While the current estate tax exemption is higher than most people will qualify for at $11.4 million, estate planning is an important process for everyone. Critical decisions such as who will be the legal guardian of your children, how your… Read More

The post Making Technology Work for You: 5 Tips for Proactive Digital Estate Planning appeared first on Anders CPAs.

Margaret Parker, MD, FCCM, speaks with Andrew Argent, MD, Medical Director of the Pediatric Intensive Care Unit (PICU) at the Red Cross War Memorial Childrens Hospital.

Tech investments aimed at making Jio a solid digital company: Axis Securities

The chapati recently made an appearance in NYT Cooking as an unleavened curiosity in a world overrun with fluffed-up delights. It may be the most common way in which north Indian homes make their daily bread but there is more to it than simply roasting it on a hot iron tawa.

The Securities and Exchange Commission today announced that it is providing temporary, conditional exemptive relief for business development companies (BDCs) to enable them to make additional investments in small and medium-sized businesses, including…

The Communication Alliance for Networking Thoroughbred Ex-Racehorses' Kentucky division took its operation to a new level this month when it opened its first official retraining facility in Georgetown. For both CANTER Kentucky executive director Amanda Graham and trainer Stephanie Calendrillo, the event marks the realization of long-term goals. Graham has been saving money to open the […]

The post Three Chimneys presents Good News Friday: CANTER Kentucky Making New Strides appeared first on Horse Racing News | Paulick Report.

Atlanta Hawks guard Malcolm Delaney is a hero in more ways than one to some Baltimore City Public Schools students who attend the very same elementary school that he attended in northeast Baltimore.

President Donald Trump participated in a tour of a Honeywell International plant that manufactures personal protective equipment, Tuesday, May 5, 2020, in Phoenix .

Grand Canyon fire managers are making plans to initiate the Walla Valley Prescribed Fire within the next few weeks on the North Rim of Grand Canyon National Park. https://www.nps.gov/grca/learn/news/2011-05-26_walla.htm

https://www.nps.gov/grca/learn/news/2011-10-27_range.htm

National Park Service (NPS) and U.S. Forest Service (USFS) fire managers, working together as the North Zone Interagency Fire Management Program, are making plans for the Range and Thompson Prescribed Fires on the North Rim of Grand Canyon National Park. Fire managers anticipate initiating these prescribed fire treatments within the next four weeks as weather and fuel moisture conditions allow. https://www.nps.gov/grca/learn/news/2012-10-23_range-thompson.htm

In a world where photographs are everywhere, displayed largely via web pages and small screens, the traditional career tracks for professional photographers have fallen by the wayside. So what do you have to do to make photography your livelihood in today’s world? I recently moderated a lively discussion on this topic with two professional photographers […]

The post Making Photography Your Career appeared first on Complete Digital Photography.

In recent years, the Forest Service and the public have placed increasing priority on making sure that management of public lands takes into account the needs of nearby communities, regional residents, national residents, and even members of the public who may not currently visit public lands.

Forests significantly influence the global carbon budget: they store massive amounts of carbon in their wood and soil, they sequester atmospheric carbon as they grow, and they emit carbon as a greenhouse gas when harvested or converted to another use.

The Community Socioeconomic Information System (CSIS) is a tool that allows users to retrieve 1990 and 2000 U.S. census data to examine conditions and trends for communities in western Washington, western Oregon, and northern California. The tool includes socioeconomic data for 1,314 communities in the entire region, including incorporated and unincorporated places. The tool delivers socioeconomic data using mapping and database features. In addition to providing data for one community, the tool produces community-level data at a variety of scales, including communities in areas surrounding Forest Service and Bureau of Land Management lands, all communities in the Northwest Forest Plan (NWFP) region, and communities within planning provinces within the NWFP region. One feature allows users to customize community data by creating boundaries and socioeconomic data for group of selected communities. The CSIS tool was designated to increase the usefulness of socioeconomic information at the small scale. Typically community socioeconomic assessments use U.S. census designations called census places. However, census places only represent a portion of the rural population. The CSIS uses a smaller unit of analysis (block groups) that we have aggregated to represent contiguous communities across the landscape, thereby representing the entire population. Community data can be printed as reports with graphs and tables, queried within an Access database, mapped and queried as geographic information system (GIS) data within ArcExplorer (a free GIS software included), exported as a table for use in Excel, or exported as GIS data for use in ArcGIS. The tool has features that allow users to locate communities by county or state and become familiar with local geography. The CSIS includes GIS data, such as major land ownerships, political boundaries, and physical landscape features. Applications produce maps that can be printed for specific communities showing community boundaries, water features, roads, metropolitan areas, community population centers, public land ownership, census places, planning provinces, counties, and state boundaries. Or, using the spatial data provided on the CD and ArcExplorer, users can produce custom maps.

