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How to Specify User Agent with cURL

Over the years I’ve shared how to perform a number of actions with cURL: how to send POST data, how to retrieve headers, follow redirects, check GZIP encoding, and more. Another useful cURL directive is sending the user agent, as some servers respond with different content or headers depending on the user agent. Let’s have […]

The post How to Specify User Agent with cURL appeared first on David Walsh Blog.




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Agents late, fail to file plea in HC against curb on potato trade

Meanwhile, Subrata Biswas, principal secretary, department of agriculture and marketing, said they were ready for a legal explanation.




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Asymmetric copper-catalyzed conjugate additions of organometallic reagents in syntheses of natural compounds and pharmaceuticals

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00278J, Review Article
Denisa Vargová, Ivana Nemethova, Radovan Sebesta
Stereoselective synthesis of complex molecular structures is needed in medicine as well as in crop-protection. Copper-catalyzed 1,4-additions of organometallic reagents is a robust C-C bond formation strategy applicable in a...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of Biaryl Ketones by Arylation of Weinreb Amides with Functionalized Grignard Reagents under Thermodynamic Control vs. Kinetic Control of N,N-Boc2-Amides

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00813C, Communication
Guangchen Li, Michal Szostak
A highly efficient method for chemoselective synthesis of biaryl ketones by arylation of Weinreb amides (N-methoxy-N- methylamides) with functionalized Grignard reagents is reported. This protocol offers rapid entry to functionalized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Design FX - Agent Carter: Creating Movie-Quality Effects on a Weekly TV Schedule

In the new series “Agent Carter” Marvel expands its universe to the small screen with help from Industrial Light & Magic. Creating high-quality visual effects was nothing new for the the award-winning team, but working against grueling weekly delivery dates proved to be a monstrous challenge. Mike Seymour finds out how they did it.




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Unnecessarily Rushed Explanations - Best Music Game of All Time: Elite Beat Agents

Elite Beat Agents is based off a Japanese video game for Nintendo DS. But instead of male cheerleaders and Japanese pop songs, the U.S. version relies on “Men In Black”-like agents and good ol’ fashioned American hits from the Jackson 5 and Madonna. Chris Kohler explains why the stateside edition is the best music game of all time.




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Design FX - The Special Effects Behind Zero Matter in "Agent Carter"

We go behind the scenes to show you how visual effects company Double Negative created the dark energy Zero Matter in ABC's "Agent Carter."




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WIRED Tradecraft - Former FBI Agent Explains How to Read Body Language

Former FBI agent and body language expert Joe Navarro breaks down the various ways we communicate non-verbally. What does it mean when we fold our arms? Why do we interlace our fingers? Can a poker player actually hide their body language?




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WIRED Tradecraft - Former FBI Agent Breaks Down Gangsters' Body Language

Former FBI agent and body language expert Joe Navarro breaks down the body language of well known mobsters. Why did Bugsy Siegel dress so sharply? What does it mean when Mickey Cohen pinches his nose? Why does John Dillinger sit with his arms crossed? Joe Navarro teaches us what all these non-verbals REALLY mean.




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WIRED Tradecraft - FBI Agent Explains How Bombs Are Disposed Of

John Stewart, FBI agent and unit chief at the Hazardous Devices School, breaks down how bomb units in the police and military dispose of improvised explosive devices (IED) and other forms of ordnance. John explores the various disposal techniques used in the field, and explains how they keep themselves safe while investigating suspicious packages.




