented Budget, with the mantra of reforming, performing and transforming India

The continued focus on increased capital investments will result in generation of employment opportunities while MSME-centric initiatives will help them compete globally; the Budget also promotes sustainable growth  




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T20 World Cup: Taking cricket to America involves a difficult culture transfer

It might be politically incorrect to say this, but America isn’t ready to embrace cricket yet




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Maharashtra Polls Exclusive: `Rs 125 Cr Transferred To 200 Accounts, Withdrawn Overnight`; Deal Done For Muslim Votes?

In today's DNA, the Zee News anchor analysed the transfer of a huge amount of money to 200 Accounts ahead of polls in Maharashtra.




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Tecno Spark 30 C 5G with transformers skin, 120 Hz refresh rate launched in India for entry segment buyers

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Setup may make transferring <em>tert</em>-butyl lithium and other pyrophoric reagents safer

Simple pieces of equipment decrease the danger of moving small volumes of chemicals prone to igniting




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Un dispositivo hace más fácil y segura la transferencia de <i>terc</i>-butil litio y otros compuestos químicos pirofóricos

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Setup may make transferring <i>tert</i>-butyl lithium and other pyrophoric reagents safer

Simple pieces of equipment decrease the danger of moving small volumes of chemicals prone to igniting




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Tarapur Transformers Ltd - Board Meeting Intimation for The Quarter Ended On 30Th June, 2019




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Tarapur Transformers Ltd - Closure of Trading Window




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National Fertilizers Ltd. - Register Of Member And Share Transfer Books Of The Company Will Remain Closed From 12Th September, 2019 To 18Th September, 2019 (Both Days Inclusive)




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National Fertilizers Ltd. - Register Of Member And Share Transfer Books Of The Company Will Remain Closed From 12Th September, 2019 To 18Th September, 2019 (Both Days Inclusive).




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Visible light-induced strain-release transformations of bicyclo[1.1.0]butanes

Green Chem., 2024, 26,11083-11105
DOI: 10.1039/D4GC03193H, Tutorial Review
Qing-Bao Zhang, Feng Li, Bin Pan, Shanshan Zhang, Xiang-Guo Yue, Qiang Liu
This review aims to provide an overview on the recent visible light-mediated strain-release transformations of bicyclo[1.1.0]butanes. Prospects for future development of (aza)bicyclo[1.1.0]butanes in this fascinating field are outlined.
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Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate)

Green Chem., 2024, 26,11125-11131
DOI: 10.1039/D4GC05070C, Communication
Open Access
Lee B. Anderson, Conall Molloy, Lorenzo Pedrini, Ian L. Martin, Stephen J. Connon
The evaluation of a library of phase transfer catalysts in the alkaline hydrolysis of polyethylene terephthalate revealed the key interplay between catalyst structure/properties and the reaction conditions.
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Utilize rather than create: transforming phthalonitrile resin into N-rich hierarchical porous carbon for supercapacitor materials

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04103H, Paper
Yi Li, Qiancheng Liu, Qian Zhang, Xiaoxiao Li, Yang Yang, Pan Wang, Kui Li, Ying Li, Fei Zhong, Qi Liu, Yun Zheng, Xulin Yang, Peng Zhao
The “utilize rather than create” strategy employs the reaction product (RPH) as the precursor and the by-product (KCl) as the template for the synthesis of N-rich hierarchical porous carbon for high performance supercapacitor materials.
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EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
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Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05207B, Paper
Yao Chai, Zirui Pang, Heng Jiang, Chi Chung Tsoi, Liang Wan, Yu Du, Huaping Jia, Yujiao Zhu, Detao Liu, Fengjia Xie, Guangya Zhou, Xuming Zhang
The direct electron transfer mechanism of single-layer Bi2MoO6 ultrathin nanosheets promotes the efficient regeneration of photocatalytic coenzyme NAD(P)H.
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77 families get new homes after Kolhapur settlement undergoes transformation through PMAY’s beneficiary-led construction




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Project Mgr-NPD/Process Engg-Ludhiana (Hot Forged/Steel & Alloy Parts by Progrssive & Tansfer Dies)

Company: P & I Management Consultants
Experience: 0 to 50
location: India
Ref: 24341084
Summary: Job Description: New Product & Process Development Engineer/Project Manager-Ludhiana must have: 1. Knowledge and ability to develop new products and process of hot forged Steel and Alloy components 2. Knowledge and ability to....




