ph Improved charge carrier mobility in a copper oxide heterostructure enhances the photocatalytic partial oxidation of benzyl alcohol to benzaldehyde By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Advance ArticleDOI: 10.1039/D4CY00889H, PaperHanggara Sudrajat, Dmytro Lisovytskiy, Juan Carlos ColmenaresThe enhancement of the partial oxidation of an aromatic alcohol to its corresponding aldehyde through the coupling of Cu2O with CuO is comprehensively discussed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Ag co-catalyst prepared by ultrasonic reduction method for efficient photocatalytic conversion of CO2 with H2O using ZnTa2O6 photocatalyst By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6207-6214DOI: 10.1039/D4CY00564C, PaperKio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro TeramuraTowards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO2 with H2O—known as artificial photosynthesis—is important.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6411-6419DOI: 10.1039/D4CY00808A, PaperManish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. GhoraiA metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Single-step in situ synthesis of bimetallic catalysts via a gas-phase route: the case of PdZn–ZnO By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6321-6330DOI: 10.1039/D4CY00807C, PaperAndrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica StankicIn this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Multiscale modelling of CO2 hydrogenation of TiO2-supported Ni8 clusters: on the influence of anatase and rutile polymorphs By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6393-6410DOI: 10.1039/D4CY00586D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. FilotThe selection of TiO2 phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO2 hydrogenation to methane.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6176-6179DOI: 10.1039/D4CY00955J, CommunicationZhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei LuVisible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Synthesis of Co3O4 catalysts with different morphologies and their excellent catalytic performance for soot combustion By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Advance ArticleDOI: 10.1039/D4CY01115E, PaperXinyu Zhang, Chunlei Zhang, Siyu Gao, Xinyu Chen, Siyuan Chen, Shengran Zhou, Di Yu, Lanyi Wang, Xiaoqiang Fan, Xuehua Yu, Zhen ZhaoA series of Co3O4 catalysts with different morphologies were prepared by a hydrothermal method. Among them, the sea urchin shaped Co3O4 catalyst exhibits the best catalytic performance for soot combustion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Green Photocatalytic N-Debenzylations with Molecular Oxygen Catalyzed by Recyclable Metal-free Tubular Carbon Nitride By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Accepted ManuscriptDOI: 10.1039/D4CY00981A, PaperYufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei MengDebenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Innovations in nanocomposite photocatalysts for CO2 to CH3OH conversion By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6443-6465DOI: 10.1039/D4CY00822G, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shuang Deng, Nannan Wang, Yanqiu Zhu, Kunyapat ThummavichaiNowadays, the excessive use of fossil fuels has led to a global energy shortage and exacerbated the greenhouse effect.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph 1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6573-6583DOI: 10.1039/D4CY00969J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-OchoaThe study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6561-6572DOI: 10.1039/D4CY00888J, PaperYan Wang, Chengkai Luo, Li Wei, Mingzhong CaiHeterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6670-6677DOI: 10.1039/D4CY00949E, PaperChandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook BaegFacile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Broadening the substrate range of serine palmitoyltransferase by protein engineering and applications to 3-keto-dihydrosphingosine analogs By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6600-6608DOI: 10.1039/D4CY01019A, PaperHyunjun Choe, Minsun Cha, Ahram Kim, Jon D. StewartIntroducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Photocatalytic H2O2 production with perylene(bis-imide)-doped periodic mesoporous silica using micropollutants as sacrificial donors By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6710-6719DOI: 10.1039/D4CY00739E, PaperCharlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann PellegrinA perylene-doped mesoporous silica material is used as a photocatalyst to produce H2O2 from aerated polluted water samples under light soaking.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Dual defect sites at g-C3N4 synergistically induce the electron localization effect for boosting photocatalytic H2O2 production By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6701-6709DOI: 10.1039/D4CY01101E, PaperJingjing Jiang, Yuyao Chen, Shijian Zhou, Haoran Xie, Changlai Li, Zheng Wei, Yan KongDefect engineering (such as doping of non-metallic elements or vacancies) is a universally effective modification to improve the electronic structure and physical properties of g-C3N4, which has been widely applied in various photocatalytic systems.