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A peek at Kokūn’s zero-waste, naturally-dyed apparel

Zero-waste apparel dyed with home-grown rhubarb and madder is the forte of Mridu Mehra Tiwari’s brand Kokūn, which just launched its Spring collection and a men’s range




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An efficient approach to AviCys analogues via regio- and stereoselective hydrosulfuration of ynamides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01572J, Research Article
Zhenjia Zhang, Zhe Ding, Jinhua Yang, Yongli Zhao, Zhenguang Zhao, Can Liu, Norman Metanis, Junfeng Zhao
A novel synthetic strategy for the construction of AviCys analogues via a highly efficient regio- and stereoselective hydrosulfuration of ynamides was reported.
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Shaping cycles with light: a regiodivergent approach to tetracyclic aza-aromatic compounds

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01606H, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Clara Mañas, Belén Ibarra, Estíbaliz Merino
We present a novel visible light-promoted regiodivergent cyclization, enabling the selective synthesis of distinct azapolyaromatic regioisomers from 2-alkynlazobenzenes.
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General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01698J, Research Article
Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen Xu
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
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Total synthesis of spiro Ganoderma meroterpenoids spiroapplanatumines B, D, F, and H

Org. Chem. Front., 2024, 11,6333-6339
DOI: 10.1039/D4QO01147C, Research Article
Jia-Hao Zhang, Wen-Cai Luo, Wen-Tao Chen, Yu-Tao He, Ya-Jian Hu
The first total synthesis of spiroapplanatumines B, D, F, and H as well as the possibly undiscovered natural product spiroapplanatumine R has been achieved.
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Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives

Org. Chem. Front., 2024, 11,6380-6384
DOI: 10.1039/D4QO01329H, Research Article
Hang Luo, Fangnian Yu, Luqing Lin
The photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.
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Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives

Org. Chem. Front., 2024, 11,6319-6326
DOI: 10.1039/D4QO01368A, Research Article
Yu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming Wang
A variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.
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Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes

Org. Chem. Front., 2024, 11,6470-6476
DOI: 10.1039/D4QO01532K, Research Article
Xiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu Li
A novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.
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Electrochemical approach for upgrading the pollutant CS2: three-component N–H thiocarbamylation of sulfoximines

Org. Chem. Front., 2024, 11,6477-6482
DOI: 10.1039/D4QO01310G, Research Article
Peng Qian, Wenjing Xiong, Qian Meng, Jinxiu Liu, Xiyuan Li, Liangquan Sheng
We report an electrochemical approach for upgrading the pollutant CS2via the thiocarbamylation of sulfoximines, in which CS2 and amines are incorporated as a readily available source of dithiocarbamate.
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Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01844C, Research Article
Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
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Copper(II)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01560F, Research Article
Hong Xu, Jie Liao, Fei Ren, Chuan-Rong Zhou, Xiao-Zhuo Liu, Yao Xiao, Dong-Wei Hang, Fuyu Li, Bei Wang, Ji-Yu Wang
Through crucial selective radical tandem process and intramolecular nucleophilic addition, a facile copper-catalyzed four-component cascade has been realized to selectively construct novel sulfonyl-functionalized quinone-fused cyclopenta[b]indole.
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Thiocyanoalkylation of Alkenes via Dual Photoredox and Copper Catalysis

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01864H, Research Article
Xu Wang, Bi-Yin Xiao, Qi-Xuan Jiang, Wei Huang, Feng-Hua Zhang
Organic thiocyanates are commonly used as an essential organic synthesis intermediate and widely present in various drug molecules and bioactive molecules. Herein, a copper and photoredox catalyzed thiocyanoalkylation reaction of...
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Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01832J, Research Article
Open Access
Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh Hariharan
Achieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...
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Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01828A, Review Article
Kazutaka Shoyama, Frank Wuerthner
Polycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...
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π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01592D, Research Article
Bin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao He
The development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...
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Man arrested for kidnapping, marrying, sexually assaulting minor




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Apprehensions aplenty in Hyderabad about caste survey

Many residents refuse to share details, with some regarding questions too intrusive and some wary about data privacy and identity of enumerators in the backdrop of rising scams; officials face public ire over unfulfilled government promises and outcome of ‘Praja Palana’ applications




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Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana




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Nodal officers appointed for the caste survey in Greater Hyderabad




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People’s committee slams BJP, BRS for ‘opposing’ caste survey in Telangana




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Can skipper Rohit find inspiration to ‘pull’ his side out of the numbing depths?