This report reviews the growing literature on the concept of agency-citizen interactions after large wildfires. Because large wildfires have historically occurred at irregular intervals, research from related fields has been reviewed where appropriate. This issue is particularly salient in the West where excess fuel conditions indicate that the large wildfires occurring in many states are expected to continue to be a major problem for forest managers in the coming years. This review focuses on five major themes that emerge from prior research: contextual considerations, barriers and obstacles, uncertainty and perceptions of risk, communication and outreach, and bringing communities together. It offers ideas on how forest managers can interact with stakeholders for planning and restoration activities after a large wildfire. Management implications are included.

Operational-scale experiments that evaluate the consequences of fire and mechanical "surrogates" for natural disturbance events are essential to better understand strategies for reducing the incidence and severity of wildfire. The national Fire and Fire Surrogate (FFS) study was initiated in 1999 to establish an integrated network of long-term studies designed to evaluate the consequences of using fire and fire surrogate treatments for fuel reduction and forest restoration. Beginning in September2005, four regional workshops were conducted with selected clients to identify effective and efficient means of communicating FFS study findings to users. We used participatory evaluation to design the workshops, collect responses to focused questions and impressions, and summarize the results. We asked four overarching questions: (1) Who needs fuel reduction information? (2) What information do they need? (3) Why do they need it? (4) How can it best be delivered to them? Participants identified key users of FFS science and technology, specific pieces of information that users most desired, and how this information might be applied to resolve fuel reduction and restoration issues. They offered recommendations for improving overall science delivery and specific ideas for improving delivery of FFS study results and information. User groups identified by workshop participants and recommendations for science delivery are then combined in a matrix to form the foundation of a strategic plan for conducting science delivery of FFS study results and information. These potential users, their information needs, and preferred science delivery processes likely have wide applicability to other fire science research.

The team at the UF/ IFAS Extension office show us how to create a pond, and fill it with native aquatic plants, to attract wildlife to our yards.

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Sewing is my new coping mechanism.…

If you've ever taken a stroll around downtown Spokane's west side, you may have come across Barrister Winery, tucked into a historic brick and timber building alongside the railroad tracks at 1213 Railroad Ave.…

An improved process for making ethoxylated amine compounds such as ethanolamines. The improvement comprises the addition of an acid to the amine compound prior to the addition of ethylene oxide to a reactor wherein the ethoxylated amine compound is prepared. The improvement reduces the concentration of undesirable glycol ether and/or vinyl ether ethoxylate byproducts which may contribute to undesirable properties, such as color and foaming, of the ethoxylated amine compounds.

Processes for continuous preparation of bioproducts are described herein. The processes include contacting fatty acid glycerides with alcohols in the presence of an acidic heterogeneous catalyst and separating the fatty acid alkyl esters from the reaction products.

A method of forming a product from an oil feedstock, such as a biodiesel product, and a heterogeneous catalyst system used to form said product is disclosed. This catalyst system, which has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock, may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La2CO5, LaOOH, and combinations or mixtures thereof.

The invention relates to a process for making esters, in particular biodiesel, using heterogeneous catalysts. The invention provides a process for making biodiesel, in particular FAME, which process is versatile and robust. The process of the invention can be carried out continuously, in particular in a fixed bed reactor or a slurry reactor and may be operated in a continuous fashion. In accordance with the invention, the transesterification reaction of triglycerides is carried out using a heterogeneous catalyst that comprises a Group 4 silicate and less than 3 wt. % Na in the presence of at least one acid compound.

Described herein are nitrated lipids and methods of making and using the nitrated lipids.