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6621-6640DOI: 10.1039/D4CY00930D, PaperBin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen HuangAs a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Enhancing light-driven photocatalytic reactions through solid solutions of bismuth oxyhalide/bismuth rich photocatalysts: a systematic review By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6466-6495DOI: 10.1039/D4CY00820K, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. MsagatiThe pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Correction: 1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6720-6720DOI: 10.1039/D4CY90084G, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-OchoaThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Elucidation of Ce/Zr ratio effects on the physical properties and catalytic performance of CuOx/CeyZr1−yO2 catalysts By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Advance ArticleDOI: 10.1039/D4CY01012D, PaperMohammed Sifat, Michal Luchowski, Amol Pophali, Wenhui Jiang, Yunfan Lu, Byeongseok Kim, Gihan Kwon, Kwangsuk Yoon, Jihun Kim, Kwangjin An, Sang Eun Shim, Hocheol Song, Taejin KimAlthough cerium oxide (CeO2) is widely used as a catalyst support, its limited defect sites and surface oxygen vacancy/mobility should be improved.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Phenol Hydroxyl-Modified Imine-Based Covalent organic framework for enhanced solar-driven generation of H2O2 via Hydrogen Bonds By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Accepted ManuscriptDOI: 10.1039/D4CY01096E, PaperLang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia ChuanqinPhotosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Deciphering the role of chemisorbed CO in CO2 methanation: kinetic and mechanistic investigation over monometallic (Ru) and bimetallic (Ru–Ni) catalysts By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Advance ArticleDOI: 10.1039/D4CY01004C, PaperPavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini DeviSupported metal catalysts have made prominent contributions to CO2 mitigation through conversion into useful chemicals.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Accepted ManuscriptDOI: 10.1039/D4CY01315H, CommunicationMarlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira BiszIron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Effect of graphene electrode functionalization on machine learning-aided single nucleotide classification By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20202-20215DOI: 10.1039/D4NR02274B, PaperMohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup PathakIn this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph BP/GaN and BP/GaP core/shell nanowires: theoretical insights into photovoltaic and gas-sensing abilities By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20235-20251DOI: 10.1039/D4NR02602K, PaperRishit S. Shukla, Vidit B. Zala, Sanjeev K. Gupta, P. N. GajjarBP/GaN and BP/GaP core/shell nanowires (CSNWs) show good sensitivity for some small oxide gases. Also, BP/GaP CSNWs show >33% photovoltaic conversion efficiency.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph An eco-friendly polycaprolactone/graphite composite as a robust freestanding electrode platform for supercapacitive energy storage By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20155-20167DOI: 10.1039/D4NR03113J, PaperRajeev Gupta, Monika SinghalA novel eco-friendly composite electrode/current collector made from polycaprolactone and graphite filler offers bulk conductivity, is freestanding, cost-effective, and shows supercapacitive energy storage potential with electrodeposited polyaniline.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111) By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20216-20227DOI: 10.1039/D4NR02935F, PaperHang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed NaitabdiThickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Size effect on the structural and magnetic phase transformations of iron nanoparticles By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20304-20311DOI: 10.1039/D4NR02488E, PaperAlexis Front, Georg Daniel Förster, Chu Chun Fu, Cyrille Barreteau, Hakim Amara(a) Magnetic (top) and structural (bottom) phase transformation of an iron nanoparticle. (b) Size dependence on magnetic and structural transition temperatures on iron nanoparticles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Ni,S co-doped Cu dendrites decorated with core–shell architecture assisted by MOF and Fe0.92Co0.08S nanoflakes on nanocellulose/graphene fibers for fabrication of flexible wire-type micro-supercapacitor By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20260-20279DOI: 10.1039/D4NR02283A, PaperLeila Naderi, Saeed ShahrokhianA flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Preparation and application of high thermal conductivity phase change microcapsules with fluorescence characteristics based on a ZnWO4 shell By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20331-20341DOI: 10.1039/D4NR02691H, PaperH. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. LuThis method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph A negative photoconductivity photodetector based on two-dimensional Nb3Cl8 By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20312-20318DOI: 10.1039/D4NR03376K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bom Lee, Xiaojie Zhang, Jinsu Kang, Byung Joo Jeong, Sooheon Cho, Kyung Hwan Choi, Jiho Jeon, Sang Hoon Lee, Dahoon Kim, Yeong Hyeop Kim, Ji-Hee Kim, Hak Ki Yu, Jae-Young ChoiWe developed a Nb3Cl8-based photodetector with negative photoconductivity from 400 to 1050 nm, featuring high electron mobility, a strong Ion/Ioff ratio, and high responsivity, making it ideal for energy-efficient optoelectronic applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Magnetic dimeric metal–porphyrin rings mechanically bonded around carbon nanotubes: the role of nanotube defects modulating magnetic properties By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20342-20353DOI: 10.1039/D4NR02984D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rocío Sánchez-de-Armas, Nicolás Montenegro-Pohlhammer, Emilio M. Pérez, Enrique Burzurí, Carmen J. CalzadoA DFT study of mechanically bonded magnetic Co2+ and Cu2+ dimeric metal–porphyrin rings around carbon nanotubes (mMINTs) points to defcts in the NT as responsible for the different dimer–nanotube interactions and the loss of the Co2+ EPR signal.