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[ASAP] Zinc Nitrate as an Activation Agent for the Synthesis of Nitrogen-Doped Porous Carbon and Its Application in CO<sub>2</sub> Adsorption

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00305




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[ASAP] Evaluation of Two Potassium-Based Activation Agents for the Production of Oxygen- and Nitrogen-Doped Porous Carbons

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00427




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Computer games: fourth Workshop on Computer Games, CGW 2015 and the fourth Workshop on General Intelligence in Game-Playing Agents, GIGA 2015, held in conjunction with the 24th International Conference on Artificial Intelligence, IJCAI 2015, Buenos Aires,

Online Resource




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[ASAP] Pd-Catalyzed Cross-Coupling of Highly Sterically Congested Enol Carbamates with Grignard Reagents via C–O Bond Activation

Organic Letters
DOI: 10.1021/acs.orglett.0c01127




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Becoming a real estate agent / Tom Chiarella

Browsery HD1382.C45 2019




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Contrast agents III [electronic resource] : radiopharmaceuticals from diagnostics to therapeutics / volume editor, Werner Krause ; with contributions by R. Alberto [and others]

Berlin ; New York : Springer-Verlag, [2005]




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SPIONs as nano-theranostics agents / Atefeh Zarepour, Ali Zarrabi, Arezoo Khosravi

Online Resource




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Drugs that changed the world: how therapeutic agents shaped our lives / Irwin W. Sherman

Hayden Library - RM300.S53 2017




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[ASAP] Supramolecular Encapsulation of Small-Ultrared Fluorescent Proteins in Virus-Like Nanoparticles for Noninvasive In Vivo Imaging Agents

Bioconjugate Chemistry
DOI: 10.1021/acs.bioconjchem.0c00190




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Web Intelligence and Intelligent Agent Technology, IEEE/WIC/ACM International Conference on [electronic journal].

IEEE Computer Society




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Autonomous Agents and Multiagent Systems, International Joint Conference on [electronic journal].

IEEE Computer Society




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2015 IEEE / WIC / ACM International Conference on Web Intelligence and Intelligent Agent Technology (WI-IAT) [electronic journal].

IEEE Computer Society




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2015 IEEE / WIC / ACM International Conference on Web Intelligence and Intelligent Agent Technology (WI-IAT) [electronic journal].

IEEE Computer Society




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2013 IEEE/WIC/ACM International Joint Conferences on Web Intelligence (WI) and Intelligent Agent Technologies (IAT) [electronic journal].

IEEE Computer Society




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2006 IEEE/WIC/ACM International Conference on Web Intelligence International Intelligence Agent Technology Workshops [electronic journal].

IEEE Computer Society




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Current biochemical understanding regarding the metabolism of acinetobactin, the major siderophore of the human pathogen Acinetobacter baumannii, and outlook for discovery of novel anti-infectious agents based thereon

Nat. Prod. Rep., 2020, 37,477-487
DOI: 10.1039/C9NP00046A, Highlight
Woon Young Song, Hak Joong Kim
This Highlight covers recently unveiled biochemical aspects the acinetobactin metabolism, a central iron acquisition mechanism of Acinetobacter baumannii, in addition to various efforts for therapeutic application of these findings.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Essential Reagents for Organic Synthesis / by Philip L. Fuchs, Andr?. Charette, Tomislav Rovis, Jeffrey W. Bode

Online Resource




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Horse gram: a cost-effective therapeutic agent




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[ASAP] Enhanced Selectivity and Stability of Cu/SiO<sub>2</sub> Catalysts for Dimethyl Oxalate Hydrogenation to Ethylene Glycol by Using Silane Coupling Agents for Surface Modification

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00789




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[ASAP] When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.0c00090




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Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A study on the effectiveness of anonymous agents in computer-supported collaborative learning (CSCL) for the facilitation of student learning and execution of team projects / Wudhijaya Philuek

Philuek, Wudhijaya, author




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Climate change perception and changing agents in Africa & South Asia / edited by Suiven John Paul Tume & Vincent Itai Tanyanyiwa

Hayden Library - QC903.2.A35 C55 2018




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[ASAP] Mechanism-Based Rational Discovery and <italic toggle="yes">In Vitro</italic> Evaluation of Novel Microtubule Stabilizing Agents with Non-Taxol-Competitive Activity

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.9b01133




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Agent running in the field / John Le Carré

Dewey Library - PR6062.E33 A72 2019




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Gold(III) bis(dithiolene) complexes: from molecular conductors to prospective anticancer, antimicrobial and antiplasmodial agents