Described herein are dicarboxylate-capped estolide compound and methods of making the same. Exemplary dicarboxylate-capped estolide compounds include those of the formula x is, independently for each occurrence, an integer selected from 0 to 20; y is, independently for each occurrence, an integer selected from 0 to 20; W is, independently for each occurrence, selected from —CH2— and —CH═CH—; z is an integer selected from 1 to 40; n is an integer equal to or greater than 0; R5 is selected from hydrogen, optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, and an estolide residue; and R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein each fatty acid chain residue of said at least one compound is independently optionally substituted.

The present invention relates to processes and intermediates for preparing compounds useful as inhibitors of ATR kinase, such as aminopyrazine-isoxazole derivatives and related molecules. The present invention also relates to compounds useful as inhibitors of ATR protein kinase. The invention relates to pharmaceutically acceptable compositions comprising the compounds of this invention; methods of treating of various diseases, disorders, and conditions using the compounds of this invention; processes for preparing the compounds of this invention; intermediates for the preparation of the compounds of this invention; and solid forms of the compounds of this invention. The compounds of this invention have formula I or II: wherein the variables are as defined herein.

Embodiments of the present disclosure relate to the preparation of colloidal dispersions or suspensions of inorganic materials with nano-sized and nano-structured morphologies, preferably the nanosheet form, compositions produced by this method, and the like.

In certain embodiments, the invention is directed to composition comprising stable particles comprising ganaxolone, wherein the volume weighted median diameter (D50) of the particles is from about 50 nm to about 500 nm.

A memory device includes a semiconductor channel, a tunnel dielectric layer located over the semiconductor channel, a first charge trap including a plurality of electrically conductive nanodots located over the tunnel dielectric layer, dielectric separation layer located over the nanodots, a second charge trap including a continuous metal layer located over the separation layer, a blocking dielectric located over the second charge trap, and a control gate located over the blocking dielectric.

Disclosed are methods for producing rubber-containing bituminous mixtures by pressurizing mixtures of bituminous materials, crumb rubber, and one or more suspension agents with a gas, and then reducing the pressure, creating bubbles of the gas in the mixture. Also disclosed are methods of introducing gas into such mixture by rapid mixing. Mixtures produced by the disclosed methods, such as rubber-containing asphalt mixtures and paving compositions thereof, and their use are also disclosed.

A coating/sealant system that includes a coating and a sealant deposited over at least a portion of the coating, in which the coating includes a reaction product formed from reactants comprising a phosphated epoxy resin and a curing agent, and the sealant includes a sulfur-containing polymer.

A durable ambient light curable waterproof liquid rubber coating with volatile organic compound (VOC) content of less than 450 grams per liter made from ethylene propylene diene terpolymer (EPDM) in a solvent, a photoinitiator, an additive, pigments, and fillers, and a co-agent and a method for making the formulation, wherein the formulation is devoid of thermally activated accelerators.

Disclosed is a reactor and agitator useful in a high pressure process for making 1-chloro-3,3,3-trifluoropropene (1233zd) from the reaction of 1,1,1,3,3-pentachloropropane (240fa) and HF, wherein the agitator includes one or more of the following design improvements: (a) double mechanical seals with an inert barrier fluid or a single seal;(b) ceramics on the rotating faces of the seal;(c) ceramics on the static faces of seal;(d) wetted o-rings constructed of spring-energized Teflon and PTFE wedge or dynamic o-ring designs; and(e) wetted metal surfaces of the agitator constructed of a corrosion resistant alloy.

The disclosure relates to methods of making polymer particles, said methods including the steps of: making an aqueous gel reaction mixture; forming an emulsion having dispersed aqueous phase micelles of gel reaction mixture in a continuous phase; adding an initiator oil comprising at least one polymerization initiator to the continuous phase; and performing a polymerization reaction in the micelles. Further, the initiator oil is present in a volume % relative to a volume of the aqueous gel reaction mixture of between about 1 vol % to about 20 vol %. The disclosure also relates to methods of making nucleic acid polymer particles having the same method steps and wherein the aqueous gel reaction mixture includes a nucleic acid fragment, such as a primer.

Method for making a liquid foam from graphene. The method includes preparing an aqueous dispersion of graphene oxide and adding a water miscible compound to the aqueous dispersion to produce a mixture including a modified form of graphene oxide. A second immiscible fluid (a gas or a liquid) with or without a surfactant are added to the mixture and agitated to form a fluid/water composite wherein the modified form of graphene oxide aggregates at the interfaces between the fluid and water to form either a closed or open cell foam. The modified form of graphene oxide is the foaming agent.

