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AMF-SporeChip provides new insights into arbuscular mycorrhizal fungal asymbiotic hyphal growth dynamics at the cellular level

Lab Chip, 2024, 24,1930-1946
DOI: 10.1039/D3LC00859B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Felix Richter, Maryline Calonne-Salmon, Marcel G. A. van der Heijden, Stéphane Declerck, Claire E. Stanley
A new microfluidic platform – the AMF-SporeChip – enables immobilisation of arbuscular mycorrhizal fungal spores and confrontation of asymbiotic hyphae with physical obstacles, allowing the identification of various exploration strategies.
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Development of a self-contained microfluidic chip and an internet-of-things-based point-of-care device for automated identification of respiratory viruses

Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00933E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huynh Quoc Nguyen, Van Dan Nguyen, Vu Minh Phan, Tae Seok Seo
The COVID-19 pandemic greatly impacted the in vitro diagnostic market, leading to the development of new technologies such as point-of-care testing (POCT), multiplex testing, and digital health platforms.
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Detection and Identification of Single Ribonucleotide Monophosphates using a Dual In-Plane Nanopore Sensor Made from a Thermoplastic via Replication

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC01062G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Steven A. Soper, Chathurika Rathnayaka, Indu Chandrasoma, Junseo Choi, Katie Childers, Maximillian Chibuike, Khurshed Akabirov, Farhad Shiri, Adam R Hall, Collin J McKinney, Matthew David Verber, Sunggook Park
We report the generation of ~8 nm dual in-plane pores fabricated in a thermoplastic via nanoimprint lithography (NIL). These pores were connected in series with nanochannels, one of which served...
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A point-of-care testing platform for on-site identification of genetically modified crops

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00040D, Paper
Yangyang Wang, Furui Yang, Yingyi Fu, Xin He, Haowei Tian, Lili Yang, Mengxi Wu, Jijuan Cao, Junshan Liu
To fulfil the urgent needs of on-site testing, we develop a point-of-care testing platform that is able to identify 12 types of GM crops in less than 40 minutes without using laboratory settings.
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A Chemist's guide to multi-objective optimization solvers for reaction optimization

React. Chem. Eng., 2024, 9,2882-2891
DOI: 10.1039/D4RE00175C, Paper
Aravind Senthil Vel, Daniel Cortés-Borda, François-Xavier Felpin
This paper presents a chemist's guide for selecting multi-objective optimization algorithms for reaction optimization.
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Evaluating metal-free quaternized boronate esters as efficient catalysts for the fixation of CO2 with epoxides to form cyclic carbonates under suitable conditions

React. Chem. Eng., 2024, 9,2938-2953
DOI: 10.1039/D4RE00282B, Paper
Eyyup Yasar, Emine Aytar, Ahmet Kilic
The conversion of CO2 into high value-added chemicals is receiving increasing attention from the scientific community, commercial enterprises, and policymakers due to environmental problems like global warming.
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Closed-loop identification of enzyme kinetics applying model-based design of experiments

React. Chem. Eng., 2024, 9,2984-2993
DOI: 10.1039/D4RE00127C, Paper
Leon Hennecke, Lucas Schaare, Mirko Skiborowski, Andreas Liese
This study presents an automated reactor platform for the identification of enzyme kinetic models using model-based design of experiments on the example of the reduction of NAD+ by formate dehydrogenase from Candida boidinii.
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Synthesis of ethylphenols and xanthenes via reaction of calcium carbide and phenol: experimental and theoretical studies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00397G, Paper
Xin Liu, Yuxin Yan, Zhenyu Liu, Qingya Liu
A novel synthesis of xanthenes and ethylphenols by the reaction of phenol with CaC2 without catalysts and solvents.
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Nickel foam supported biochar doped Ni–Mo bimetallic oxide for supercapacitor application

