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A cheaper substitute for HRP: ultra-small Cu–Au bimetallic enzyme mimics with infinitesimal steric hindrance to promote catalytic lateral flow immunodetection of clenbuterol

Lab Chip, 2024, 24,2272-2279
DOI: 10.1039/D3LC01079A, Paper
Huilan Hu, Jiaqi Tian, Rui Shu, Huihui Liu, Shaochi Wang, Xuechi Yin, Jianlong Wang, Daohong Zhang
A lateral flow immunoassay (LFIA) is developed for enzyme-catalyzed double-reading determination of clenbuterol (CLE) through the direct electrostatic adsorption of ultra-small copper–gold bimetallic enzyme mimics (USCGs) and monoclonal antibodies.
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A novel ratiometric design of microfluidic paper-based analytical device for the simultaneous detection of Cu2+ and Fe3+ in drinking water using a fluorescent MOF@tetracycline nanocomposite

Lab Chip, 2024, 24,2306-2316
DOI: 10.1039/D3LC01045G, Paper
Sabah H. Al-Jaf, Sameera Sh. Mohammed Ameen, Khalid M. Omer
On-site monitoring of ions in drinking water is essential for safeguarding public health, ensuring high water quality, and preserving the ecological balance of aquatic ecosystems.
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Brachytherapy on-a-chip: a clinically-relevant approach for radiotherapy testing in 3d biology

Lab Chip, 2024, 24,2335-2346
DOI: 10.1039/D4LC00032C, Paper
Rodin Chermat, Elena Refet-Mollof, Yuji Kamio, Jean-François Carrier, Philip Wong, Thomas Gervais
We introduce the first brachytherapy-on-chip device for in vitro testing of brachytherapy on naturally hypoxic tumor spheroids, for translational research and drug development.
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Kinetics of the valorization of hexoses with Sn-USY catalysts in methanolic media: glycosidation vs. retroaldol cleavage

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00307A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
J. M. Jimenez-Martin, M. El Tawil-Lucas, C. García-Jerez, J. Moreno, A. García, B. Hernández, J. Iglesias
Two operational regions in the transformation of hexoses have been revealed by experimental and kinetic analysis: glycosidation and retroaldol cleavage at low and high temperatures, respectively.
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Evaluating metal-free quaternized boronate esters as efficient catalysts for the fixation of CO2 with epoxides to form cyclic carbonates under suitable conditions

React. Chem. Eng., 2024, 9,2938-2953
DOI: 10.1039/D4RE00282B, Paper
Eyyup Yasar, Emine Aytar, Ahmet Kilic
The conversion of CO2 into high value-added chemicals is receiving increasing attention from the scientific community, commercial enterprises, and policymakers due to environmental problems like global warming.
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A novel magnetic nanoparticle as an efficient and recyclable heterogeneous catalyst for the Suzuki cross-coupling reaction

React. Chem. Eng., 2024, 9,2954-2962
DOI: 10.1039/D4RE00226A, Paper
Hui Jin, Mengyu Cui, Peiwen Liu, Zhuo Wang, Tongxia Jin, Yonghui Yang, Weiping Zhu, Xuhong Qian
A novel magnetically recyclable heterogeneous palladium catalyst Fe3O4@FSM@Pd was constructed and characterized, which is highly efficient and reusable for the Suzuki–Miyaura cross-coupling reaction.
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Combination of near-infrared spectroscopy and a transient flow method for efficient kinetic analysis of the Claisen rearrangement

React. Chem. Eng., 2024, 9,2975-2983
DOI: 10.1039/D4RE00301B, Paper
Yoshihiro Takebayashi, Kiwamu Sue, Sho Kataoka
An automated flow reactor with a rapid inline monitoring using a compact near-infrared spectrometer and a flow rate ramp control enabled high-density kinetic data acquisition.
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Closed-loop identification of enzyme kinetics applying model-based design of experiments

React. Chem. Eng., 2024, 9,2984-2993
DOI: 10.1039/D4RE00127C, Paper
Leon Hennecke, Lucas Schaare, Mirko Skiborowski, Andreas Liese
This study presents an automated reactor platform for the identification of enzyme kinetic models using model-based design of experiments on the example of the reduction of NAD+ by formate dehydrogenase from Candida boidinii.
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Immobilization of cationic dye on photoluminescent hydroxyapatite particles through a citric acid bonding layer

