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[ASAP] Development and Production of an Enantioselective Tetrahydroisoquinoline Synthesis Enabled by Continuous Cryogenic Lithium–Halogen Exchange

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00141




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Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00322K, Paper
Open Access
Elba Ochoa, Wilson Henao, Sara Fuertes, Daniel Torres, Tomas van Haasterecht, Elinor Scott, Harry Bitter, Isabel Suelves, Jose Luis Pinilla
Evaluation of the dispersion of Pd active sites on the catalyst performance during fatty acids decarbonylation to α-olefins was explored in this work. Pd subnanometric particles, clusters and aggregates were found to modulate the catalyst activity.
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Computational investigation of the ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02562F, Paper
Pan Li, Chaoren Shen, Jie Min, Jing-Yuan Mei, Huan Zheng, Lin He, Xinxin Tian
The ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation has been discussed.
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Synergistic photocatalysis–Fenton reaction for selective conversion of methane to methanol at room temperature

Catal. Sci. Technol., 2020, 10,2329-2332
DOI: 10.1039/D0CY00028K, Communication
Yi Zeng, Hang Chen Liu, Jing Sheng Wang, Xing Yang Wu, Song Ling Wang
Combining the photocatalysis and Fenton reaction highly promote the yield and selectivity of CH3OH from CH4 with solar light at room temperature, up to 471 μmol g−1 h−1 and 83%, respectively.
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Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
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Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
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Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
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Loop engineering of aryl sulfotransferase B for improving catalytic performance in regioselective sulfation

Catal. Sci. Technol., 2020, 10,2369-2377
DOI: 10.1039/D0CY00063A, Paper
Yu Ji, Shohana Islam, Haiyang Cui, Gaurao V. Dhoke, Mehdi D. Davari, Alan M. Mertens, Ulrich Schwaneberg
Loop engineering of aryl sulfotransferase B improves catalytic performance in regioselective sulfation.
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Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
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Self/made / writer, Mat Groom ; artist, Eduardo Ferigato ; colorist, Marcelo Costa ; color flats, Mariana Calil ; letterer, A Larger World Studios' Troy Peteri ; editor, Kyle Higgins

Barker Library - PN6728.S437 G76 2019




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American Gods: shadows / story and words by Neil Gaiman ; script and layouts by P. Craig Russell ; art by Scott Hampton ; letters by Rick Parker ; cover by David Mack

Barker Library - PN6728.A482 R87 2018




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Development of new self-assembled cationic amino liposomes for efficient gene delivery

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00331J, Communication
Yihang Wu, Yue Xiong, Ling Wang, Quanming Zhou, Linxian Li, Pavel A. Levkin, Gary Davidson, Liqian Gao, Wenbin Deng
A library of lipidoids self-assembling to liposomes exhibits excellent transfection efficiency in HEK 293T cells and mESCs with low cytotoxicity.
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Self-assembled nucleo-tripeptide hydrogels provide local and sustained doxorubicin release

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00134A, Paper
Kiheon Baek, Alexander David Noblett, Pengyu Ren, Laura J. Suggs
Doxorubicin is intercalated within the nanofibril structure of self-assembled nucleo-peptide hydrogels and injection leads to decrease in tumor volume and greater concentration of chemotherapeutic relative to soluble form.
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A disulfide based low molecular weight gel for the selective sustained release of biomolecules

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00508H, Paper
Nitin D. Bansode, Kotagudda Ranganath Sindhu, Chloe Morel, Murielle Rémy, Julien Verget, Claudine Boiziau, Philippe Barthélémy
Constructing biocompatible soft materials via supramolecular approaches remains an important challenge for in vivo applications.
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Enhanced selectivity, cellular uptake, and in vitro activity of an intrinsically fluorescent copper–tirapazamine nanocomplex for hypoxia targeted therapy in prostate cancer

Biomater. Sci., 2020, 8,2420-2433
DOI: 10.1039/C9BM01905G, Paper
Vera L. Silva, Abdessamad Kaassis, Ashkan Dehsorkhi, Cédrik-Roland Koffi, Maja Severic, Moustafa Abdelhamid, Duuamene Nyimanu, Christopher J. Morris, Wafa’ T. Al-Jamal
Cu(TPZ)2 complex as a promising hypoxia selective cytotoxin in prostate cancer.
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A thermo-responsive, self-assembling biointerface for on demand release of surface-immobilised proteins

Biomater. Sci., 2020, 8,2673-2681
DOI: 10.1039/C9BM01957J, Paper
Angela Saccardo, Mikhail Soloviev, Enrico Ferrari
Engineering of the neuronal SNARE proteins yields chimeric bio-materials that reversibly assemble and disassemble at set temperatures.
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A multifunctional metal-biopolymer coordinated double network hydrogel combined with multi-stimulus responsiveness, self-healing, shape memory and antibacterial properties