Metallomics, 2020, Accepted Manuscript
DOI: 10.1039/D0MT00064G, Paper
Diana Fontinha, Silvia Andreia Sousa, Tânia S. Morais, Miguel Prudêncio, Jorge Leitão, Yann Le Gal, Dominique Lorcy, Rafaela Silva, Mariana Velho, Dulce Belo, Manuel Almeida, Joana Guerreiro, Teresa Pinheiro, Fernanda M. Marques
The anticancer, antimicrobial and antiplasmodial activities of six gold(III) bis(dithiolene) complexes were studied. Complexes (1-6) showed relevant anticancer properties against A2780/A2780cisR ovarian cancer cells (IC50 values of 0.08-2 µM), also...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enantiomeric Copper Based Anticancer Agents Promoting Sequence-Selective Cleavage of G-Quadruplex Telomeric DNA and non-random cleavage of plasmid DNA

Metallomics, 2020, Accepted Manuscript
DOI: 10.1039/D0MT00084A, Paper
Sabiha Parveen, J. A. Cowan, Zhen Yu, Farukh Arjmand
Copper-based binuclear enantiomeric complexes 1S and 1R were synthesized as anticancer chemotherapeutic agents to target G-quadruplex rich region of DNA and thoroughly characterized by various spectroscopic and single X-ray crystal...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heterobimetallic Ru(II)/Fe(II) complexes as potent anticancer agents against breast cancer cells, inducing apoptosis through multiple targets

Metallomics, 2020, 12,547-561
DOI: 10.1039/C9MT00272C, Paper
Adriana Pereira Mundim Guedes, Francyelli Mello-Andrade, Wanessa Carvalho Pires, Maria Alice Montes de Sousa, Paula Francinete Faustino da Silva, Mariana S. de Camargo, Hendryk Gemeiner, Menegário A. Amauri, Clever Gomes Cardoso, Paulo Roberto de Melo Reis, Elisângela de Paula Silveira-Lacerda, Alzir A. Batista
Antimetastatic activity, high selectivity and cytotoxicity for human tumor cell lines make ruthenium(II) complexes attractive for the development of new chemotherapeutic agents for cancer treatment.
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Development of Ketone-Based Brominating Agents (KBA) for the Practical Asymmetric a-Bromination of Aldehydes Catalyzed by Tritylpyrrolidine

ACS Catalysis
DOI: 10.1021/acscatal.0c01596




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Cottage Industry of Biocontrol Agents and Their Applications: Practical Aspects to Deal Biologically with Pests and Stresses Facing Strategic Crops / Nabil El-Wakeil, Mahmoud Saleh, Mohamed Abu-hashim, editors

Online Resource




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Handbook of flotation reagents : chemistry, theory and practice / Srdjan M. Bulatovic

Bulatovic, Srdjan M




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Hydroxyethyl sulfone based reactive coalescing agents for low-VOC waterborne coatings

RSC Adv., 2020, 10,17171-17179
DOI: 10.1039/D0RA00753F, Paper
Open Access
Jagjit Kaur, Ranganathan Krishnan, Balamurugan Ramalingam, Satyasankar Jana
Hydroxyethyl sulfone based compounds were revealed to exhibit characteristics of reactive coalescing agents towards application in environmentally-benign water borne coatings.
The content of this RSS Feed (c) The Royal Society of Chemistry




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FBI tries to fire Indian-origin agent who shot unarmed man



  • DO NOT USE Indians Abroad
  • World

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User agents

I was on the podcast A Question Of Code recently. It was fun! The podcast is aimed at people who are making a career change into web development, so it’s right up my alley.

I sometimes get asked about what a new starter should learn. On the podcast, I mentioned a post I wrote a while back with links to some great resources and tutorials. As I said then:

For web development, start with HTML, then CSS, then JavaScript (and don’t move on to JavaScript too quickly—really get to grips with HTML and CSS first).

That’s assuming you want to be a good well-rounded web developer. But it might be that you need to get a job as quickly as possible. In that case, my advice would be very different. I would advise you to learn React.