React. Chem. Eng., 2024, 9,2863-2867
DOI: 10.1039/D4RE00277F, Communication
Daichi Noda, Wanyu Shi, Aiga Yamada, Zizhen Liu, Motohiro Tagaya
Promotion of the immobilization of cationic porphyrin on Eu(III) ion-doped hydroxyapatite nanoparticles through citric acid as the bonding layer was achieved.
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Removal of gaseous Hg0 by Cl-loaded carbonaceous material prepared from rice husk

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00414K, Paper
Naoto Tsubouchi, Momone Yoshizawa, Javzandogole Bud, Yuuki Mochizuki
The main objective of this study was to investigate the removal of gaseous Hg0 from the residue obtained during the chlorination of rice husk char to recover silica.
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A computational study of nematic core structure and disclination interactions in elastically anisotropic nematics

Soft Matter, 2024, 20,2900-2914
DOI: 10.1039/D3SM01616A, Paper
Lucas Myers, Carter Swift, Jonas Rønning, Luiza Angheluta, Jorge Viñals
The structure of isolated disclinations and disclination dipoles in anisotropically elastic nematic liquid crystals is explored via a singular potential computational model.
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Hydrodynamically induced aggregation of two dimensional oriented active particles

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01670F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roee Bashan, Naomi Oppenheimer
We show that in many cases aligned active particles in a two-dimensional fluid attract and form fractal-like clusters.
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Thermoresponsive oil-continuous gels based on double-interpenetrating colloidal-particle networks

Soft Matter, 2024, 20,3033-3043
DOI: 10.1039/D3SM01582C, Paper
Braulio A. Macias-Rodriguez, Roland Gouzy, Corentin Coulais, Krassimir P. Velikov
Gels of multicomponent building blocks offer promising opportunities for the development of novel soft materials with unique and useful structures and properties.
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Shear zones in granular mixtures of hard and soft particles with high and low friction

Soft Matter, 2024, 20,3118-3130
DOI: 10.1039/D4SM00100A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Aditya Pratap Singh, Vasileios Angelidakis, Thorsten Pöschel, Sudeshna Roy
Granular materials show inhomogeneous flows characterized by strain localization.
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Dilute gel networks vs. clumpy gels in colloidal systems with a competition between repulsive and attractive interactions

Soft Matter, 2024, 20,3143-3153
DOI: 10.1039/D3SM01717F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. Gimperlein, Jasper N. Immink, M. Schmiedeberg
Dilute and dense systems differ in the way structural properties emerge. Two regimes of percolation might be responsible for differences. Global and local structural properties give insights into these differences.
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Stable and permeable polyion complex vesicles designed as enzymatic nanoreactors

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00216D, Paper
Yuting Wan, Yuening Qiu, Jin Zhou, Jinbo Liu, Martien A. Cohen Stuart, Yangfeng Peng, Junyou Wang
Stable and permeable polyion complex vesicles designed as enzymatic nanoreactors.
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Pinning–depinning transition of droplets on inclined substrates with a three-dimensional topographical defect

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00081A, Paper
Ninad V. Mhatre, Satish Kumar
The influence of defect geometry on the critical inclination angle required for droplet depinning on inclined substrates is studied.
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Particle-based and continuum models for confined nematics in two dimensions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01684F, Paper
Humberto Híjar, Apala Majumdar
Particle-based mesoscopic simulations conduct 2D nematics confined in polygons through consistent defect annihilation dynamics and produce unstable structures that transform into equilibrium textures predicted by the Landau-de Gennes theory.
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The sweetest polymer nanoparticles: opportunities ahead for glycogen in nanomedicine

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00261J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Quinn A. Besford
Glycogen is a biomaterial nanoparticle composed of sugar. In this perspective, the opportunities of glycogen in nanomedicine going forward is discussed.
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Theory and simulation of ligand functionalized nanoparticles – a pedagogical overview

