tal Catalyst free PET and PEF polyesters using a new traceless oxalate chain extender By pubs.rsc.org Published On :: Green Chem., 2024, 26,11182-11195DOI: 10.1039/D4GC02791D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kevin van der Maas, Daniel H. Weinland, Robert-Jan van Putten, Bing Wang, Gert-Jan M. GruterWhen producing PET the metal catalyst (typically Sb) remains in the polymer. This raises concerns as our food and the air we breathe is contaminated with PET microplastics. Here we report the production of metal-free PET using a small amount of DGO.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Toward safer and more sustainable by design biocatalytic amide-bond coupling By pubs.rsc.org Published On :: Green Chem., 2024, 26,11147-11163DOI: 10.1039/D4GC03665D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Elisabeth Söderberg, Kerstin von Borries, Ulf Norinder, Mark Petchey, Ganapathy Ranjani, Swapnil Chavan, Hanna Holmquist, Magnus Johansson, Ian Cotgreave, Martin A. Hayes, Peter Fantke, Per-Olof SyrénWe describe an exploratory approach to a concept of safer and more sustainable by design in biocatalytic amide bond synthesis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Photocatalytic acylation of lysine screened using a microfluidic-based chemical robotic system By pubs.rsc.org Published On :: Green Chem., 2024, 26,11238-11248DOI: 10.1039/D4GC03562C, PaperZhanfeng Hou, Chuan Wan, Heming Jiang, Yuena Wang, Yun Xing, Jinpeng Wang, Zhihong Liu, Xiaochun Guo, Yuhao An, Wei Han, Rui Wang, Xinhao Zhang, Feng Yin, Zigang LiIn our work, we contribute to the photoredox catalytic lysine acylation in proteins and peptides. The optimal reaction conditions were obtained using a high-throughput microfluidic-based chemical robotic system and GPR model.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Catalytic synthesis of renewable lubricant base oils with methyl oleate and aromatics By pubs.rsc.org Published On :: Green Chem., 2024, 26,11249-11258DOI: 10.1039/D4GC03448A, PaperBinbin Zhou, Nan Wang, Sibao Liu, Guozhu LiuAromatic-ester and cyclo-branched alkane renewable lubricant base oils were produced from methyl oleate and biomass-derived aromatics by alkylation and alkylation followed by hydrodeoxygenation (HDO).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Selective electrosynthesis of aldehydes at industrially relevant current densities via tandem electrochemical–chemical catalysis By pubs.rsc.org Published On :: Green Chem., 2024, 26,11290-11302DOI: 10.1039/D4GC04536J, PaperTing Lin, Menglu Cai, Huijie Chen, Yiming MoA closed-loop tandem electrochemical–chemical catalysis system for aldehyde synthesis was developed, demonstrating a viable approach for the electrosynthesis of valuable intermediates under practical current densities with minimal waste electrolyte.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Chemodivergent alkylation of trifluoromethyl alkenes via photocatalytic coupling with alkanes By pubs.rsc.org Published On :: Green Chem., 2024, 26,11196-11205DOI: 10.1039/D4GC04176C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pol Martínez-Balart, Álvaro Velasco-Rubio, Sergio Barbeira-Arán, Hugo Jiménez-Cristóbal, Martín Fañanás-MastralA photocatalytic methodology for the chemodivergent direct cross-coupling of simple alkanes with trifluoromethyl alkenes that enables the selective formation of gem-difluoroalkenes and trifluoromethyl alkanes is presented.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Catalytic C–N bond formation strategies for green amination of biomass-derived molecules By pubs.rsc.org Published On :: Green Chem., 2024, 26,11019-11060DOI: 10.1039/D4GC03182B, Critical ReviewYan Zhong, Feng Liu, Jingsha Li, Chunxian GuoRecent advances in the amination of biomass-derived molecules to generate valuable nitrogenous chemicals by employing thermocatalysis, electrocatalysis and photocatalysis strategies are reviewed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Comparative techno-economic and life cycle assessment of electrocatalytic processes for lignin valorization By pubs.rsc.org Published On :: Green Chem., 2024, 26,11303-11315DOI: 10.1039/D4GC01963F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zahra Ebrahimpourboura, Manish Mosalpuri, Cheng Yang, Aditya Ponukumati, Corey Stephenson, Marcus Foston, Mark Mba WrightThis study explores the potential of using electrochemical (EC) methods for valorizing lignin, a lignocellulosic biomass cell wall component, into biofuels and high-value compounds.