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00471J, Paper
Zhongxin Jin, Kaijia Hu, Feng Lin, Siqi Liu, Ruining Gu, Wei Zhang, Siyu Liu, Caiying Li, Hongyang Liao, Xinping Cai, Haijun Pang, Chunjing Zhang, Huiyuan Ma
A novel C-MoO3-NiO2/NF electrode derived from polyoxometalate and rice is obtained and provides a new strategy for the development of high-performance supercapacitors.
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Surfactant-induced alterations in optoelectronic properties of perylene diimide dyes: modulating sensing responses in the aqueous environment

Soft Matter, 2024, 20,3044-3052
DOI: 10.1039/D3SM01694C, Paper
Animesh Pal, Nilanjan Dey
The compartmentalization effect of microheterogeneous systems, like surfactant aggregates, showcases altered optoelectronic properties of a perylene diimide-based chromogenic dye (PDI-Ala) compared to bulk water.
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Self-healing polyacrylates based on dynamic disulfide and quadruple hydrogen bonds

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00257A, Paper
Longjin Du, Yuting Zhong, Linying Zhao, Chengzhen Hu, Liang Shen, Yuping Yang, Jiang Zhong
Herein, a self-healing polyacrylate system was successfully prepared by introducing crosslinking agents containing disulfide bonds and monomers capable of forming quadruple hydrogen bonds through free radical copolymerization.
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The interplay of chirality and restricted rotation: stabilisation of chiral, frustrated mesophases over a wide thermal range

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00126E, Paper
Sachin A. Bhat, Channabasaveshwara V. Yelamaggad
Chiral dimers formed by linking cholesterol to phenyl 3-(4-(n-alkoxy)phenyl)propiolate via ω-oxyalkanoyloxy spacer exhibit odd–even effect, stabilizing SmA, N*, BPI/II, & TGBC* phases. TGBC* phase width increases with longer terminal tails.
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Slide electrification of drops at low velocities

Soft Matter, 2024, 20,3349-3358
DOI: 10.1039/D4SM00019F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chirag Hinduja, Hans-Jürgen Butt, Rüdiger Berger
The novelty of our electro drop friction force instrument (eDoFFI) is the simultaneous measurements of the drop discharging current and friction force acting on the sliding drops. With eDOFFI, we measure the surface charge density deposited behind sliding drops.
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Effect of Aromatic Side Chain on the Dilational Rheological Properties of N-Acyltaurate Amphiphiles at Water-Decane Interfaces

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00269E, Paper
Yang-Wen Zhu, Zhicheng Xu, Li Zhang, Ping Liu, Yu Hou, Lei Zhang, Lu Zhang
To elucidate the effect of aromatic side chains on dilational rheological properties of N-acyltaurate amphiphiles at the decane-water interface, the interfacial rheological properties of sodium N-2-(2-naphthoxy)-tetradecanolytaurinate (12+N-T) and sodium N-2-(p-butylphenoxy)-...
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Lipidation Alters the Phase-separation of Resilin-like Polypeptides

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00358F, Paper
Open Access
Zhe Zhang, Jingjing Ji, Md Shahadat Hossain, Briah Bailey, Shikha Nangia, Davoud Mozhdehi
Biology exploits biomacromolecular phase separation to form condensates, known as membraneless organelles. Despite significant advancements in deciphering sequence determinants for phase separation, modulating these features in vivo remains challenging. A...
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Agri-waste derived electroactive carbon–iron oxide nanocomposite for oxygen reduction reaction: an experimental and theoretical study

RSC Adv., 2024, 14,12171-12178
DOI: 10.1039/D4RA01264J, Paper
Open Access
Pallavi B. Jagdale, Sai Rashmi Manippady, Rohit Anand, Geunsik Lee, Akshaya Kumar Samal, Ziyauddin Khan, Manav Saxena
Herein, we have utilized agri-waste and amalgamating low Fe3+, to develop an economic iron oxide–carbon hybrid-based electrocatalyst for oxygen reduction reaction (ORR) with water as a main product following close to 4e transfer process.
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Discovery of new triterpene glycosides from Dendrobium officinale with their α-glucosidase and α-amylase inhibitory activity