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Photomanipulatable colloidal clusters from the aggregation of azo molecular glass spheres By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20060-20066DOI: 10.1039/D4NR03618B, CommunicationBo Tang, Lier Wang, Xitong Ai, Chuyi Liao, Zhiyuan Xiong, Yaning He, Xiaogong WangControllable fabrication of photoresponsive colloidal clusters with a wide range of adjustable sizes and complex architectures are fabricated through the aggregation, fusion and photoinduced deformation of azo colloidal spheres.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Dual metal centers within a water-stable Co/Ni bimetallic metal-triazolate framework contribute to durable photocatalysis for water treatment By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20082-20088DOI: 10.1039/D4NR03940H, CommunicationMinling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming HuangA bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Modulating the photodynamic modality of Au22 nanoclusters through surface conjugation of arginine for promoted healing of bacteria-infected wounds By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20089-20099DOI: 10.1039/D4NR03278K, PaperXinyue Dou, Sariah Saalah, Chel-Ken Chiam, Jianping Xie, Coswald Stephen SipautAn Au nanocluster (NC)-based photodynamic antibacterial is designed by conjugating arginine on the surface of Au22 NCs, achieving healing of bacteria-infected wounds via producing reactive oxygen species (ROS) and reactive nitrogen species (RNS).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Correction: Ce6-Conjugated and polydopamine-coated gold nanostars with enhanced photoacoustic imaging and photothermal/photodynamic therapy to inhibit lung metastasis of breast cancer By pubs.rsc.org Published On :: Nanoscale, 2024, 16,20354-20355DOI: 10.1039/D4NR90194K, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ziwei Li, Fan Yang, Di Wu, Yanhong Liu, Yang Gao, Haichen Lian, Hongxin Zhang, Zhibin Yin, Aiguo Wu, Leyong ZengThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Glycosylated AIE-active Fe (III) photosensitizer activated by tumor microenvironment for synergistic type I photodynamic and chemodynamic therapy By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03871A, PaperGai-li Feng, Wei Zhou, Jinping Qiao, Guang-Jian Liu, Guo-Wen XingPhotodynamic therapy (PDT) and chemodynamic therapy (CDT) are both promising cancer treatments to inhibit tumor cells by generating highly cytotoxic reactive oxygen species (ROS). Herein, we report a novel tumor...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Cr2TiC2Tx MXene as an Adsorbent Material in Ultrasonic-Assisted d-µ-Solid Phase Extraction for Trace Detection of Heavy Metals By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR02556C, PaperSaman Bagheri, Rashmeet Kaur Khurana, Md. Ibrahim Kholil, Michael J. Loes, Shengyuan Luo, Alexander SinitskiiMXenes are a large family of two-dimensional transition metal carbides, nitrides, and carbonitrides. While MXenes have great potential for applications in analytical chemistry, most of the studies in this field...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Minimizing defect states through multidentate coordination and morphology regulation for enhancing the performance of inverted perovskite solar cells By pubs.rsc.org Published On :: Nanoscale, 2024, Advance ArticleDOI: 10.1039/D4NR03140G, PaperHimangshu Baishya, Mayur Jagdishbhai Patel, Ramkrishna Das Adhikari, Deepak Yadav, Parameswar Krishnan IyerThe interaction between CO and Pb2+ regulated grain growth, enhanced crystallinity that effectively passivated non-radiative recombination centres and CF3 group stabilizes the perovskite structure by interacting with FA and Pb cationic defects.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Oxygen electrode catalysis in N-doped graphene: the role of nitrogen coordination and solvation effects By pubs.rsc.org Published On :: Nanoscale, 2024, Advance ArticleDOI: 10.1039/D4NR03645J, PaperJunxian Liu, Yun Wang, Yuantong Gu, Liangzhi KouThe significance of explicit solvents in describing the adsorption behaviors of ORR/OER intermediates is emphasized. A higher HOMO level of active sites enhances binding to oxygen intermediates, thereby improving ORR/OER activity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Controlling TiO2 photocatalytic behaviour via perhydropolysilazane-derived SiO2 ultrathin shell By pubs.rsc.org Published On :: Nanoscale, 2024, Advance ArticleDOI: 10.1039/D4NR03566F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Darya Burak, Jae Hyun Han, Joon Soo Han, In Soo Kim, Md Abdur Rahman, Joel K. W. Yang, So-Hye ChoPHPS was transformed via TiO2 photocatalytic properties into ultrathin SiO2 shells, passivating TiO2 activity while retaining its whiteness and high refractive index—perfect for cosmetics, paints, and optical coatings.