A process for selective formation of ethanol from acetic acid by hydrogenating acetic acid in the presence of a catalyst comprises a first metal on an acidic support. The acidic support may comprise an acidic support material or may comprise an support having an acidic support modifier. The catalyst may be used alone to produced ethanol via hydrogenation or in combination with another catalyst. In addition, the crude ethanol product is separated to obtain ethanol.

Disclosed are processes relating to the production of polyglycerol ethers of fatty alcohols, in particular, one step process using fatty alcohol and glycerine to synthesize polyglycerides of fatty alcohols will provide a 100% renewable surfactant that is cost effective efficient and CMR free. The synthetic methods mentioned in prior art uses hazardous chemicals as glycidyl ethers, epichlorohydrin that are listed as CMR and known carcinogens and hazardous to handle.

A new general purpose foaming agent having application as drilling fluid foaming agents or as any foaming agent needed an a wide variety of applications is disclosed, where the agent includes at least one anionic surfactant, at least one cationic surfactant, and mixtures thereof and one or more zwitterionic compounds. A method for using the foaming agent in capillary coiled tubing application is also disclosed. The foaming agents can also include additive to augment the properties of the foaming agent for a given application.

The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C20 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of an alkali metal or ammonium or substituted ammonium ion.

An improved multi-reaction zone process provides for improved nitrile product quality and yield. In a first reaction zone, 1,3-butadiene is reacted with hydrogen cyanide in the presence of a catalyst to produce pentenenitriles comprising 3-pentenenitrile and 2-methyl-3-butenenitrile. In a second reaction zone, 2-methyl-3-butenenitrile, recovered from the first reaction zone, is isomerized to 3-pentenenitrile. In an optional third reaction zone, 3-pentenenitrile recovered from the first and second reaction zones is reacted with hydrogen cyanide in the presence of a catalyst and a Lewis acid to produce adiponitrile. A portion of the first catalyst is purified and recycled. Zero valent nickel is added to the purified first catalyst before it is recycled.

Adiponitrile is made by reacting 3-pentenenitrile with hydrogen cyanide. The 3-pentenenitrile is made by reacting 1,3-butadiene with hydrogen cyanide and by isomerizing 2-methyl-3-butenenitrile. The reaction of 1,3-butadiene with hydrogen cyanide to produce 3-pentenenitrile also produces small amounts of dinitrile compounds, including adiponitrile (ADN) and methylglutaronitrile (MGN). Methylglutaronitrile is removed to provide an adiponitrile-enriched stream, which is used in a catalyst purification step.

The present invention relates to a process for hydrocyanating 3-pentenenitrile. The process can include feeding 3-pentenenitrile and HCN to a hydrocyanation reaction zone that includes a Lewis acid promoter, nickel, and a phosphorus-containing ligand. In various embodiments, the process can also include controlling water concentration within the hydrocyanation reaction zone sufficient to maintain a high activity of the ligand catalyst complex while recycling at least a portion of the ligand catalyst complex.

Disclosed herein are forms of L-ornithine phenyl acetate and methods of making the same. A crystalline form may, in some embodiments, be Forms I, II, III and V, or mixtures thereof. The crystalline forms may be formulated for treating subjects with liver disorders, such as hepatic encephalopathy. Accordingly, some embodiments include formulations and methods of administering L-ornithine phenyl acetate.

A method of making modified carbon materials for use in fabricating fuel cell components. The modified carbon may comprise pendant fluorocarbon groups bonded covalently bonded thereto. In one embodiment, a mixture is formed and comprises carbon material suitable for use in a fuel cell component, an organic solvent, a compound having the general formula I—R wherein R is a fluorocarbon, and a reductant.

A silane compound having a secondary amino group protected with a specific silyl group is useful as silane coupling agent, resin additive, textile treating agent, surface treating agent, paint additive, and adhesive.

A dual end glycerol (meth)acrylate-modified silicone having formula (I): R1Me2SiO(R22SiO)aSiMe2R1 is novel. R1 is a mixture of 70-95 mol % of a group having formula (i) and 30-5 mol % of a group having formula (ii) wherein R3 is H or methyl, R2 is a monovalent hydrocarbon group which may be halogenated, Me stands for methyl, and a is an integer of 10-300.