Phys. Chem. Chem. Phys., 2024, 26,27751-27762
DOI: 10.1039/D4CP03534H, Paper

Po-Jen Hsu, Atsuya Mizuide, Jer-Lai Kuo, Asuka Fujii
Infrared spectroscopy combined with a deep-learning structure sampling approach reveals the origin of the unusual structure preference in protonated fluorinated alcohol clusters.
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Phys. Chem. Chem. Phys., 2024, 26,27741-27750
DOI: 10.1039/D4CP02722A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Simon U. Okafor, Gabriele Pinto, Michael Brdecka, William Smith, Tucker W. R. Lewis, Michael Gutierrez, Darrin J. Bellert
Rate-limiting hydrogen/deuterium tunneling rate constants are measured in the photon initiated decay of Co(CH₃COOH)⁺ with small KIE values.
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03093A, Paper

Kazuki Shun, Akihito Fujimoto, Kohsuke Mori, Hiromi Yamashita
The interparticle hydrogen spillover can be facilitated over TiO₂ and WO₃ as a consequence of the interfacial diffusion of H⁺ and e⁻ pairs, while the e⁻ diffusion coupled with H⁺ is inhibited on MgO and CeO₂.
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03153A, Paper

Jiake Fan, Lei Yang, Hui Li, Zijian Sun, Mengyun Mei, Weihua Zhu
The chlorine evolution reaction (CER) is a crucial solution for treating chlorine-containing wastewater, a type of wastewater generated during the chemical production process.
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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP02875A, Paper

Nicholas Adu-Effah, Nabanita Saikia
Non-canonical nucleobase pairs differ from canonical Watson-Crick (WC) pairs in their hydrogen bonding patterns. This study uses density functional theory with empirical dispersion correction to examine the stability and electronic...
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03697B, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Ahmet Altun, Eduardo Schiavo, Michael Mehring, Stephan Schulz, Giovanni Bistoni, Alexander A. Auer
Combined Hartree–Fock plus London Dispersion (HFLD) and fragment-pairwise Local Energy Decomposition (fp-LED) enables computation of lattice energies, their breakdown into pairwise terms, and assessment of relative stability sources in polymorphs.
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03784G, Paper

Shuyan Xu, Jian Wang, Chuncai Shan, Kaixian Li, Huiyuan Wu, Gui Li, Shaoke Fu, Qionghua Zhao, Yi Xi, Chenguo Hu
Direct current triboelectric nanogenerator (DC-TENG) utilized air-breakdown effect to collect triboelectrification charges from dielectric tribo-layers, providing a new type of mechanical energy harvesting mode for TENGs, which has demonstrated its...
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Chem. Soc. Rev., 2024, 53,3327-3349
DOI: 10.1039/D3CS00699A, Review Article

Anastasiia D. Vlasova, Siarhei M. Bukhalovich, Diana F. Bagaeva, Aleksandra P. Polyakova, Nikolay S. Ilyinsky, Semen V. Nesterov, Fedor M. Tsybrov, Andrey O. Bogorodskiy, Egor V. Zinovev, Anatolii E. Mikhailov, Alexey V. Vlasov, Alexander I. Kuklin, Valentin I. Borshchevskiy, Ernst Bamberg, Vladimir N. Uversky, Valentin I. Gordeliy
Organelle optogenetics is an approach to control cell physiology by targeted expression of microbial rhodopsins in membranes of subcellular organelles.
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Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article

Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05026F, Highlight

Hangqian Fan, Yuxin Fang, Jingbo Yu
Direct functionalization of alkenes with C(sp³)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication

Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication

Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO₃ NSs) were fabricated as SERS substrates.
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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication

Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)₂ at 23 °C.
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Chem. Commun., 2024, 60,13388-13391
DOI: 10.1039/D4CC04732J, Communication

Zhenchuan Yu, Biaolong Ma, Jiqiang Wang
A strategy to fabricate ultra-tough ionogels by ionic induction is proposed, which provides a simple and general method for tuning ionogel properties.
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Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00106K, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Sijie Xian, Yuanhui Xiang, Svenja Deichmann, Matthew J. Webber
New diol chemistries are explored for insulin delivery from glucose-responsive hydrogels comprised of dynamic-covalent crosslinking interactions between phenylboronic acids and diols.
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Mol. Syst. Des. Eng., 2024, 9,1107-1115
DOI: 10.1039/D4ME00112E, Paper