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Ab-initio Calculations of Vibrational Fingerprints in the Photoluminescence of Graphene Quantum Dots By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR02458C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ruoyu Wu, Peng Han, Tobias Dittmann, Fu-He Wang, Yan Zhang, Gabriel BesterWe use a computational method based on ab initio (constrained) density functional theory to obtain the photoluminescence spectrum of graphene quantum dots with up to 240 carbon atoms, including the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Mixed phase Ti3+-rich TiO2 thin films by oxide defect engineered crystallization By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03545C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lauri Palmolahti, Harri Ali-Löytty, Markku Hannula, Tuomas Tinus, Kalle Lehtola, Antti Tukiainen, Jarno Reuna, Mika ValdenAmorphous TiO2 has insufficient chemical stability that can be enhanced with annealing induced crystallization. However, the crystalline structure is already predetermined by the defect composition of the amorphous phase. In...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Photoemission spectroscopy and microscopy for Ta@Si16 superatoms and their assembled layers By pubs.rsc.org Published On :: Nanoscale, 2024, Advance ArticleDOI: 10.1039/D4NR02778G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Masahiro Shibuta, Tsutomu Ohta, Toshiaki Kamoshida, Kana Yamagiwa, Hironori Tsunoyama, Tomoya Inoue, Tsugunosuke Masubuchi, Atsushi NakajimaAn alkaline-like Ta-encapsulating Si16 superatom film was fabricated on a C60 substrate. Charge transfer between Ta@Si16 and C60 lowers the work function. In the multilayer film, the central Ta atom's positive charge is compensated by the Si16 cage.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Preceramic polymer hybridized phenolic aerogels and the derived ZrC/SiC/C ceramic aerogels with ultrafine nanocrystallines By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03470H, PaperDing Nie, Hangyu Zhong, Hongli Hu, Zhenhua Luo, Boxing ZhangPhenolic and carbon aerogels have important applications for thermal insulation and ablative resistance materials in aerospace areas. However, their antioxidant ability in long-term and high-temperature aerobic environments is facing serious...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph pH controlled synthesis of end to end linked Au nanorod dimer in an aqueous solution for plasmon enhanced spectroscopic applications By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03235G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Satyajit Patra, Shubhangi Sharma, Théo Minchella, Susmita Pradhan, Davy Gerard, Quanbo JiangEnd-to-end linked nanorod dimer nanogap antennas exhibit superior plasmonic enhancement compared to monomers due to the coupling of localized surface plasmon resonances (LSPR) of individual nanorods. However, controlling the assembly...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Electrochemical chiral recognition of tryptophan enantiomers by using chiral polyaniline and β-CD-MOF By pubs.rsc.org Published On :: Nanoscale, 2024, Advance ArticleDOI: 10.1039/D4NR02854F, PaperJiamin Liang, Yuxin Song, Huan Xing, Liang Ma, Fengxia Wang, Mingfang Zhang, Hongli Zhang, Gang Zou, Guang YangA electrochemical sensor for the chiral recognition of Trp based on chiral polyaniline (D-PANI) and β-CD-MOF was designed. It displayed higher affinity of L-Trp, and the oxidation peak current ratio (IL/ID) of DPV could be reached at 2.26.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Conduction band photonic trapping via band gap reversal of brookite quantum dots using controlled graphitization for tuning a multi-exciton photoswitchable high-performance semiconductor By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03616F, PaperSanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha KhareThe photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Photo-Assisted Epitaxial Growth from Nanoparticles to Enhance Multi-Materialization for Advanced Surface Functionalization By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03112A, PaperMasayuki Fukuda, Yuuki Kitanaka, Tomohiko NakajimaTo meet the requirements of freeform objects, a wide range of highly designable resin-based materials has been created, highlighting the need for low-temperature ceramic deposition methods for surface functionalization. Photo-assisted...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Exploring Graphene's Impact on Graphite/PANI Matrix Composites: High-Press Fabrication and Enhanced Thermal-Electrical Properties By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03171G, PaperMurat OZLEK, Merve Sehnaz Akbulut, Engin BurgazThis study investigates the effects of graphene content and applied press on electrical and thermal conductivities of graphite/polyaniline (GP) and graphite/graphene/polyaniline (GGP) composites which were produced by using direct mixing...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Low Volume Shrinkage Alkaline Degradable UV Nanoimprint Lithography Resists Based on Acrylic Anhydride By pubs.rsc.org Published On :: Nanoscale, 2024, Accepted ManuscriptDOI: 10.1039/D4NR03291H, PaperChuan Zhe Zhao, Ya-Juan Cai, Yi-Xing Sun, Ya-Ge Wu, Kexiao Sang, Ting Yue, Zihao Yang, Jinggang GaiThe shrinkage phenomenon of UV-NIL resist during photocuring is still regarded as an important problem hindering the wide application of UV-NIL technology. We designed four degradable UV-NIL resists with low...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article