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Realty sector rises 63%, outshining Nifty50; more firms eye IPOs

The sector is attracting new entrants via record IPOs, with seven listings raising ₹13,550 crore in 2024, showing strong investor interest in this thriving market.




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Threads of partnership

Friends and collaborators Bina Rao and Villoo Mirza are bound by their passion for handlooms




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Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01638F, Research Article
Aijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei Ding
A highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.
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Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01848F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tobias B. Tischer, Zulema Fernandez, Lorenz Borsdorf, Constantin Daniliuc, Shigehiro Yamaguchi, Soichiro Ogi, Gustavo Fernandez
Supramolecular polymers are often investigated for highly symmetric and planar molecules, such as typically explored BF2-substituted BODIPY dyes . However, it is surprising that the possibility of desymmetrizing the sp3...
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Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects

Org. Chem. Front., 2024, 11,6393-6410
DOI: 10.1039/D4QO01451K, Research Article
Jiaoyang Liu, Li-juan Huang, Zeang Sun, Juan Li
DFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.
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Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes

Org. Chem. Front., 2024, 11,6470-6476
DOI: 10.1039/D4QO01532K, Research Article
Xiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu Li
A novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.
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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
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Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00984C, Research Article
Guolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming Ma
Chiral diphenylprolinol silyl ethers have been successfully identified for the enantioselective allenation reaction of terminal alkynes and 2-alkynals, delivering a diverse set of chiral allenynes with high efficiency.
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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
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Influence of hydrogen bonds and π-π stacking on the self-assembly of aryldipyrrolidones

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01577K, Research Article
Open Access
Pedro Ximenis, Llorenç Rubert, Heike Ehmann, Bartolome Soberats
We report on the self-assembly behaviour in solution and solid-state of two newly designed bisdendronized aryldipyrrolidones (BDP and NDP) dyes with two free N-H at the lactam positions. Interestingly, while...
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Ind vs NZ 3rd Test: New Zealand scripts history as India suffers Test series whitewash

No team had been able to win all the Test matches in India in a series featuring three or more Test matches in nine decades.




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World Test Championship standing: India loses top spot to Australia, slips to second

India lost to New Zealand by 25 runs in the third and final Test in Mumbai resutling in a 0-3 whitewash, their first in a home Test series since South Africa's 2-0 win in 1999-2000




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IPL auction set to be held in Riyadh at end of November

This year's auction is a mega one with high profile India stars like Rishabh Pant, KL Rahul, Shreyas Iyer and Arshdeep Singh are going to go under the hammer




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Can skipper Rohit find inspiration to ‘pull’ his side out of the numbing depths?

India has been in similar situations in the past and found a way to bounce back in style. Nothing will motivate the skipper more than the prospect of a statement-making performance down under, especially with qualification for the final of the World Test Championship now hanging by a slender thread




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IPL mega auction to be held in Jeddah in Saudi Arabia on November 24, 25: BCCI

The player registration officially closed and a total of 1,574 cricketers (1,165 Indian and 409 overseas) have been signed up for the auction




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Ben Stokes missing from IPL’s list of 1,574 players ahead of mega auction

IPL mega auction list includes marquee Indian players like Pant, Iyer, and Rahul, with a total purse of ₹120 crore




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James Anderson wants to grow his 'knowledge of the game' through IPL

In a surprising move, James Anderson, who last played a T20 match in 2014 and never played a match in the IPL, registered himself for the auction




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Ranji Trophy | Shreyas and Lad’s regal partnership takes reigning champion to mammoth score

The duo’s 354-run stand for the fourth wicket helps Mumbai declare its first innings at 602 for four before dismissing five Odisha batters for 146 at the end of day two




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Make the most of internships

Competitive edge, high stipends and exposure… lucrative opportunities abound for students.




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EMBO membership for Indian scientist




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Udayavar’s management principles

It was Sri Ramanuja who laid out plans for carrying out temple rituals at Srirangam, Tirumala and Melkote



  • History & Culture

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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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Macroporous chitosan/alginate hydrogels crosslinked with genipin accumulate and retain glioblastoma cancer cells

RSC Adv., 2024, 14,35286-35304
DOI: 10.1039/D4RA06197G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lauriane Parès, Sahar Naasri, Lisa Delattre, Hélène Therriault, Benoît Liberelle, Gregory De Crescenzo, Marc-Antoine Lauzon, Nathalie Faucheux, Benoit Paquette, Nick Virgilio
This work demonstrates how macroporous hydrogels can be prepared with porous polylactide molds, and homogeneous solutions of sodium alginate and chitosan crosslinked with genipin, in order to accumulate glioblastoma cancer cells.
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Synthesis and antiproliferative activity of 2-oxo-3-phenylquinoxaline derivatives and related compounds against colon cancer

RSC Adv., 2024, 14,35679-35695
DOI: 10.1039/D4RA06822J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. S. Gomaa, Abdulghany H. A. Ahmed, S. M. El Rayes, Ibrahim A. I. Ali, Walid Fathalla, Mansour S. Alturki, Abdulaziz Hassan Al Khzem, Atiah H. Almalki, Mohammed F. Aldawsari, F. H. Pottoo, Firdos A. Khan, Mohd Amir
The impact of compound 7j on colon cancer cells (HCT-116). Fig. (A) shows the control cells Fig. (B) shows the treatment cells. The arrows show chromatin condensation, nuclear augmentation, and formation of apoptotic bodies.
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Piezoresistivity and strain-sensing behaviour of poly(butylene adipate-co-terephthalate)/multiwalled carbon nanotube nanocomposites

RSC Adv., 2024, 14,35715-35726
DOI: 10.1039/D4RA04826A, Paper
Open Access
Kedar Nath Dhakal, Ralf Lach, Wolfgang Grellmann, Beate Krause, Jürgen Pionteck, Rameshwar Adhikari
The interconnectedness of the exfoliated multi-walled carbon nanotubes well dispersed in the PBAT matrix (TEM image; left) leads to strain-sensing properties at lower strains as illustrated by the variation of ΔR/R0 as a function of mechanical strain with time (right).
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Retraction: Highly sensitive cadmium sulphide quantum dots as a fluorescent probe for estimation of doripenem in real human plasma: application to pharmacokinetic study

RSC Adv., 2024, 14,35992-35992
DOI: 10.1039/D4RA90134G, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marwa F. B. Ali, Baher I. Salman, Samiha A. Hussein, Mostafa A. Marzouq
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A facile synthesis of iron oxide nanoparticles as a nano-sensor to detect levofloxacin and ciprofloxacin in human blood and evaluation of their biological activities

RSC Adv., 2024, 14,36093-36100
DOI: 10.1039/D4RA05024J, Paper
Open Access
Erum Hasan, Ziana Manzar, Nabeel Haroon, Ali Raza, Syed Nawazish Ali, Mehreen Lateef, Sabira Begum
New bioactive magnetic nanoparticles were synthesized and stabilized by 3-aminobenzoic acid (3-ABA) utilized in detection of levofloxacin and ciprofloxacin.
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Agnipath at political centre stage as Haryana assents to Agniveer Policy

Policy offers employment and entrepreneurship opportunities post-service, with several exceptions in norms




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Assam group opposes Meghalaya ban on cave worship, threatens road blockade

Meghalaya’s Tourism Minister justifies a ban by the local village council as a move against promoting a tourist spot as a religious site