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00177J, Review Article
Thi Vo
Synthesizing reconfigurable nanoscale synthons with predictive control over shape, size, and interparticle interactions is a holy grail of bottom-up self-assembly.
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In situ aggregation and early states of gelation of gold nanoparticle dispersions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00080C, Paper
Florian Schulz, Avni Jain, Francesco Dallari, Verena Markmann, Felix Lehmkühler
The aggregation and onset of gelation of PEGylated gold nanoparticles dispersed in a glycerol–water mixture is studied by small-angle X-ray scattering and X-ray photon correlation spectroscopy.
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Removal of diclofenac sodium from water using a polyacrylonitrile mixed-matrix membrane embedded with MOF-808

RSC Adv., 2024, 14,12142-12146
DOI: 10.1039/D3RA08682H, Paper
Open Access
Xiao-Jing Hu, Yu-Lin Li, Hai-Xiong Liu, Shao-Ming Ying, Qi Yin, Tian-Fu Liu
Based on the excellent diclofenac sodium (DCF) removal capacity of MOF-808, a free-standing mixed-matrix membrane composed of polyacrylonitrile and MOF-808 was fabricated and used to remove DCF from water via an easily accessible filtration method.
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Kinetic and reactivity of gas-phase reaction of acyclic dienes with hydroxyl radical in the 273–318 K temperature range

RSC Adv., 2024, 14,12303-12312
DOI: 10.1039/D3RA08750F, Paper
Open Access
Chenyang Xue, Xinmiao Xu, Han Lyu, Yunfeng Li, Yangang Ren, Jinhe Wang, Yujing Mu, Abdelwahid Mellouki, Zongzheng Yang
The relative position of two CC on the acyclic dienes could determine its reactivity. The number and type of alkyl group and the number of addition sites on diene could also strongly affect its reactivity toward OH radical.
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Progress of research on the bonding-strength improvement of two-layer adhesive-free flexible copper-clad laminates

RSC Adv., 2024, 14,12372-12385
DOI: 10.1039/D4RA01408A, Review Article
Open Access
Wanqi Tang, Yuxi Liu, Xianghai Jing, Jinsong Hou, Qianfeng Zhang, Chongguang Jian
Bond strength of two-layer adhesive-free flexible copper-clad laminate is an important factor that directly affects the stability and reliability of electronic devices.
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Correction: 2-cyanopyridine derivatives enable N-terminal cysteine bioconjugation and peptide bond cleavage of glutathione under aqueous and mild conditions

RSC Adv., 2024, 14,12416-12416
DOI: 10.1039/D4RA90039A, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tetsuya Yano, Takahiro Yamada, Hiroaki Ishida, Nami Ohashi, Toshimasa Itoh
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Synergistic effects of β-NaFeO2 ferrite nanoparticles for photocatalytic degradation, antibacterial, and antioxidant applications

RSC Adv., 2024, 14,12513-12527
DOI: 10.1039/D4RA02430C, Paper
Open Access
Tahira Jabeen, Muhammad Shahid Khan, Sana Javaid, Waqar Azeem, Rabia Ayoub, Martin Motola
Detailed antibacterial mechanism using by synthesized β-NaFeO2.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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Insight into the probability of ethoxy(pentafluoro)cyclotriphosphazene (PFPN) as the functional electrolyte additive in lithium–sulfur batteries

RSC Adv., 2024, 14,12754-12761
DOI: 10.1039/D3RA08379A, Paper
Open Access
Ning Li, Yu Zhang, Shun Zhang, Lu Shi, Jie-Yu Zhang, Ke-Meng Song, Jin-Chun Li, Fang-Lei Zeng
Enhancing the flame retardancy of electrolytes and the stability of lithium anodes is of great significance to improve the safety performance of lithium–sulfur (Li–S) batteries.
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Innovative surfactant-free synthesis of core–shell SiO2/ZnO particles: rapid ultrasonication and photocatalytic inhibition

RSC Adv., 2024, 14,12665-12675
DOI: 10.1039/D4RA01309C, Paper
Open Access
Lailatul Qomariyah, Tomoyuki Hirano, Nicky Rahmana Putra, Suprapto Suprapto, Hendrix Abdul Ajiz, Mar'atul Fauziyah
This study demonstrates the preparation of SiO2/ZnO core–shell nanoparticles with controllable shell size and their optical properties.
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Construction of glutathione-responsive paclitaxel prodrug nanoparticles for image-guided targeted delivery and breast cancer therapy