Yongbaek Kim, Hiroto Isobe, Keishi Nishio, Kazuki Murai
Biomineralization has garnered attention not only for its fundamental role in understanding the mechanisms of biomineral formation but also as a method for fabricating next-generation functional materials.
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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00067F, Communication

Manish Kumar Dixit, Moupia Mukherjee, Bharat Kumar Sahu, Abul Kalam, Mrigendra Dubey
Herein, we report a dual acid/base responsive fluorescent and simultaneous reversible phase transformative organohydrogel (OHG).
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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00131A, Paper

Ramalingam Mahaan, Murugesan Panneerselvam, Luciano T. Costa, Aruljothy John Bosco
The effects of heavy atoms and oxidation states in chalcogen groups on D(X)BNA cores, combined with substitutions of weak and strong donors, led to the identification of potential TADF and RTP molecules among the 14 molecules.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ04581A, Paper

Yi Shan, Jiayu Lu, Na Li, Xiaoxue Mo, Cheng Wang, Huaizhen He
This article reports that exogenous analogues of the neuropeptide substance P can activate MRGPRX2 to trigger pseudo-allergic reactions.
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00559G, Paper

Gerald Lepcha, Indrajit Pal, Santanu Majumdar, Yogesh Dhasmana, Sanjay Mondal, Ennio Zangrando, Deepak Chopra, Biswajit Dey
Supramolecular self-assembly directed two unique organogels were achieved through varying gel-immobilized solvents. One gel is comprised of adipic acid (ADP) and triethanolamine (TEA) in pure dimethylformamide medium (i.e., ADP-TEA-DMF), while...
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00502C, Paper

Dong Wang, Zihan Guo, Zhiwei Wang, Yanfang Gao
The excellent electrochemistry performance is attributed to vanadium nitride quantum dots (VNQDs) offering large capacity and nitrogen-doped reduced graphene oxide (NrGO) acting as a conductive network and buffer skeleton.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00664J, Paper

Lidan Deng, Xingwang Liu, Chong Chen, Lu Wang, Fan Liu, Jie Zhang
The pyrolysis in H₂ at lower temperatures can obtain MNP/MOF with more complete MOFs structure and dispersed Ni–Co alloy nanoparticles, which display significantly better activity for the hydrogenation of toluene to methylcyclohexane.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00820K, Paper

Open Access

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Jie Zou, Yi Pan, Di Zhang, Jie Zhang, Weilong Chen, Hongyan Sun, Kai-Chung Lau, Jingdong Luo
Direct transfer hydrogenation from a strong electron donor to highly polarizable hemicyanines was discovered in the synthesis of push–pull chromophores. The reaction mechanism and experimental results were elucidated using DFT calculations.
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New J. Chem., 2024, 48,7405-7412
DOI: 10.1039/D4NJ00622D, Paper

Yi Zhang, Yingming Zhu, Kejing Wu, Yingying Liu, Houfang Lu, Bin Liang
Choline chloride–lactic acid deep eutectic solvent assisted by ball milling effectively dissolved microcrystalline cellulose. Regenerated cellulose was used to prepare novel cellulose hydrogel with self-reinforced mechanical properties.
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New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper

Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO₃–MoSe₂ encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
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New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper

Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00361F, Paper

Guanglei Liu, Yutong Feng, Yifan Yang, Yuan Wang, Huixiang Liu, Can Li, Mingxin Ye, Jianfeng Shen
Construction of NiCo₂S_4−xP_x nanowire arrays for improved HER performances in both acidic and alkaline media.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05752F, Paper

Huamei Yang, Ziqin Chen, Kai Luo, Mengjun Yu, Yao Zhang
Surface chemical etching for the in situ growth of metal–organic materials and electrochemical reconstruction are expected to efficiently improve the catalytic performance of oxygen evolution reactions (OERs).
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00310A, Paper

Chenchen Ji, Xinhong Lin, Yang Hong, Junfeng Liu, Aoteng Liu, Yijia Yao, Sicheng Liu, Hongyu Mi
A hydrogel electrolyte was designed by constructing a multi-crosslinked network. The quasi-solid-state ZHSC based on the hydrogel electrolyte and HSSPC delivers a high specific capacity, high energy/power densities, and good cycle stability.
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00797B, Paper

Venkatachalam Ananth, Venkatesan Senthilnathan, Murugan Veerapandian, Neelamegam Rajasekaran
Electrochemical energy conversion for hydrogen production is a crucial method to address global energy demand. Here, a cost-effective approach for the preparation of transition metal-based alloy electrode through electrodeposition with...
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01677G, Paper

