ter A Left that Dares to Speak Its Name: 34 Untimely Interventions By www.wiley.com Published On :: 2020-04-27T04:00:00Z With irrepressible humor, Slavoj Žižek dissects our current political and social climate, discussing everything from Jordan Peterson and sex “unicorns” to Greta Thunberg and Chairman Mao. Taking aim at his enemies on the Left, Right, and Center, he argues that contemporary society can only be properly understood from a communist standpoint.Why communism? The greater the triumph of global capitalism, the more its dangerous antagonisms multiply: climate Read More... Full Article
ter A Left that Dares to Speak Its Name: 34 Untimely Interventions By www.wiley.com Published On :: 2020-04-27T04:00:00Z With irrepressible humor, Slavoj Žižek dissects our current political and social climate, discussing everything from Jordan Peterson and sex “unicorns” to Greta Thunberg and Chairman Mao. Taking aim at his enemies on the Left, Right, and Center, he argues that contemporary society can only be properly understood from a communist standpoint.Why communism? The greater the triumph of global capitalism, the more its dangerous antagonisms multiply: climate Read More... Full Article
ter Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00554A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chi Y. Cheng, Josh E. Campbell, Graeme M. DayEvolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Palladium-catalysed 5-endo-trig allylic (hetero)arylation By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01932A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bara Singh, Siddheshwar K. Bankar, Ketan Kumar, S. S. V. RamasastryA palladium-catalysed intramolecular allylic (hetero)arylation strategy for the synthesis of fused cyclopentenes incorporated with all-carbon quaternary and spiro centres is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01911A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech PisulaThe solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01349H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael Fairley, Leonie Bole, Florian Mulks, Laura Main, Alan Kennedy, Charles T. O'Hara, Joaquín García-Álvarez, Eva HeviaLithium amides constitute one of the most commonly used class of reagents in synthetic chemisty. However, despite many applications, their use is handicapped by their requirements of low temperatures, in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Thermal effects – an alternative mechanism for plasmon-assisted photocatalysis By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/C9SC06480J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yonatan Dubi, Ieng Wai Un, Yonatan SivanA simple Arrhenius-based theory of heating, rather than “hot electrons”, can reproduce some high-profile photocatalysis experimental results to remarkable accuracy. Flaws in temperature measurement may have led to wrong conclusions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Water-induced formation of an alkali-ion dimer in cryptomelane nanorods By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01517B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shaobo Cheng, Vidushi Sharma, Altug S. Poyraz, Lijun Wu, Xing Li, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, Marivi Fernández-Serra, Yimei ZhuWater displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Metal-metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00646G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shubham Deolka, Orestes Rivada, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin, Julia R KhusnutdinovaWe report selective formation of heterobimetallic PtII/CuI complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00997K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don TilleyA cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00463D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. WilliamsA new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01773F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bin Wang, Derek Yiren Ong, Yihang Li, Jia Hao Pang, Kohei Watanabe, Ryo TAKITA, Shunsuke ChibaA concise protocol for anti-hydromagnesiation of aryl alkynes was established using 1:1 molar combination of sodium hydride (NaH) and magnesium iodide (MgI2) without the aid of any transition metal catalysts....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01534B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie ZhuQuantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Highly efficient non-doped blue fluorescent OLEDs with low efficiency roll-off based on hybridized local and charge transfer excited state emitters By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01341B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xianhao Lv, Mizhen Sun, Lei Xu, Runzhe Wang, Huayi Zhou, Yuyu Pan, Shitong Zhang, Qikun Sun, Shanfeng Xue, Wenjun YangA new pure fluorescent blue HLCT-emitter was designed and synthesized. Highly efficient non-doped blue OLEDs with low efficiency roll-off were achieved.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01112F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matthias Müller, Antti J Karttunen, Magnus Richard BuchnerThe hexa-μ2-amido-tetraammine-tetraberyllium compounds [Be4(NH2)6(NH3)4]X2 (X = Cl, Br, I, CN, SCN, N3) have been prepared from beryllium metal and NH4X or [Be(NH3)4]X2 in liquid ammonia at ambient temperature. The obtained...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I) By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01512A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana SanchezThe first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4287-4296DOI: 10.1039/C9SC06006E, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. EngleNickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter DP4-AI automated NMR data analysis: straight from spectrometer to structure By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4351-4359DOI: 10.1039/D0SC00442A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander Howarth, Kristaps Ermanis, Jonathan M. GoodmanA robust system for automatic processing and assignment of raw 13C and 1H NMR data DP4-AI has been developed and integrated into our computational organic molecule structure elucidation workflow.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter SAXS studies of the thermally-induced fusion of diblock copolymer spheres: formation of hybrid nanoparticles of intermediate size and shape By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4312-4321DOI: 10.1039/D0SC00569J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.E. J. Cornel, P. S. O'Hora, T. Smith, D. J. Growney, O. O. Mykhaylyk, S. P. ArmesDilute dispersions of poly(lauryl methacrylate)-poly(benzyl methacrylate) diblock copolymer spheres of differing mean diameter are mixed and thermally annealed at 150 °C to produce either spherical or non-spherical nanoparticles of intermediate size.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Peculiar bond characters of fivefold coordinated octet compound crystals By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4340-4350DOI: 10.1039/D0SC00292E, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.An-An Sun, Shang-Peng Gao, Gong GuA refreshed view of chemical bonds in solids unveils unusual bonding in fivefold coordinated bulk crystals of octet compounds: out-of-plane cation–anion chain bonding via overlapping pz orbitals replaces in-plane π bonding of the isolated monolayer.