RSC Adv., 2024, 14,12147-12157
DOI: 10.1039/D4RA01483A, Paper
Open Access
Pham Hai Yen, Bui Huu Tai, Dan Thi Thuy Hang, Le Doan Tung Lam, Duong Thi Dung, Do Thi Trang, Duong Thi Hai Yen, Nguyen Huy Hoang, Phan Thi Thanh Huong, Nguyen Viet Dung, Ngo Anh Bang, Nguyen Duc Duy, Phan Van Kiem
Seven new oleanane saponins were discovered from Dendrobium officinale. These saponins containing 29-noroleana-12,20(30)-dien-28-oic acid framework, caffeoyl, and coumaroyl moieties potentially inhibited α-glucosidase and α-amylase activities.
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Aluminum and polyanion-doping to improve structural and moisture stability of Ni-rich layered oxides for lithium-ion batteries

RSC Adv., 2024, 14,12247-12254
DOI: 10.1039/D4RA00879K, Paper
Open Access
Yan Mo, Yingke Wu, Guohui Yuan, ZiKun Li, Meng Zhang
The substitution of Al3+ and PO34− in LiNi0.8Co0.1Mn0.1O2 material is favorable for stabilizing the layered structure against the undesired phase transition of H2 to H3 as well as the contamination of ambient air.
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Reusable magnetic mixture of CuFe2O4–Fe2O3 and TiO2 for photocatalytic degradation of pesticides in water

RSC Adv., 2024, 14,12337-12348
DOI: 10.1039/D4RA00094C, Paper
Open Access
Dmytro Danilian, Franziska Maria Bundrück, Arvo Kikas, Tanel Käämbre, Hugo Mändar, Sandro Lehner, Alexander Gogos, Jekaterina Kozlova, Mati Kook, Valter Kiisk, Joosep Link, Raivo Stern, Angela Ivask, Vambola Kisand, Rainer Pärna
Mixture of TiO2-P25 and magnetic CuFe2O4–Fe2O3 nanocomposites improves photocatalytic water treatment and enables easy catalyst recovery, effectively degrading pollutants like 2,4-D.
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Correction: 2-cyanopyridine derivatives enable N-terminal cysteine bioconjugation and peptide bond cleavage of glutathione under aqueous and mild conditions

RSC Adv., 2024, 14,12416-12416
DOI: 10.1039/D4RA90039A, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tetsuya Yano, Takahiro Yamada, Hiroaki Ishida, Nami Ohashi, Toshimasa Itoh
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Surface modification of halide perovskite using EDTA-complexed SnO2 as electron transport layer in high performance solar cells

RSC Adv., 2024, 14,12397-12406
DOI: 10.1039/D3RA08900B, Paper
Open Access
Nuno Marques, Santanu Jana, Manuel J. Mendes, Hugo Águas, Rodrigo Martins, Shrabani Panigrahi
The long-term performance of metal halide perovskite solar cells (PSCs) can be significantly improved by tuning the surface characteristics of the perovskite layers.
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Harnessing the power of natural deep eutectic solvents (choline chloride/sucrose) and polypropylene glycol in the formation of aqueous biphasic systems and the application of these systems in drug extraction

RSC Adv., 2024, 14,12349-12359
DOI: 10.1039/D3RA07066B, Paper
Open Access
Fariba Ghaffari, Mohammed Taghi Zafarani-Moattar, Hemayat Shekaari
In recent times, there has been considerable interest in utilizing aqueous biphasic systems (ABSs) containing natural deep eutectic solvents (NADESs) for the extraction of various substances.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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In situ one step growth of amorphous tin oxide electron transport layer for high-performance perovskite solar cells

RSC Adv., 2024, 14,12650-12657
DOI: 10.1039/D4RA01724B, Paper
Open Access
Wenlin Du, Zhe Wan, Jingyi Zhu, Xin Liu, Li Chen, Shuxia Li, Ning Kang, Chenglong Wang
Perovskite solar cells prepared by using amorphous Tin oxide as electron transport layer.
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Construction of glutathione-responsive paclitaxel prodrug nanoparticles for image-guided targeted delivery and breast cancer therapy