India has been in similar situations in the past and found a way to bounce back in style. Nothing will motivate the skipper more than the prospect of a statement-making performance down under, especially with qualification for the final of the World Test Championship now hanging by a slender thread




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Ageing Kohli, Rohit must rekindle youthful mindset to rediscover lost glory: Greg Chappell

According to Chappell, the ageing Sharma and Kohli must summon the same drive and focus that once marked their prime years if India hopes to reclaim its form on foreign soil




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Latest scholarship opportunities




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Approaching the IAS Main Exam

Like other competitive exams, this too requires careful preparation.




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Latest Internship opportunities




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Latest internship opportunities




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Latest internship opportunities




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Latest scholarship opportunities




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‘Opportunities still exist in the software sector’




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Latest internship opportunities




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Latest internship opportunities




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Latest internship opportunities




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Latest internship opportunities




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Latest internship opportunities




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Latest internship opportunities




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Latest internship opportunities




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Tiruppugazh scholar’s new book



  • History & Culture

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Cash-strapped Archaeology Department takes MGNREGA route for upkeep of monuments in Karnataka

The proposed initiative will cover the protected and unprotected sites in Karnataka, most of which lack even a fence, so as to prevent encroachment




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Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
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Probing intrinsic defects of aluminium-doped CuO thin films for solar cell applications

RSC Adv., 2024, 14,35184-35197
DOI: 10.1039/D4RA06413E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Adithya Prakash, Vikash Mishra, Mahesha M. G.
Defect-engineered Al-doped CuO thin films deposited via chemical spray pyrolysis find application in solar cell absorbers.
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Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications

RSC Adv., 2024, 14,35490-35497
DOI: 10.1039/D4RA06404F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lili Xie, Haiyan Qiu, Yuxin Chen, Yingxue Lu, Yanyan Chen, Lanlan Chen, Shanwen Hu
A zero-dimensional halide perovskite in micron scale is constructed to gain a deeper understanding of phase transformation mechanism and better fluorescence applications.
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Investigation and development of novel synthetic approaches for synthesis of euxanthone and derived dyes

RSC Adv., 2024, 14,35601-35609
DOI: 10.1039/D4RA06475E, Paper
Open Access
M. Mustafa Cetin
This work explores new synthetic methods for euxanthone and its derived dye Indian yellow through euxanthic acid formation, confirming structures with analytical techniques and proposing a mechanism for the euxanthone synthesis.
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A dual-response fluorescence sensor for SO2 derivatives and polarity and its application in real water and food samples

RSC Adv., 2024, 14,35638-35643
DOI: 10.1039/D4RA04805A, Paper
Open Access
Jianfeng Wang, Ruiji Li, Tao Ou, Yamin Fu, Chang Gao, Yehao Yan
A dual-response fluorescent probe for SO2 derivatives and polarity and their application in real samples.
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An efficient extraction device for microplastics in marine sediments and its applications

RSC Adv., 2024, 14,35610-35617
DOI: 10.1039/D4RA04347B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wang Jiahan, Liu Xiaowei, Yang Feng, Yang Xiujiu, Jiao Wenguang, Tang Kai, Wang Jinli, Chen Yan
Microplastics, defined as small pieces of plastic with a size less than 5 millimeters, constitute a significant sink for microplastics in marine sediments.
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Retraction: Fabrication of novel quantum dots for the estimation of COVID-19 antiviral drug using green chemistry: application to real human plasma

RSC Adv., 2024, 14,35696-35696
DOI: 10.1039/D4RA90133A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Baher I. Salman, Adel Ehab Ibrahim, Sami El Deeb, Roshdy E. Saraya
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