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Real Madrid 'set Arsenal transfer deadline for Pierre-Emerick Aubameyang deal'

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Sport24.co.za | Rabiot 'open' to Premier League transfer

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Communist Party’s Plenum Will Be Important, Not Transformative, for China

8 November 2013

Professor Kerry Brown

Associate Fellow, Asia-Pacific Programme

20131108PudongChina.jpg

View of the Pudong financial district skyline from the historic Bund, Shanghai 29 October 2013. Photo by Getty Images.

Despite the hype surrounding it, the gathering of the country’s ruling elite in Beijing is likely to prize measured change over dramatic reform.

If there was a clearer idea of what makes China’s new elite leadership tick, then the Plenum of the Central Committee of the Communist Party that is about to be held in Beijing would not be such a big deal. But in a polity which privileges concealment over overt statement, it is viewed widely as the one chance for outsiders to see more clearly what the leadership aims to achieve. Expectations were raised by the October statement by one of the most staid members of the current Standing Committee of the Politburo, Yu Zhengsheng, that the plenum would presage a new era of reform.

In Chinese politics reform is a word that has a wholesome, positive air about it. But the question is where and when reform will happen and who will gain from it. The plenum is not like a party convention in the Western sense. It is not an eye-grabbing, media-dominating event that produces surprises. Comparing this year’s installment with the great Third Plenum of 1978 that heralded the repudiation of late Maoism and the embracing of the market, the non-state sector and foreign capital – all anathema before then – is misleading. The significance of the 1978 meeting was only obvious in hindsight. It took years for the scale of the radical transformation of the whole strategic direction of the Communist Party to be appreciated. That 2013 will prove a similar historic moment is unlikely, perhaps even impossible.

What is much more likely is that the highly tactical leadership now in charge will reaffirm its commitment to incremental reform. It will make some statements about the radical urbanization that China is about to undergo and say something about social welfare reform. China’s leaders will do what they have always done in plenums over the last three decades, namely set the broad parameters of politically permissible activity that provinces, ministries and other stakeholders will then need to implement.

This plenum will also have to produce something about the need to achieve greater egality and balance in the economy. It needs to answer some of the questions about how Premier Li Keqiang, in particular, intends to meet the goal of 'fast, sustainable growth' when a falling overall GDP figure looks likely. It needs to communicate to as broad a constituency as possible the arch-narrative of a world where the raw statement of growth on its own is no longer the be all and end all of government policy. It needs to say something about how the party is going to fulfill the increasingly complex aspirations of the Chinese people, aspirations that exceed purely having a materially good level of life and concern broader questions of well-being that vex the politics of all developed economies.

Observers will want to see some signs too of addressing the most sensitive issues. Yu Zhengsheng talked of economic reform. Reforming the economy is now a wholly uncontroversial mantra in China. However, it impacts on one enormously important issue that reaches beyond economics: whether wealth, prosperity and development benefit the few or are accessible to the many – in other words, good, old-fashioned questions of economic and social justice. At the heart of this lies the question of how state-owned enterprises have become vehicles of profit not just for the party state, but also for tightly knit networks of vested interests. Reforms that lap at the doors of these entities also creep into the space of powerful political players, who will resist any attempt to cut down their wealth, and who have the power to resist.

China’s new leadership is proving more confident than was expected and displays a high sense of historic mission. President Xi Jinping speaks increasingly like a politician who believes it is almost his historic destiny to sit at the centre of the leadership of a renascent 'rich, strong country'. The ultimate question for the plenum is not what outside observers make of it but what the vastly complex mixture of groups in China does. For them, a sign that the leadership is willing to take on some of the entrenched vested interests that penetrate the operations of some state-owned sectors to the core is critical.

This is likely to be couched in the language of more support for the market, which is the key channel in any attack on vested interests – through widening access to wealth and economic benefits, and support for the non-state sector and entrepreneurs. It is hard to see how deeper reform can occur without these two crucial elements. And it is through these that the attitude of China’s leadership to political and legal reforms – far more complex issues that, almost certainly, will not be addressed at the plenum but will lurk in the background − will become clearer. The leadership thinks it is too early to tackle these issues directly, but this plenum will still be part of the process for it to come up with ideas for how to transform not just China’s economy, but its polity too.

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