RSC Adv., 2024, 14,12796-12806
DOI: 10.1039/D4RA00610K, Paper
Open Access
Weiwei Ma, Qiufeng Zhao, Shilong Zhu, Xinyue Wang, Chuangchuang Zhang, Daming Ma, Na Li, Yanyan Yin
HA-coated redox sensitive visualized nano-prodrug HA/TPE-CS-SS-PTX were exploited in order to highly efficient treatment of cancer and real-time monitoring of drug localization.
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Carbon dots–cadmium sulfide quantum dots nanocomposite for ‘on–off’ fluorescence sensing of chromium(VI) ions

RSC Adv., 2024, 14,12923-12934
DOI: 10.1039/D4RA00436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anisha B. Patil, Pooja L. Chaudhary, Parag V. Adhyapak
This work involves fluorescent probe which is composed of carbon dots (CD) and cadmium sulfide quantum dots (CdS QD) for the sensitive and selective fluorescence detection of chromium(VI) ions.
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Nickel-catalyzed γ-alkylation of cyclopropyl ketones with unactivated primary alkyl chlorides: balancing reactivity and selectivity via halide exchange

RSC Adv., 2024, 14,12883-12887
DOI: 10.1039/D4RA02616K, Paper
Open Access
Zheng-Ying Wang, Shi-Zheng Liu, Cong Guo, Yi-Zheng Cheng, Qiang Li, Jianmin Dou, Dacheng Li
Nickel-catalyzed cross-electrophile coupling of cyclopropyl ketones and alkyl chlorides. High reactivity and selectivity can be achieved with sodium iodide as a cocatalyst that generates a low concentration of alkyl iodide via halide exchange.
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Wet adhesive hydrogels based on niobium carbide for experimental research of oral mucosal impairment

RSC Adv., 2024, 14,12935-12946
DOI: 10.1039/D4RA01352B, Paper
Open Access
Jiayuan Chen, Junyu Ren, Yingjie Wu, Narisu Hu, Fang Zhao, Lin Zhang
Illustration of the mechanism of NbC/TA–GelMA hydrogel with multifunctional properties for potential application in oral mucosal impairment.
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Development of an imidazole-based N,N-bidentate ligand for the manganese catalyzed direct coupling of nitriles with alcohols

RSC Adv., 2024, 14,12978-12982
DOI: 10.1039/D4RA00817K, Paper
Open Access
Qian Tang, Dingguo Song, Kali Zhang, Wenhao Mao, Xianghua Zhao, Ding Du, Fei Ling, Weihui Zhong
This work describes the manganese catalyzed direct coupling of nitriles with alcohols with assistance of a set of simple and new imidazole-based N,N-bidentate ligands.
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Antioxidant-rich brilliant polymeric nanocomposites for quick and efficient non-enzymatic hydrogen peroxide sensor

RSC Adv., 2024, 14,13142-13156
DOI: 10.1039/D4RA01768D, Paper
Open Access
M. S. Hashem, Hend S. Magar, Asmaa M. Fahim, Rokaya A. Sobh
New polymeric nanocomposites with metal oxide nanoparticles enhance electrical impedance ratings, offer energy storage and supercapacitors, and enable rapid creation of hydrogen peroxide sensors through microemulsion polymerization.
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Exploring the synthetic potential of epoxide ring opening reactions toward the synthesis of alkaloids and terpenoids: a review

RSC Adv., 2024, 14,13100-13128
DOI: 10.1039/D4RA01834F, Review Article
Open Access
Madiha Hanif, Ameer Fawad Zahoor, Muhammad Jawwad Saif, Usman Nazeer, Kulsoom Ghulam Ali, Bushra Parveen, Asim Mansha, Aijaz Rasool Chaudhry, Ahmad Irfan
Epoxides are oxygen containing three-membered heterocycles which can undergo ring opening reactions. These reactions have been significantly employed in the synthesis of alkaloids and terpenoids-based natural products.
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Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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Dispersive micro solid phase extraction of glibenclamide from plasma, urine, and wastewater using a magnetic molecularly imprinted polymer followed by its determination by a high-performance liquid chromatography-photodiode array detector

