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Ball milling-promoting difunctionalization of alkynyl sulfonium salts with sulfinic acids towards (Z)-1,2-disulfonylethenes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04895D, Paper
Li-Hua Yang, Bei Li, Lin Chen, Wen-Shi Yao, Han-Yue Peng, Sha Peng, Long-Yong Xie
A simple ball milling-mediated disulfonylation of alkynyl sulfonium salts with sulfinic acids for the stereoselective synthesis of various (Z)-1,2-disulfonylethenes has been developed under catalyst-, additive- and solvent-free conditions.
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EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The big promotion

Remo has shown that even an average film can be turned into a superhit if marketed aggressively enough




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Lions stare down back-from-the-dead RCB

The victor goes straight to the final; the loser gets another shot, plays winner of Eliminator



  • Indian Premier League

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Takeaways from the 2018 IPL auction

Surprising bids and non-bids during the auction weekend in Bengaluru




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CSK-SRH match ticket sales from April 18



  • Indian Premier League

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Tips from Ms. Twinkle toes

On the eve of International Dance Day, Madhuri Dixit talks about dance as a means to overcome grief and aggression




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Bajaj commences production of 400-cc bike from Chakan plant




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From luxury SUVs to city-smart hybrids, here’s a quick look at the cars that are turning heads this month

This month has been unusually busy in the Indian automotive industry with most major players dropping new models. Here’s a roundup of what we drove.



  • Life & Style

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'Keep Gambhir Away From Media'

'Rohit and amp; Agarkar, much better guys to front up for the media.'




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PCB seeks clarity from ICC over Ind's CT participation

A hybrid model was followed during the Asia Cup last year, when India's matches were held in Sri Lanka while other matches were played in Pakistan.




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Do Our Pacers Need Tips From Pak Pacers?

Pakistan's ODI series victory in Australia showcased the raw pace and skill of their fast bowling attack, spearheaded by Haris Rauf.




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Will Dhruv Jurel steal the spotlight from Pant?

Paine, who coached Australia A in the recent series against India A, witnessed Jurel's exploits in the second 'unofficial' Test where the 23-year-old scored an 80 and 68 at Melbourne.




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Mohammad Nabi to retire from ODIs after...

Afghanistan all-rounder Mohammad Nabi has announced that he will retire from One-Day Internationals after next year's Champions Trophy in Pakistan.




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Delhi-NCR: Smog envelopes city as AQI remains in 'very poor' category for 15th consecutive day, mercury to drop from...

The Air Quality Index (AQI) of the national capital remained in 'very poor' category for the 15th consecutive day on Wednesday, i.e., November 13.




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Building Pune: Elevated e-way from Pune to Sambhajinagar to expedite travel by 2 hrs




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Maharashtra Assembly elections: NCP fields MLA Sunil Tingre from Vadgaonsheri despite opposition from local BJP unit




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Fake CBI officer arrested for demanding Rs 12 lakh from owner of Pimpri Chinchwad company




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Facing challenge from nephew, Ajit Pawar says confident Baramatikars will keep his pride intact




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SPPU invites PhD applications from NET-qualified applicants




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2019 re-run in both seats: Cong fields former minister Bagwe from Cantonment, Bahirat from Shivajinagar




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Bursting crackers? Here are the Dos and Don’ts from Fire Department




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Pune advocates send legal notice to EC, seek clarification on quota promises ahead of Maharashtra polls




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Indigo to launch direct flights from Pune to Dubai from Nov 22




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Health risk from excessive heat rising in India, says new Lancet report




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Pune police bust gang smuggling marijuana from Odisha on train, seize drugs worth Rs 12 lakh




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Old friends turn foes in Ambegaon as seven-time MLA Dilip Walse Patil faces stiff challenge from Devdutta Nikam




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Maharashtra Assembly polls: Congress fails to get rebels to withdraw from Pune seats




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Sharad Pawar hints at retirement from parliamentary politics, bats for Yugendra in Baramati Assembly constituency




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Ajit Pawar says MVA’s poll promises will deplete coffers, alleges hypocrisy citing opposition to Ladki Bahin Yojana




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Porsche crash: Cops secure production warrant of father of minor co-passenger, take custody from prison




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Maharashtra Assembly polls: Back from Glasgow, 28-year-old lawyer contesting in Hadapsar on VBA ticket, advocates for minority rights




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Pune’s elderly celebrate first-ever ‘Vote from Home’ with enthusiasm and gratitude




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Ladki Bahin Yojana helps to swing some women voters, fails to move others from their political inclination




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Maharashtra Election 2024 Live Updates: ‘It is alleged that Cong using money looted from Karnataka for assembly polls in state,’ says PM Modi at Pune rally




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Amol Khatal, grandson of Congress leader B J Khatal, seeks to oust Sangamner MLA Balasaheb Thorat from his constituency of decades




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Who is Allah Mohammad Ghazanfar? R Ashwin fan, who swears by carrom ball, claims six wickets in Afghanistan win over Bangladesh




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Magnus Carlsen on what’s affecting Ding Liren: ‘He’s not completely recovered from last world championship’




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ISL: How Hyderabad FC came from behind to stun Kerala Blasters in Indian Super League clash




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England legend Ian Botham rescued from fall in crocodile, shark-infested river by former Aussie rival Merv Hughes




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Why Rory McIlroy spent a month away from golf, in a studio hitting balls against a screen?




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Border Gavaskar Trophy : ‘Now we’re almost picking our Test team not just from Shield form,’ says former Australian captain Mark Taylor




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Saim Ayub: School prodigy from Pakistan, trolled by former cricketers, inspired by Pant and now dominates Australia’s Starc, Cummins, and Zampa




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What Gautam Gambhir’s 46 all out team can learn from Ravi Shastri’s 36 all out BGT comeback?




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South Africa vs India: How did Sanju Samson recover from his slump to hit two successive T20I hundreds




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Lionel Messi scores but Inter Miami suffer stunning first-round elimination from MLS playoffs




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‘It was pretty clear to us where CA’s priorities lie’: Pakistan coach Jason Gillespie on Cricket Australia promoting BGT ahead of ODI series against Pakistan




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Afghanistan all-rounder Mohammad Nabi to retire from ODIs after Champions Trophy 2025




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22-year-old Ecuador international footballer Marco Angulo dies from injuries sustained in car crash




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IPO-bound Hyundai raises Rs 8,315 cr from investors

Hyundai Motor India (HMIL) raised Rs 8,315 crore from anchor investors on Monday, setting the stage for the country's biggest-ever maiden share sale.