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter An RGB-emitting molecular cocktail for the detection of bacterial fingerprints By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4403-4409DOI: 10.1039/D0SC01704C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sheng Hong, Di-Wei Zheng, Qiu-Ling Zhang, Wei-Wei Deng, Wen-Fang Song, Si-Xue Cheng, Zhi-Jun Sun, Xian-Zheng ZhangA technique named the Microcolor system was developed to detect microbes and diagnose diseases based on changes in microbiota signatures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4397-4402DOI: 10.1039/D0SC00844C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong LiA novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4381-4390DOI: 10.1039/D0SC01026J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen NiemeyerSupramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Intramolecular Csp3–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4482-4487DOI: 10.1039/C9SC05522C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaojin Wen, Xinyao Li, Xiao Luo, Weijin Wang, Song Song, Ning JiaoA novel intramolecular cyclization of alkyl azides for the synthesis of cyclic imines and tertiary amines has been developed. The aliphatic C–H or C–C bond was selectively cleaved with the efficient formation of two C–N single bonds or a CN double bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4374-4380DOI: 10.1039/D0SC00206B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. CozzolinoA new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter J-dimer emission in interwoven metal–organic frameworks By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4391-4396DOI: 10.1039/D0SC00876A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wesley J. Newsome, Arnab Chakraborty, Richard T. Ly, Gavin S. Pour, David C. Fairchild, Amanda J. Morris, Fernando J. Uribe-RomoJ-dimer emission is an emergent property that occurs when pairs of ground-state fluorophores associate within multivariate MOFs producing tunable red shifted emission.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Machine-enabled inverse design of inorganic solid materials: promises and challenges By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00594K, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juhwan Noh, Geun Ho Gu, Sungwon Kim, Yousung JungThe grand challenge of materials science, discovery of novel materials with target properties, can be greatly accelerated by machine-learned inverse design strategies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4475-4481DOI: 10.1039/D0SC01194K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-EwingShort-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Redox deracemization of β,γ-alkynyl α-amino esters By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4444-4449DOI: 10.1039/D0SC00944J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lu Zhang, Rongxiu Zhu, Aili Feng, Changyin Zhao, Lei Chen, Guidong Feng, Lei LiuA one-pot deracemization of β,γ-alkynyl α-amino esters consisting of an aerobic oxidation and chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation has been described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Functional group interaction profiles: a general treatment of solvent effects on non-covalent interactions By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4456-4466DOI: 10.1039/D0SC01288B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mark D. Driver, Mark J. Williamson, Joanne L. Cook, Christopher A. HunterFunctional group interaction profiles are a quantitative tool for predicting the effect of solvent on the free energy changes associated with non-covalent interactions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Geometric landscapes for material discovery within energy–structure–function maps By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00049C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seyed Mohamad Moosavi, Henglu Xu, Linjiang Chen, Andrew I. Cooper, Berend SmitWe introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00266F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yunyi Wang, Jihyun Kim, Christian HiltyElucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01025A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor AlabuginHow far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01763A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal KhanThe first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01290D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P CramerA diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00021C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Koichiro Masuda, Shū KobayashiA direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter The Role of Porphyrin Peripheral Substituents in Determining the Reactivities of Ferrous Nitrosyl Species By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01625J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sk Amanullah, Abhishek DeyFerrous nitrosyl {FeNO}7 species are intermediates common to the catalytic cycles of Cd1NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity vary dramatically in these enzymes. The former...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00968G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. LipshutzA new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01796E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.David Zhi Hong Zee, T. David HarrisCatalytic heme active sites of enzymes are sequestered by the protein superstructure and are regulated by precisely defined outer coordination spheres. Here, we emulate both of these protective functions in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01694B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David WildenAn electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Now, write letters & send cards to Covid warriors By timesofindia.indiatimes.com Published On :: Sat, 09 May 2020 04:47:00 IST Writing letters may have become a passé, but thanks to the initiative of Patna postal division, many city residents are now thanking corona warriors by sending them personal handwritten letters or greeting cards. Full Article
ter Is it possible to enter an IPO bid below floor price? By economictimes.indiatimes.com Published On :: 2020-04-06T10:59:22+05:30 Floor price is the minimum price at which bids can be made for offer. Full Article
ter Who are intermediaries in an IPO? By economictimes.indiatimes.com Published On :: 2020-04-06T12:18:25+05:30 All the relevant information regarding the four intermediates such as addresses, telephone/fax numbers, registration number, and contact person and email addresses, are disclosed in the offer documents. Full Article
ter Half of FY20 IPOs hold head above water in this selloff, some remain multibaggers By economictimes.indiatimes.com Published On :: 2020-04-20T13:46:16+05:30 Out of the 15 stocks that got listed in FY 2019-20, seven are still trading above issue prices. Full Article
ter International guide to student achievement / edited by John Hattie, Eric M. Anderman By prospero.murdoch.edu.au Published On :: Full Article
ter National Strategy for International Education 2025 / Australian Government By prospero.murdoch.edu.au Published On :: Australia, author, issuing body Full Article
ter Interim report : first steps for improving educational opportunities for Aboriginal and Torres Strait Islander students / House of Representatives Standing Committee on Indigenous Affairs By prospero.murdoch.edu.au Published On :: Australia. Parliament. House of Representatives. Standing Committee on Indigenous Affairs, author, issuing body Full Article
ter Creating environments for learning : birth to age eight / Julie Bullard, University of Montana Western By prospero.murdoch.edu.au Published On :: Bullard, Julie, author Full Article
ter Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman By prospero.murdoch.edu.au Published On :: Full Article
ter The Humboldtian tradition : origins and legacies / edited by Peter Josephson, Thomas Karlsohn, Johan Östling By prospero.murdoch.edu.au Published On :: Full Article