RSC Adv., 2024, 14,13168-13179
DOI: 10.1039/D4RA00452C, Paper
Open Access
Najmeh Sabbaghi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani, Majid Farsadrooh
The present study describes the development of a simple and selective analytical method for dispersive micro solid phase extraction and determination of glibenclamide (GLB) using magnetic molecularly imprinted polymer (MMIP) as a sorbent.
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Engineering the interaction of short antimicrobial peptides with bacterial barriers

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00021H, Minireview
Open Access
Costanza Montis, Elisa Marelli, Francesco Valle, Francesca Baldelli Bombelli, Claudia Pigliacelli
Designing short antimicrobial peptides and tuning their interaction with bacterial barriers.
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Design and engineering of an artificial disulfide bond in human cytochrome c to regulate the protein structure and function

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00196B, Paper
Yan-Yan Li, Yu Feng, Lu Yu, Shuang-Shuang Long, Shu-Qin Gao, Ying-Wu Lin
An artificial disulfide bond was rationally constructed in human cytochrome c (hCyt c) via double mutations (A51C/G77C), which weakened the coordination of Met80 to the heme iron and enhanced the peroxidase activity of hCyt c.
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Countryside caretaker of the dainty demoiselle

Meet Sevaram, who has made it his life’s mission to care for the migrant visitors to a Rajasthan hamlet every year




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Working with pride, not prejudice

A recent job fair for the LGBTI community attracted people from cities and small towns




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Influence of polyol impurities on the transesterification kinetics, molecular structures and properties of isosorbide polycarbonate

Polym. Chem., 2024, 15,4204-4220
DOI: 10.1039/D4PY00840E, Paper
Mingfa Guo, Yaning Wang, Zhenguang Li, Jielin Xu, Qian Chen, Jing Wu, Huaping Wang
A so-called “reverse-addition” model protocol based on two kinds of polyol impurities (glycerol and 2-deoxy-D-ribose) was established to systematically demonstrate their influence on the polymerization and properties of PIC.
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Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

Polym. Chem., 2024, 15,4255-4263
DOI: 10.1039/D4PY00781F, Paper
Xiuling Wang, Yang Wang, Zhonglei Qin, Liying Shen, Xiaochao Shi
Phenylthiol-functionalized rare-earth metal cationic species showed unparalleled stereoselectivity in the polymerization of isoprene and butadiene to respectively produce cis-1,4-polyisoprene and trans-1,4-polybutadiene.
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Expanding the poly(2-oxazoline) block copolymer possibilities through nitroxide mediated polymerisation

Polym. Chem., 2024, 15,4416-4424
DOI: 10.1039/D4PY00887A, Paper
Open Access
James Lefley, C. Remzi Becer
In recent years, poly(2-oxazoline)s (POx) have become a sought-after biomaterial to replace PEG. Endcapping POx with BlocBuilder MA enables copolymerization with a variety of vinylic monomers, producing unique POx-vinyl block copolymer combinations.
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A novel amine-first strategy suitable for preparing both functional and engineering bio-polyamides: furfurylamine as the sole furan source for bisfuranic diamine/diacid monomers

Polym. Chem., 2024, 15,4433-4446
DOI: 10.1039/D4PY00567H, Paper
Hong-Hui Shu, Yun Liu, Sheng-Li Han, Xiu-Qin Fang, Chang Wang, Cheng-Mei Liu
Biomass-based polyamides (bioPAs) are renewable materials that are viable alternatives to petroleum-based polyamides in the engineering field.
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Constructing self-healing flexible supercapacitors via graphene oxide synergistic multi-network polymer-supramolecular hydrogel electrolyte

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00809J, Paper
Xiaoyan Li, Xiuting Shi, Anbai Li, Mengmeng Xun, Shuzhen Cui, Kanjun Sun, Hui Peng, Guofu Ma, Yuxi Xu
Hydrogels are increasing interest and have great potential as electrolytes for flexible supercapacitors (FSCs) in wearable and portable electronic devices. However, the hydrogel electrolytes for practical applications are hampered by...
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Mesomorphic and photochromic luminescent behaviour of side-chain liquid crystalline polymers containing di-substituted cyanostilbene groups with the different number of alkyl tail chain