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Substrate-controlled regioselective hydrophosphorylation of allenes to enable photocatalytic synthesis of alkenylphosphoryl compounds By pubs.rsc.org Published On :: Green Chem., 2024, 26,11272-11279DOI: 10.1039/D4GC03588G, PaperTian-Ming Yang, Xin-Lu Fan, Wei Shi, Xuefei Zhao, Xu-Hong HuA visible-light-induced hydrophosphorylation of allenes with H-phosphine oxides is demonstrated to give a diverse range of alkenylphosphoryl compounds in a highly stereoselective and regioselective manner.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Iron/photoredox dual-catalyzed redox-neutral double decarboxylative C(sp3)–C(sp3) cross-coupling By pubs.rsc.org Published On :: Green Chem., 2024, 26,11334-11339DOI: 10.1039/D4GC04523H, PaperQi Zhang, Shanghui Wu, Xuesong WuAn efficient iron porphyrin/photoredox dual catalytic system for the double decarboxylative radical C(sp3)–C(sp3) cross-coupling under redox-neutral and mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions By pubs.rsc.org Published On :: Green Chem., 2024, 26,11316-11327DOI: 10.1039/D4GC04186K, PaperGuangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei NiuIn a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal A paired alkaline electrolyzer for furfural oxidation and hydrogen evolution over noble metal-free NiFe/Ni and Co/MXene catalysts By pubs.rsc.org Published On :: Green Chem., 2024, 26,11351-11363DOI: 10.1039/D4GC04447A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaopeng Liu, Mohammad Albloushi, Michael Galvin, Connor W. Schroeder, Yue Wu, Wenzhen LiA paired alkaline electrolyzer with non-noble metal catalysts was developed, demonstrating higher performances of furfural oxidation on NiFe/Ni foam at the anode and hydrogen evolution on Co/MXene at the cathode under practical current densities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate) By pubs.rsc.org Published On :: Green Chem., 2024, 26,11125-11131DOI: 10.1039/D4GC05070C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lee B. Anderson, Conall Molloy, Lorenzo Pedrini, Ian L. Martin, Stephen J. ConnonThe evaluation of a library of phase transfer catalysts in the alkaline hydrolysis of polyethylene terephthalate revealed the key interplay between catalyst structure/properties and the reaction conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Correction: Continuous production of 1,2-pentanediol from furfuryl alcohol over highly stable bimetallic Ni–Sn alloy catalysts By pubs.rsc.org Published On :: Green Chem., 2024, 26,11364-11364DOI: 10.1039/D4GC90117G, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ajaysing S. Nimbalkar, Kyung-Ryul Oh, Do-Young Hong, Byung Gyu Park, Maeum Lee, Dong Won Hwang, Ali Awad, Pravin P. Upare, Seung Ju Han, Young Kyu HwangThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis By pubs.rsc.org Published On :: Green Chem., 2024, 26,11177-11181DOI: 10.1039/D4GC04569F, PaperHaoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen LeiUnsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Converting waste PET into dimethyl terephthalate and diverse boronic esters under metal-free conditions By pubs.rsc.org Published On :: Green Chem., 2024, 26,11132-11139DOI: 10.1039/D4GC03358B, CommunicationMinghao Zhang, Yunkai Yu, Zhuo Wang, Shaoyu Zhang, Xiong Gao, Jiaming Liu, Jing Li, Weixiang Wu, Qingqing MeiAn ionic liquid-catalyzed metal-free approach was proposed to upcycle waste PET into dimethyl terephthalate and boronic esters, facilitated by multiple hydrogen bonds.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Reusable Co-catalysts for general and selective α-alkylation of nitriles with alcohols By pubs.rsc.org Published On :: Green Chem., 2024, 26,11140-11146DOI: 10.1039/D3GC04436J, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhuang Ma, Zechen Wu, Carsten Kreyenschulte, Stephan Bartling, Henrik Lund, Matthias Beller, Rajenahally V. JagadeeshA general cobalt-catalyzed α-alkylation of nitriles with alcohols is reported.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode By pubs.rsc.org Published On :: Green Chem., 2024, 26,11328-11333DOI: 10.1039/D4GC04617J, PaperHiroaki Tajima, Hideki Ishii, Shinsuke Inagi, Toshio FuchigamiA novel flow and circulation electrolytic system has been developed for the highly efficient cathodic hydrogenation of unsaturated compounds and dehalogenation of various aromatic halides.