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Nuclear translocation of silver ions and hepatocyte nuclear receptor impairment upon exposure to silver nanoparticles

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01348B, Paper
Open Access
Vanessa Tardillo Suárez, Elizaveta Karepina, Mireille Chevallet, Benoit Gallet, Cécile Cottet-Rousselle, Peggy Charbonnier, Christine Moriscot, Isabelle Michaud-Soret, Wojciech Bal, Alexandra Fuchs, Rémi Tucoulou, Pierre-Henri Jouneau, Giulia Veronesi, Aurélien Deniaud
Upon exposure to non-toxic concentration of silver nanoparticles, only the ionic form of silver is found in the nucleus leading to an endocrine disruptor-like effect.
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Outstanding Reviewers for Environmental Science: Nano in 2019

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90015J, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Environmental Science: Nano in 2019, as selected by the editorial team for their significant contribution to the journal.
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Critical role of water stability in metal–organic frameworks and advanced modification strategies for the extension of their applicability

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01321K, Critical Review
Botao Liu, Kumar Vikrant, Ki-Hyun Kim, Vanish Kumar, Suresh Kumar Kailasa
Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).
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Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments enhances DNA damage and stress gene expression in freshwater Asian clam Corbicula fluminea

Environ. Sci.: Nano, 2020, 7,1252-1265
DOI: 10.1039/C9EN01270B, Paper
Chi-Wei Huang, Chun-Han Chang, Shang-Wei Li, Pei-Ling Yen, Vivian Hsiu-Chuan Liao
Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments increases mortality, Zn bioaccumulation, stress genes expression, and DNA damage in freshwater Asian clam Corbicula fluminea.
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Efficacy of chitosan/double-stranded RNA polyplex nanoparticles for gene silencing under variable environmental conditions

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00137F, Paper
Stuart S. Lichtenberg, Kanthi Nuti, Jason DeRouchey, Olga V. Tsyusko, Jason M. Unrine
Chitosan/dsRNA polyplex nanoparticles have shown great potential as insect biocontrol agents. Here, we show that polyplex nanoparticles have their gene silencing capacity altered by environmental variables.
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Peroxymonosulfate (PMS) activation on cobalt-doped TiO2 nanotubes: degradation of organics under dark and solar light irradiation conditions

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00131G, Paper
Jonghun Lim, Michael R. Hoffmann
The Co-TNT/PMS system enables the continuous degradation of organic pollutants under dark and solar light-irradiation conditions.
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2019 Best Papers published in the Environmental Science journals of the Royal Society of Chemistry

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90016H, Editorial
Kristopher McNeill, Paige J. Novak, Peter J. Vikesland
The Editors-in-Chief of the Environmental Science journals introduce the Best Papers of 2019.
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Nanoparticulate zero valent iron interaction with dissolved organic matter impacts iron transformation and organic carbon stability

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00197J, Paper
Yanlong Wang, Kun Yang, Daohui Lin
Although there is an increasing use of nanoparticulate zero-valent iron (nZVI) in the remediation of contaminated soil and water environments, there is still little understanding of the mechanisms of interaction...
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Integrating an Ag0-Ag+ mediated Ag2Ta4O11/Ag8(Nb0.5Ta0.5)26O69 Heterojunction to Timely Decontaminate Indoor Gaseous Formaldehyde under Natural Temperature, Humidity and Sunlight Irradiation

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00202J, Paper
Yuhang Wu, Meiting Song, Zhanli Chai, Jintian Huang, Xiaojing Wang
Formaldehyde (HCHO) is the primary pollutant in indoor, thus it is very essential to establish feasible proposal to decontaminate HCHO up to the accepted level in terms of human health....
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Environmental fate of sulfidated nZVI particles: the interplay of nanoparticle corrosion and toxicity during aging

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00075B, Paper
Jaroslav Semerád, Jan Filip, Alena Ševců, Miroslav Brumovský, Nhung H. A. Nguyen, Jiří Mikšíček, Tomáš Lederer, Alena Filipová, Jana Boháčková, Tomáš Cajthaml
This work describes an important, environmentally relevant phenomenon of metal nanoparticle aging in relation to the toxicity of nanomaterials; in this case, sulfidated nanoscale zero-valent materials intended for remediation purposes.
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Existence of untypical halogen-involving interactions in crystal packings: a statistical and first-principles study

CrystEngComm, 2020, 22,2756-2765
DOI: 10.1039/C9CE01885A, Paper
Yaser Balmohammadi, Hamid Reza Khavasi, S. Shahab Naghavi
There is a common perception by the scientific community that a halogen-involving interaction forms when the distance between the donor atom and the acceptor atom is less than the sum of their van der Waals (vdW) radii.
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New 2D layered structures with direct fluorine–metal bonds: MF(CH3COO) (M: Sr, Ba, Pb)