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00889H, Paper
Juan Luo, Juan Wang, Junde Zhang, Huizi Cao, Xiaofang Chen
In this work, side-chain luminescent liquid crystalline polymers (SCLLCPs) that contain di-substituted cyanostilbene (CS) groups with the different substituted number of terminal alkyl chain, which are PNB-Z-4, PNB-Z-34, and PNB-Z-345,...
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Diversified synthesis of poly(sulfonyl isourea)s by multicomponent polymerizations of isocyanides, sulfonyl azides, and alcohols/phenols

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00953C, Paper
Dongyang Fan, Fenggang Chen, Dong Wang, Ting Han, Ben Zhong Tang
A novel multicomponent polymerization strategy using diverse monomer combinations of isocyanides, sulfonyl azides, and alcohols/phenols was developed to synthesize thermally and morphologically stable and heteroatom-rich poly(sulfonyl isourea)s.
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Reducing Agent Triggered Templated Synthesis of Dynamic Covalent Poly(disulfide)s Nanonetwork: Remarkable Tuning in Noncovalent Encapsulation Stabilities and Cargo Release

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01109K, Paper
Arun Mondal, S. K. Sujauddin, Dhiman Mondal, Soumya Kolay, Shuvajyoti Sarkar, Mijanur Rahaman Molla
Here, we demonstrated a new methodology for the templated synthesis of cross-linked poly(disulfide)s based dynamic covalent nanonetwork as highly stable potential delivery vehicle in the field of chemotherapeutic applications. The...
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Single-ion quasi-solid-state electrolytes based on sulfonimide-functionalized covalent organic framework

Polym. Chem., 2024, 15,4529-4541
DOI: 10.1039/D4PY00352G, Paper
Haomin Wu, Wencan Ma, Xin Huang, Yifeng Cai, Junheng Li, Qiaobo Liao, Kai Xi, Qiuhong Zhang, Xudong Jia
The COF based SIQSSEs with a high ionic conductivity of 4.3 × 10−4 S cm−1, a high LTN of 0.90. A high initial capacity (150.3 mA h g−1), high retention (99% after 100 cycles), good cycling stability and rate performance in Li/LFP battery test.
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Catalytic copolymerization of carbon dioxide and cyclohexene oxide by a trinuclear cyclohexane-bridged tetradentate Schiff base chromium complex

Polym. Chem., 2024, 15,4519-4528
DOI: 10.1039/D4PY00956H, Paper
Jie Huang, Boxiong Shen
The development of catalytic systems is a central area of research in carbon dioxide (CO2) and epoxy copolymerization.
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Backbone editing of oxidized polyethylene: insertion of oxygen and nitrogen atoms via hydroxyalkyl azide-mediated rearrangements

Polym. Chem., 2024, 15,4554-4561
DOI: 10.1039/D4PY00973H, Paper
Andrew J. King, Ryan P. Sherrier, Jeffrey Aubé, Aleksandr V. Zhukhovitskiy
Hydroxyalkyl azide-mediated rearrangement modularly inserts heteroatoms and pendent functionality into oxidized polyethylene.
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Interpretable machining learning assisted insights into bifunctional squaramide catalyzed ring-opening polymerization of lactide

Polym. Chem., 2024, 15,4562-4569
DOI: 10.1039/D4PY00866A, Paper
Shaoju Cao, Mengting Hong, Junyuan Hu, Zhenjiang Li, Jin Huang, Kai Guo
A bifunctional squaramide catalyst with tunable activity enables the controlled ring-opening polymerization of lactide. Combining bench experiments and interpretable machine learning offer insights into catalyst structures, promoting catalyst design.
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A highly active zinc-based catalyst system for lactide homo- and copolymerization under industrially relevant conditions

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01034E, Paper
Zisheng Zhang, Yi Zhou, Shuang Liu, Baixue Li, Rui Qu, Yanan Gu, Hongyi Suo, Yusheng Qin
A guanidine-based zinc catalyst with a rigid backbone exhibited excellent activity in the ring-opening polymerization and copolymerization of lactide.
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