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Economic and environmental sustainability of bio-based HMF production and recovery from lignocellulosic biomass By pubs.rsc.org Published On :: Green Chem., 2024, 26,11340-11350DOI: 10.1039/D4GC04270K, PaperYuyao Jia, Shraddha Maitra, Lavanya Kudli, Jeremy S. Guest, Vijay SinghTransforming waste stream of biorefinery into high-value bioproducts.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC04640D, Tutorial ReviewGuanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua QiThis work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal CdS/Mg–Fe layered double hydroxide: a versatile heterogeneous photocatalyst for the acylation of indoles with α-keto acids By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC05239K, PaperJun-Bo Wang, Tong Yue, Ling Xu, Zhi-Qiang Hao, Zhan-Hui ZhangThe composite CdS/Mg–Fe layered double hydroxide was constructed and confirmed as an efficient recyclable heterogeneous photocatalyst for C-3 acylation of indoles with α-keto acids under light irradiation at room temperature.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Bio-derived solvent-based automated dispersive liquid–liquid microextraction for pretreatment of diamide insecticides in environmental water samples By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC04467C, PaperJin Liu, Yuxin Wang, Rui Song, Yukun Yang, Li Li, Xu JingThe automatic dispersive liquid–liquid microextraction based on bio-derived solvents achieved great environmental greenness, high-throughput operation, and low human error compared to the present sample pretreatment methods for diamide insecticides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal 1D/3D hierarchical carbon skeleton confined NiFe nanoparticles with optimized three-phase interfaces as tri-functional electrocatalysts By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC04466E, PaperYuqing Chen, Binyang Liu, Xuesong Liu, Jiahui Ye, Kuan Deng, Chengjie Wu, Qiang Niu, Tao Yang, Wen Tian, Junyi JiMultilevel 1D/3D CNTs/carbon spheres with hydrophilicity can promote the infiltration of an electrolyte into the interior and guide bubble diffusion, thus constructing an optimal gas–solid–liquid interface to enhance the electrocatalytic process.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione By pubs.rsc.org Published On :: Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC04541F, PaperWenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang LiuGreen and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Mechanoenzymatic Hydrolysis of Cotton to Cellulose Nanocrystals By pubs.rsc.org Published On :: Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC05113K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sandra Kaabel, Inge Schlapp-Hackl, Eero Kontturi, Mauri A. KostiainenSolid-state mechanoenzymatic approaches for the production of cellulose nanocrystals from cotton were examined using three commercially available cellulase systems from Trichoderma reesei, Aspergillus niger and a Cellic CTec2 cellulase blend....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC05207B, PaperYao Chai, Zirui Pang, Heng Jiang, Chi Chung Tsoi, Liang Wan, Yu Du, Huaping Jia, Yujiao Zhu, Detao Liu, Fengjia Xie, Guangya Zhou, Xuming ZhangThe direct electron transfer mechanism of single-layer Bi2MoO6 ultrathin nanosheets promotes the efficient regeneration of photocatalytic coenzyme NAD(P)H.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
tal A tale of two tattoos By www.thehindu.com Published On :: Sat, 04 Jun 2016 16:57:27 +0530 The tough choice of choosing a book or its cinematic adaptation Full Article Cinema
tal Gavaskar picks Chahal as best young talent of IPL-9 By www.thehindu.com Published On :: Tue, 31 May 2016 01:33:54 +0530 Full Article Indian Premier League
tal Talking comedy with Kapil By www.thehindu.com Published On :: Fri, 15 Apr 2016 21:03:38 +0530 Kapil Sharma reveals his professional secrets and tells us what to expect from his new show on Sony Entertainment Television Full Article Metroplus
tal Talk the talk By www.thehindu.com Published On :: Wed, 27 Apr 2016 15:53:17 +0530 Connecting with people matters the most, says RJ, actress and anchor Nyla Usha Full Article Television
tal Shaktimaan returns, nostalgia rules By www.thehindu.com Published On :: Sat, 14 May 2016 09:27:38 +0530 Full Article Entertainment