CrystEngComm, 2020, 22,2772-2780
DOI: 10.1039/D0CE00287A, Paper
S. Zänker, G. Scholz, M. Heise, F. Emmerling, E. Kemnitz
New coordination polymers with 2D network structures with fluorine directly coordinated to the metal ion were prepared both via mechanochemical synthesis and fluorolytic sol–gel synthesis.
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Melting point–solubility–structure correlations in chiral and racemic model cocrystals

CrystEngComm, 2020, 22,2766-2771
DOI: 10.1039/D0CE00014K, Paper
Ornella E. Y. Kilinkissa, Krishna K. Govender, Nikoletta B. Báthori
Comparison of chiral and racemic binary cocrystals showed that the chiral building block limits the formation of certain intermolecular interactions, decreases the packing efficiency, lowers the melting point and increases aqueous solubility.
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Agglomeration enhancement of AlN surface diffusion fluxes on a (0 0 0 1)-sapphire substrate grown by pulsed atomic-layer epitaxy techniques via MOCVD

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00113A, Paper
Mohd Nazri Abd Rahman, Yusnizam Yusuf, Afiq Anuar, Mohamad Raqif Mahat, Narong Chanlek, Noor Azrina Talik, Muhammad I. M. Abdul Khudus, Norzaini Zainal, Wan Haliza Abd Majid, Ahmad Shuhaimi
An atomically flat covering with a dense and crack-free surface of aluminium nitride films was successfully deposited on a sapphire-(0 0 0 1) substrate through a pulsed atomic-layer epitaxy technique via horizontal metalorganic chemical vapour deposition.
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A novel synthesis of YVO4:Ln3+ (Ln = Eu, Sm, and Dy) porous/hollow submicro-ellipsoids and their luminescence properties

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00526F, Paper
Shuang Zhao, Baiqi Shao, Yang Feng, Senwen Yuan, Langping Dong, Liang Zhang, Hongpeng You
A novel synthesis strategy of porous/hollow YVO4 submicro-ellipsoids with multicolor emissions has been developed based on the high structural matching of LYH and YVO4.
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Graphene-based SiC nanowires with nanosheets: synthesis, growth mechanism and photoluminescence properties

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00297F, Paper
Zhihui Hu, Zhi Chen, Juntong Huang, Mingge Yan, Meng Zhang, Lei Zhang, Xibao Li, Zhijun Feng
3C-SiC nanowires with nanosheets were synthesized via a direct reaction of Si vapor (from solid silicon) and SiO vapor (from silicon and silicon dioxide) with graphene nanosheets at 1500 °C without any additional metal catalyst.
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Self-assembled natLiCl–CeCl3 directionally solidified eutectics for thermal neutron detection

CrystEngComm, 2020, Advance Article
DOI: 10.1039/C9CE01884K, Communication
Shuangliang Cheng, Rachel E. Hunneke, Mengkun Tian, Eric Lukosi, Mariya Zhuravleva, Charles L. Melcher, Yuntao Wu
We developed novel LiCl–CeCl3 eutectic scintillators that are capable of detecting thermal neutrons.
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First Preparation of Microporous AFY-type MeAPO by Topotactic Pillaring of Lamellar Aluminophosphate Precursor

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00644K, Communication
Kazuyuki Maeda, Kentaro Wakui, Kyosuke Arakawa, Atsushi Kondo
Topotactic pillaring of lamellar aluminophosphate (ALPO) layers with zinc cations is used to prepare microporous zincoaluminophosphate (ZnAPO) with AFY-type framework for the first time. This approach should be promising for...
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Cocrystals/salt of 1-naphthaleneacetic acid and utilizing Hirshfeld surface calculations for acid–aminopyrimidine synthons

CrystEngComm, 2020, 22,2978-2989
DOI: 10.1039/D0CE00106F, Paper
Utsav Garg, Yasser Azim, Aranya Kar, Chullikkattil P. Pradeep
Revisit of acid–aminopyrimidine synthons to explore the robustness in presence of linear hetrotetramer and heterotrimer synthon.
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An Sc-based coordination polymer with concaved superstructures: preparation, formation mechanism, conversion, and their electrochemistry properties

CrystEngComm, 2020, 22,2926-2932
DOI: 10.1039/D0CE00086H, Paper
Hualan Xu, Ran Liu, Yongmei Zhu, Jinjiang Li, Changfeng Wan, Hang Zhang, Chuying Ouyang, Shengliang Zhong
Scandium-based coordination polymer octahedrons with concaved surfaces have been fabricated. The formation mechanism was also investigated. Sc2O3 octahedrons were obtained after simple calcination in a N2 atmosphere.
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A theoretical insight on the rigid hydrogen-bonded network in the solid state structure of two zinc(II) complexes and their strong fluorescence behaviors

CrystEngComm, 2020, 22,3005-3019
DOI: 10.1039/D0CE00125B, Paper
Ipsita Mondal, Tanmoy Basak, Snehasis Banerjee, Shouvik Chattopadhyay
A reduced Schiff base used as a fluorescence chemo-sensor for selective detection of zinc(II). Strong fluorescence behaviors of two zinc(II) complexes are correlated with the presence of a rigid hydrogen-bonded network in their solid state structure.
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Chirality and Stereoisomerism of Organic Multicomponent Crystals in the CSD