RSC Adv., 2024, 14,12796-12806
DOI: 10.1039/D4RA00610K, Paper
Open Access
Weiwei Ma, Qiufeng Zhao, Shilong Zhu, Xinyue Wang, Chuangchuang Zhang, Daming Ma, Na Li, Yanyan Yin
HA-coated redox sensitive visualized nano-prodrug HA/TPE-CS-SS-PTX were exploited in order to highly efficient treatment of cancer and real-time monitoring of drug localization.
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Scalable slot-die coated flexible supercapacitors from upcycled PET face shields

RSC Adv., 2024, 14,12781-12795
DOI: 10.1039/D2RA06809E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kiran Kumar Reddy Reddygunta, Andrew Callander, Lidija Šiller, Karen Faulds, Leonard Berlouis, Aruna Ivaturi
This study reports fabrication of flexible supercapacitor with slot-die coated activated carbon electrodes derived from upcycled PET face shield, displaying excellent energy and power density of 21.8 W h kg−1 and 20 600 W kg−1 with good flexibility.
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Nickel-catalyzed γ-alkylation of cyclopropyl ketones with unactivated primary alkyl chlorides: balancing reactivity and selectivity via halide exchange

RSC Adv., 2024, 14,12883-12887
DOI: 10.1039/D4RA02616K, Paper
Open Access
Zheng-Ying Wang, Shi-Zheng Liu, Cong Guo, Yi-Zheng Cheng, Qiang Li, Jianmin Dou, Dacheng Li
Nickel-catalyzed cross-electrophile coupling of cyclopropyl ketones and alkyl chlorides. High reactivity and selectivity can be achieved with sodium iodide as a cocatalyst that generates a low concentration of alkyl iodide via halide exchange.
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Superhydrophobic foam combined with biomass-derived TENG based on upcycled coconut husk for efficient oil–water separation

RSC Adv., 2024, 14,13005-13015
DOI: 10.1039/D4RA01841A, Paper
Open Access
Jiaming Liang, Yajuan Zhou, Qian Wu, Zeying Zhu, Keda Lin, Jinsheng He, Haihe Hong, Yuanzheng Luo
Ocean ecological environments are seriously affected by oil spilling and plastic-debris, significantly reducing marine pollution via using biocomposite production from natural fiber reinforcement is a friendly way to deal with marine oil pollution.
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Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(III/II/III) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study

RSC Adv., 2024, 14,13200-13208
DOI: 10.1039/D3RA07697K, Paper
Open Access
Sovana Maity, Sudip Bhunia, Michael G. B. Drew, Rosa M. Gomila, Antonio Frontera, Shouvik Chattopadhyay
Formation of hydrogen bonding network in a trinuclear linear mixed-valence centrosymmetric cobalt(III)–cobalt(II)–cobalt(III) complex has been analyzed using DFT calculations.
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Dispersive micro solid phase extraction of glibenclamide from plasma, urine, and wastewater using a magnetic molecularly imprinted polymer followed by its determination by a high-performance liquid chromatography-photodiode array detector

RSC Adv., 2024, 14,13168-13179
DOI: 10.1039/D4RA00452C, Paper
Open Access
Najmeh Sabbaghi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani, Majid Farsadrooh
The present study describes the development of a simple and selective analytical method for dispersive micro solid phase extraction and determination of glibenclamide (GLB) using magnetic molecularly imprinted polymer (MMIP) as a sorbent.
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Bishydrazone ligand and its Zn-complex: synthesis, characterization and estimation of scalability inhibition mitigation effectiveness for API 5L X70 carbon steel in 3.5% NaCl solutions

RSC Adv., 2024, 14,13258-13276
DOI: 10.1039/D4RA00404C, Paper
Open Access
Ola. A. El-Gammal, Dina A. Saad, Marwa N. El-Nahass, Kamal Shalabi, Yasser M. Abdallah
Zn-complex: characterization and estimation of scalability inhibition mitigation effectiveness for API 5L X70 carbon steel in 3.5% NaCl solutions.
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Two-state nanocomposite based on symmetric diblock copolymer and planar nanoparticles: mesoscopic simulation

Mol. Syst. Des. Eng., 2024, 9,409-422
DOI: 10.1039/D3ME00176H, Paper
Maxim Malyshev, Daria Guseva, Pavel Komarov
A method for controlling the distribution and orientation of 2D fillers in the copolymer matrix is presented.
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When ‘Uncle Godhri’ comes calling

A retired school teacher brings colour and comfort to hospital patients by stitching blankets for them




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A true digital revolution or ‘exclusion through technology’?