tal Daily Quiz | On American talk show hosts By www.thehindu.com Published On :: Wed, 25 Jan 2023 10:47:24 +0530 From analysing current events in a comedic fashion to creating the next viral moment with your favourite celebrity, hosts of talk shows are always on topic. Here is a quiz on American talk show hosts. Full Article Entertainment
tal Porsche crash: Govt gives sanction to prosecute Sassoon hospital doctors, staffer accused of changing blood samples By indianexpress.com Published On :: Thu, 24 Oct 2024 17:06:29 +0000 Full Article Cities Pune
tal 3 minors brutally stab youth to death over petty dispute By indianexpress.com Published On :: Sat, 26 Oct 2024 17:05:28 +0000 Full Article Cities Pune
tal Watch: Theft at Chitale Bandhu franchise on Pune’s Baner Road; probe underway By indianexpress.com Published On :: Sun, 27 Oct 2024 06:31:35 +0000 Full Article Cities Pune
tal Under ‘digital arrest’, Pune senior citizen loses Rs 45 lakh in cyber fraud By indianexpress.com Published On :: Sun, 27 Oct 2024 14:59:44 +0000 Full Article Cities Pune
tal Amol Khatal, grandson of Congress leader B J Khatal, seeks to oust Sangamner MLA Balasaheb Thorat from his constituency of decades By indianexpress.com Published On :: Tue, 12 Nov 2024 10:42:09 +0000 Full Article Cities Pune
tal IPL Auction 2025: Italy bowler Thomas Jack Draca in IPL long list By indianexpress.com Published On :: Wed, 06 Nov 2024 07:43:22 +0000 Full Article Cricket Sports
tal Delhi Capitals announce Munaf Patel as bowling coach ahead of IPL 2025 auction By indianexpress.com Published On :: Tue, 12 Nov 2024 14:06:04 +0000 Full Article Cricket Sports
tal Western Digital Is Offering A Rs 75,000 Scholarship To... By www.rediff.com Published On :: Mon, 11 Nov 2024 14:08:03 +0530 Western Digital is offering a one-time scholarship of up to Rs 75,000 to persons with disabilities and transgender students pursuing graduation, post-graduation and PhD degrees in STEM-related fields. Full Article
tal In first, govt nod to raise all-women CISF battalion By www.rediff.com Published On :: Tue, 12 Nov 2024 20:11:26 +0530 The Indian government has sanctioned the creation of the first all-women Central Industrial Security Force (CISF) reserve battalion, consisting of over 1,000 personnel. This move addresses the increasing demands on the force at airports and other vital installations. The new unit will be formed from existing CISF personnel and will be led by a senior commandant-rank officer. Full Article
tal Taliban appoint acting consul in Mumbai mission By www.rediff.com Published On :: Wed, 13 Nov 2024 08:16:05 +0530 The Taliban regime has appointed Ikramuddin Kamil as the acting consul in the Afghan mission in Mumbai, Afghan media has reported. This is the first such appointment made by the Taliban set up to any Afghan mission in India. The appointment, announced by the Ministry of Foreign Affairs of Afghanistan, is seen as an effort to strengthen diplomatic ties with India and enhance its presence abroad. Kamil, who holds a PhD degree in international law, is expected to facilitate consular services and represent the interests of Afghanistan in India. Full Article
tal Why Chandrababu Naidu and M K Stalin are wrong — and how their ideas on reproduction turn the clock back By indianexpress.com Published On :: Mon, 28 Oct 2024 07:43:18 +0000 Full Article Columns Opinion
tal Express View on ‘digital arrest’ fraud: Prompt action needed By indianexpress.com Published On :: Mon, 28 Oct 2024 22:30:20 +0000 Full Article Editorials Opinion
tal I lost money in a digital arrest fraud — this is what I’ve learnt from my experience By indianexpress.com Published On :: Wed, 30 Oct 2024 14:20:56 +0000 Full Article Columns Opinion
tal Delhi’s dance with Europe: Capitalising on new opportunities By indianexpress.com Published On :: Wed, 30 Oct 2024 22:40:09 +0000 Full Article Editorials Opinion
tal The Third Edit: A student who accidentally discovered an ancient city By indianexpress.com Published On :: Thu, 31 Oct 2024 20:00:23 +0000 Full Article Editorials Opinion
tal Indians’ foreign visa obsession: From bureaucrats’ kids to Gulf workers, why is talent leaving? By indianexpress.com Published On :: Sat, 02 Nov 2024 08:30:13 +0000 Full Article Columns Opinion
tal November 7, 1984, Forty Years Ago: Calm in Capital By indianexpress.com Published On :: Wed, 06 Nov 2024 19:02:22 +0000 Full Article 40 Years Ago Opinion
tal Udhayanidhi Stalin is right about Bollywood’s lack of cultural diversity By indianexpress.com Published On :: Thu, 07 Nov 2024 12:07:48 +0000 Full Article Columns Opinion