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00403K, Paper
Open Access
Eline Grothe, hugo meekes, Rene de Gelder
With the current interest in multicomponent crystals containing chiral residues, a wide variety of studies could benefit from a comprehensive inventory of chirality in multicomponent crystals. We combined computational approaches...
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Two Co-based MOFs assembled from an amine-functionalized pyridinecarboxylate ligand: inorganic acid-directed structural variety and gas adsorption properties

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00475H, Paper
Zhenzhen Jiang, Ping Zhou, Tingting Xu, Lihui Fan, Simin Hu, Jingxian Chen, Yabing He
A pair of Co-based MOFs exhibited inorganic acid-driven structural diversities, and one of them displayed the C2H2 separation and purification potential.
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A crystalline solid adduct of sulfathiazole-amantadine: The first dual-drug molecular salt containing both antiviral and antibacterial ingredients

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00368A, Paper
Ling-Yang Wang, Yueming Yu, Ming-Chao Yu, Yan-Tuan Li, Zhi-Yong Wu, Cui-Wei Yan
The first molecular salt concurrently combining antibacterial drug sulfathiazole (SFZ) and antiviral constituent amantadine (ATD) is designed and successfully synthesized via salification strategy. The precise structure of the newly obtained...
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Facile One–pot Solvothermal Synthesis of CdTe Nanorods and Their Photoelectrical Properties

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00459F, Communication
Binnian Zhong, Weifeng Kang, Zhiwei Zhang, Linhui Zhang, Bin Ma
Uniform CdTe NRs were synthesized by a one-pot PVP-assisted solvothermal process under mild conditions. By adjusting the amounts of the surfactant, reducing agent and the reaction temperature, CdTe NRs with...
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Kannur airport all set to receive expatriates: Minister

First flight with passengers from Dubai to land on May 12




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Virtual queue system likely for liquor sale

Consumers may have to register online and purchase at the time allotted




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A method to construct geographical crosswalks with an application to US counties since 1790 [electronic resource] / Fabian Eckert, Andrés Gvirtz, Jack Liang, Michael Peters

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Confirmatory bias in health decisions [electronic resource] : evidence from the MMR-Autism controversy / Mengcen Qian, Shin-Yi Chou, Ernest K. Lai

Cambridge, Mass. : National Bureau of Economic Research, 2020




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New frontiers in the internationalization of businesses : empirical evidence from indigenous businesses in Canada / Fernando Angulo-Ruiz.

New York : Routledge, 2020.




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The coronavirus and the Great Influenza Pandemic [electronic resource] : lessons from the "Spanish Flu" for the coronavirus's potential effects on mortality and economic activity / Robert J. Barro, José F. Ursúa, Joanna Weng

Cambridge, Mass. : National Bureau of Economic Research, 2020




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The coronavirus epidemic curve is already flattening in New York City [electronic resource] / Jeffrey E. Harris

Cambridge, Mass. : National Bureau of Economic Research, 2020




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The unprecedented stock market impact of COVID-19 [electronic resource] / Scott R. Baker, Nicholas Bloom, Steven J. Davis, Kyle J. Kost, Marco C. Sammon, Tasaneeya Viratyosin

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Aggregate and firm-level stock returns during pandemics [electronic resource] : in real time / Laura Alfaro, Anusha Chari, Andrew N. Greenland, Peter K. Schott

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Isolating the "tech" from EdTech [electronic resource] : experimental evidence on computer assisted learning in China / Yue Ma, Robert W. Fairlie, Prashant Loyalka, Scott Rozelle

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Paying outsourced labor [electronic resource] : direct evidence from linked temp agency-worker-client data / Andres Drenik, Simon Jäger, Pascuel Plotkin, Benjamin Schoefer

Cambridge, Mass. : National Bureau of Economic Research, 2020




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An SEIR infectious disease model with testing and conditional quarantine [electronic resource] / David W. Berger, Kyle F. Herkenhoff, Simon Mongey

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Data gaps and the policy response to the novel coronavirus [electronic resource] / James H. Stock

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Human mobility restrictions and the spread of the Novel Coronavirus (2019-nCoV) in China [electronic resource] / Hanming Fang, Long Wang, Yang Yang

Cambridge, Mass. : National Bureau of Economic Research, 2020




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Firm-level exposure to epidemic diseases [electronic resource] : Covid-19, SARS, and H1N1 / Tarek Hassan, Stephan Hollander, Laurence van Lent, Ahmed Tahoun

Cambridge, Mass. : National Bureau of Economic Research, 2020




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A new Japan for the twenty-first century : an inside overview of current fundamental changes and problems / Rien T. Segers, editor

London ; New York : Routledge, 2008





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FIRST PICTURES: Meet Kalki's baby, Sappho

Kalki Koechlin gave birth to a baby girl on February 7, and named her Sappho.







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PIX: Ranbir-Amitabh shoot Brahmastra

Amitabh Bachchan shared pictures from the sets of his upcoming film, Brahmastra.