Believe me, I take no pleasure in giving that advice. But given the reality of what recruiters are looking for, knowing React is going to increase your chances of getting a job (something that’s reflected in the curricula of coding schools). And it’s always possible to work backwards from React to the more fundamental web technologies of HTML, CSS, and JavaScript. I hope.

Regardless of your initial route, what’s the next step? How do you go from starting out in web development to being a top-notch web developer?

I don’t consider myself to be a top-notch web developer (far from it), but I am very fortunate in that I’ve had the opportunity to work alongside some tippety-top-notch developers at ClearleftTrys, Cassie, Danielle, Mark, Graham, Charlotte, Andy, and Natalie.

They—and other top-notch developers I’m fortunate to know—have something in common. They prioritise users. Sure, they’ll all have their favourite technologies and specialised areas, but they don’t lose sight of who they’re building for.

When you think about it, there’s quite a power imbalance between users and developers on the web. Users can—ideally—choose which web browser to use, and maybe make some preference changes if they know where to look, but that’s about it. Developers dictate everything else—the technology that a website will use, the sheer amount of code shipped over the network to the user, whether the site will be built in a fragile or a resilient way. Users are dependent on developers, but developers don’t always act in the best interests of users. It’s a classic example of the principle-agent problem:

The principal–agent problem, in political science and economics (also known as agency dilemma or the agency problem) occurs when one person or entity (the “agent”), is able to make decisions and/or take actions on behalf of, or that impact, another person or entity: the “principal”. This dilemma exists in circumstances where agents are motivated to act in their own best interests, which are contrary to those of their principals, and is an example of moral hazard.

A top-notch developer never forgets that they are an agent, and that the user is the principal.

But is it realistic to expect web developers to be so focused on user needs? After all, there’s a whole separate field of user experience design that specialises in this focus. It hardly seems practical to suggest that a top-notch developer needs to first become a good UX designer. There’s already plenty to focus on when it comes to just the technology side of front-end development.

So maybe this is too simplistic a way of defining the principle-agent relationship between users and developers:

user :: developer

There’s something that sits in between, mediating that relationship. It’s a piece of software that in the world of web standards is even referred to as a “user agent”: the web browser.

user :: web browser :: developer

So if making the leap to understanding users seems too much of a stretch, there’s an intermediate step. Get to know how web browsers work. As a web developer, if you know what web browsers “like” and “dislike”, you’re well on the way to making great user experiences. If you understand the pain points for browser when they’re parsing and rendering your code, you’ve got a pretty good proxy for understanding the pain points that your users are experiencing.




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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

Dalton Trans., 2020, 49,5420-5423
DOI: 10.1039/D0DT00842G, Communication
Luis M. Aguirre Quintana, Ningxin Jiang, John Bacsa, Henry S. La Pierre
The synthesis of coinage metal tris(dialkylamido)imidophosphorane complexes is reported, and the use of the silver(I) salt as an oxidative transmetallation reagent for the formation of a cerium(IV) complex is described.
The content of this RSS Feed (c) The Royal Society of Chemistry





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[ASAP] Novel Fungicide 4-Chlorocinnamaldehyde Thiosemicarbazide (PMDD) Inhibits Laccase and Controls the Causal Agent of Take-All Disease in Wheat, <italic toggle="yes">Gaeumannomyces graminis</italic> var. <italic toggle="ye

Journal of Agricultural and Food Chemistry
DOI: 10.1021/acs.jafc.0c01260




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Is a reagents shortage delaying European COVID-19 testing?

Fingers are being pointed in the Netherlands and the UK over reagent capacity constraints




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Ultrasound contrast agent enhances tissue imaging

Polymer-coated silica nanoparticles swell in response to pH changes




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[ASAP] Targeted Delivery of Anti-inflammatory and Imaging Agents to Microglial Cells with Polymeric Nanoparticles

Molecular Pharmaceutics
DOI: 10.1021/acs.molpharmaceut.9b00489