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00425A, Paper
Kun Yan, Feiyang Xu, Chunyu Wang, Yingying Li, Yuanli Chen, Xiufang Li, Zhentan Lu, Dong Wang
A universal, straightforward macroscale assembly technology has been presented for fabrication of polysaccharide-based multifunctional DN gels based on metal coordination chemistry.
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A super-stretchable, self-healing and injectable supramolecular hydrogel constructed by a host–guest crosslinker

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00290A, Paper
Yang Zhou, Yuanhao Zhang, Zhaobo Dai, Fang Jiang, Jia Tian, Weian Zhang
Supramolecular hydrogels based on host–guest interactions have drawn considerable attention due to their unique properties and promising applications.
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Working closely with states on labour reforms to help industry: Centre

The Confederation of Indian Industry (CII) suggested to the Labour Ministry to "direct workers to join back to their workplace" by issuing a circular




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RGD functionalized chitosan nanoparticle mediated targeted delivery of raloxifene selectively suppresses angiogenesis and tumor growth in breast cancer

Nanoscale, 2020, Advance Article
DOI: 10.1039/C9NR10673A, Paper
Amit S. Yadav, N. Naga Venkata Radharani, Mahadeo Gorain, Anuradha Bulbule, Dattatrya Shetti, Gaurab Roy, Thejus Baby, Gopal C. Kundu
Peptide functionalized pH sensitive raloxifene-chitosan nanoparticles with high biocompatibility synergistically inhibit tumor growth and angiogenesis in breast cancer.
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Mechanistic Insight in Site-selective and Anisotropic Etching of Prussian Blue Analogues toward Designable Complex Architectures for Efficient Energy Storage

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02241A, Paper
Hai Xu, Xi Zhao, Chenyang Yu, Yue Sun, Zengyu Hui, Ruicong Zhou, Jialu Xue, Henghan Dai, Yue Zhao, Lumin Wang, Yujiao Gong, Jin Yuan Zhou, Jianing An, Qiang Chen, Gengzhi Sun, Wei Huang
Engineering coordination compounds, e.g., prussian blue (PB) and its analogues (PBAs), with designable complex nanostructures via chemical etching holds great opportunities for improving energy storage performances by adjusting topological geometry,...
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Self-responsive co-delivery system for remodeling tumor intracellular microenvironment to promote PTEN-mediated anti-tumor therapy

Nanoscale, 2020, 12,9392-9403
DOI: 10.1039/D0NR00563K, Paper
Yifei Wang, Ruiting Wang, Sixuan Wu, Jingyi An, Yan Liang, Lin Hou, Zhenzhong Zhang
Delivering the pten gene into tumor cells to reacquire PTEN functionality is considered to be an attractive method for cancer treatment.
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A unique synthesis of rare-earth-Co-based single crystal particles by “self-aligned” Co nano-arrays

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR00490A, Paper
Qiong Wu, Liying Cong, Yue Ming, Chenglin Li, Zhenhui Ma, Xiangyu Ma, Yatao Wang
In this study, anisotropic SmCo5 magnets were prepared by a distinctive method, which is the high-temperature reductive annealing of Co@Sm2O3 with specially designed nanostructure. High resolution transmission electron microscope and...
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Florida capitol old as the state itself




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Is world's most photographed vessel




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Frederick Delius found himself in Florida




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Summary of selected post-enactment living wage studies




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Review of selected pre-enactment living wage studies




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Self organization in disaster response and recovery




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Reliability of delayed self-reports in disaster research




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Del Ingeniero Sergio Salas Arias, Gerente General SENARA, para el Licenciado José Manuel Echandi, counselor, Defensoría de Los Habitantes




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I dreamt of Africa, but awoke to find myself in Costa Rica : my experiences working at The Monteverde Institute




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The marriage record of Crowson, Charles A. and Mansell, Dulcina M




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The marriage record of Mobley, George R. and Fussel, Anna J




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The marriage record of Williams, David and Basden, Selina




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The marriage record of Selsemeyer, Edward Y. and Payne, Agnes




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The marriage record of Moseley, Daniel H. and Mardre, Maggie S




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The marriage record of Harrison, Sela P. and Thomaspon, Eugenia G




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The marriage record of Green, William A. and Moseley, Cora L




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The marriage record of Bryant, William J. and Trapnell, Selina A




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The marriage record of Selridge, C. T. and Reed, Ada U




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The marriage record of Dishong, Charles C. and Selner, Emma




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The marriage record of Lundgren, Charles G. and Brosell, Henrietta