Lack of smartphones and poor connectivity have severely cramped internet outreach in Manipur during the ongoing pandemic




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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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[Ru]-Catalyzed Olefin Metathesis and Ethenolysis for the Synthesis and Recycling of Bio-Based Polycarbonates and Polycyanurates

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00940A, Paper
Dana M. Pinson, Francesca D. Eckstrom, Gregory S. Ostrom, K. Randall McClain, Lawrence Baldwin, Benjamin Grant Harvey
Eugenol, an abundant, naturally occurring phenolic compound, was converted into a thermoplastic polycarbonate by olefin metathesis followed by interfacial polymerization with triphosghene. This resulted in polymers with Mn ranging from...
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Star Copolymers with Tunable Clusteroluminescence

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01198H, Communication
Zixuan Zhou, Xiang Chen, Yang Wang, Ting Li, Xuhui Zhang, Bihua Xia, Shibo Wang, Weifu Dong, Jinliang Qiao
Clusteroluminescence (CL) has recently drawn more attention due to its unique photophysical behaviors that differ from traditional conjugated luminogens. However, the design of red emission from such systems is still...
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Strategies to prepare polymers with cleavable linkages releasing active agents in acidic media

Polym. Chem., 2024, 15,4491-4518
DOI: 10.1039/D4PY00854E, Review Article
Nachnicha Kongkatigumjorn, Daniel Crespy
Hydrolysis stability of labile linkages in polymers can be tuned through careful selection of substituent groups near these linkages to selectively release active substances.
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Catalytic copolymerization of carbon dioxide and cyclohexene oxide by a trinuclear cyclohexane-bridged tetradentate Schiff base chromium complex

Polym. Chem., 2024, 15,4519-4528
DOI: 10.1039/D4PY00956H, Paper
Jie Huang, Boxiong Shen
The development of catalytic systems is a central area of research in carbon dioxide (CO2) and epoxy copolymerization.
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RSC - Photochem. Photobiol. Sci. latest articles




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Combined and rapid detection of anti-Brucella IgG/IgM in clinical samples based on surface-enhanced Raman scattering-lateral flow immunochromatography

J. Mater. Chem. B, 2024, 12,11012-11024
DOI: 10.1039/D4TB01367K, Paper
Yongwei Zhang, Ziyue Li, Aolin Zhu, Qian Zhang, Hao Zhou, Xuelei Zhou, Tingwei Liu, Chunyan Liu, Hefei Zha, Xin Zhang, Hui Zhao, Jiutong Li, Guodong Lü, Xinxia Li
Brucellosis is a bacterial infectious disease caused mainly by Brucella. Transmission is mainly by contact with infected domestic or wild animals or their excreta.
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Mercaptoimidazole-capped gold nanoparticles as a potent agent against plant pathogenic fungi

J. Mater. Chem. B, 2024, 12,10949-10961
DOI: 10.1039/D4TB01032A, Paper
Open Access
Tang Xu, Wenshuai Hao, Ran Du, Dai Dai, Cuixia Wang, Suhua Li, Carol Sze Ki Lin, Ruitao Cha, Jianbin Yan, Chong Li
The first evidence that MI-Au NPs prevent plants from fungal infection is presented.
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Bioinspired nanovesicles derived from macrophage accelerate wound healing by promoting angiogenesis and collagen deposition

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D3TB02158K, Paper
Tingrui Zhang, Zongguang Tai, Fengze Miao, Yingchao Zhao, Weifan Wang, Quangang Zhu, Zhongjian Chen
We prepared bioinspired nanovesicles by gradient extrusion to replace exosomes for wound healing. The nanovesicles have potential for transformation.
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Efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01987C, Paper
Wan Huang, Song Zhang, Li Luo, Yalong Pan, Lijun Han, Yao Yu
Novel efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy.
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