Pragnesh N Dave, Pradip Macwan
The present work involves the Gum ghatti-cl-poly(NIPAm)/-o-MWCNT (GGNIPACNT) hydrogels via free radical polymerization technique. The synthesized hydrogels were characterized by FTIR analysis which suggested the successful binding of -o-MWCNT in...
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01321B, Paper

Zili Xu, Yuankang Bao, Xun Xu, Ping Li, Hao Zhang, Deliang Li, Shuwang Duo
Seawater, a plentiful natural resource, is promising for hydrogen production compared to traditional electrocatalytic methods based on high-purity freshwater. This strategy shift addresses the challenge of limited freshwater resources and...
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00883E, Paper

Lucija Božičević, Korinna Altmann, Jana Hildebrandt, Xenia Knigge, Valerije Vrček, Nikolina Peranić, Nikolina Kalčec, Ivana Vinković Vrček
This study provides science-based evidence on endocrine disrupting effects of polyethylene, polystyrene and polypropylene nanoparticles and their mixtures indicating the importance of hazard assessment of aggregate exposure to nanoplastics.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00929G, Critical Review

Yiqun Mo, Yue Zhang, Qunwei Zhang
This review summarized the cytotoxic, genotoxic, and carcinogenic effects of Ni-containing NPs on humans, lung cells in vitro, and rodent lungs in vivo, and the underlying mechanisms. Their extra-pulmonary effects were also briefly mentioned.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00839H, Paper

S. Aisvarya, M. Kalyanasundaram, M. Kannan, P. Arunkumar, S. Preetha, K. Elango, K. Govindaraju
Utilizing environmentally friendly nanomaterials to address insect pests and promote plant growth is imperative.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper

Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper

Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00070F, Paper

Yuying Ren, Xiaona Li, Bingxu Cheng, Le Yue, Xuesong Cao, Chuanxi Wang, Zhenyu Wang
Tannic acid derived carbon dot (TACD)-embedded gelatin hydrogels (GTACDs) were formed by hydrogen bonding and electrostatic interactions, which as seed coating were applied to drought soil to enhance crop drought resistance and growth.
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Environ. Sci.: Nano, 2024, 11,1442-1451
DOI: 10.1039/D3EN00910F, Paper

Chaoqun You, Xinyue Ji, Hanchen Lin, Ning Ma, Wei Wei, Lingfeng Long, Like Ning, Fei Wang
A stimuli-responsive hydrogel for fungicide delivery based on UV-sensitive molecular (AZO)-conjunct CNCs is successfully prepared.
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Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper

Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg²⁺ and As³⁺ in drinking water to protect human health.
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Environ. Sci.: Nano, 2024, 11,1622-1635
DOI: 10.1039/D3EN00554B, Paper

Tahereh Nasiriani, Neda Adabi Nigjeh, Ahmad Shaabani
This study deals with the synthesis of a core–shell magnetic zinc-based molecularly imprinted polymer (M-Zn-MIP) as a robust heterogeneous catalytic nanoreactor. The catalytic activity of the M-Zn-MIP was explored in the CO₂ fixation reaction.
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Environ. Sci.: Nano, 2024, 11,1740-1754
DOI: 10.1039/D4EN00072B, Paper

Wadha Alfalasi, Tanveer Hussain, Nacir Tit
Selective detection of toxic nitrogen-containing gases (e.g. NO and NO₂) is achieved when special transition metal (TM) atoms are selected in doping molybdenum disulfide (MoS₂) monolayer. The change of magnetic state is the secret of that selectivity.
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Environ. Sci.: Nano, 2024, 11,1521-1532
DOI: 10.1039/D3EN00808H, Paper

Sivakumar Musuvadhi Babulal, Nandini Nataraj, Tse-Wei Chen, Shen Ming Chen, Bih-Show Lou, Arshad Mehmood Abbasi, Amal M. Al-Mohaimeed, Mohamed Soliman Elshikh, Jaysan Yu
An improved electrochemical sensing platform with a vital strategy for NTM antiandrogen drug detection in real environmental and biofluid samples.
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CrystEngComm, 2024, 26,1952-1961
DOI: 10.1039/D4CE00010B, Paper

Showkat Rashid, Ahmad Husain, Bilal A. Bhat, Goverdhan Mehta
This article examines C–H⋯O and O–H⋯O hydrogen-bonded patterns in polyoxygenated decalins, showcasing varied supramolecular architectures influenced by oxyfunctionalisation and surrogate carbonate groups.
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