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Maharashtra Assembly elections: 99% work on MVA's seat-sharing completed, says Sanjay Raut

Shiv Sena (UBT) leader Sanjay Raut also indicated his party could contest 100 seats




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Baba Siddique murder case: 11th accused arrested

Police suspect accused Amit Hisamsing Kumar was involved in hatching the conspiracy and its execution




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Baba Siddique murder: suspect nabbed from Ludhiana; 15 arrested so far

Elsewhere, the investigators seized a pistol from the rented house of one of the arrested accused in Panvel area near Mumbai.




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Shiv Sena (UBT) declares candidates for disputed Versova and Ghatkopar West seats in Mumbai

MVA constituents Congress and NCP (SP) too were gunning for the seats.




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Maharashtra polls: ₹17 lakh unaccounted cash seized from vehicle in Ulhasnagar

The seizure was made by flying squad number 6, operating in Ulhasnagar Assembly constituency, between Kalyan and Murbad at 2 a.m.




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Mumbai-Ahmedabad bullet train corridor: Construction of 12 river bridges completed in Gujarat

“The 120-metre-long bridge on the Kharera river in Navsari district is the 12th such structure to be recently completed in Gujarat,” the National High Speed Rail Corporation Limited said




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Baba Siddique murder case: One more arrested

Gaurav Vilas Apune, a resident of Karvenagar locality of Pune city, is the 16th person to be arrested in the case




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Maharashtra Assembly polls: Uddhav Thackeray siding with those who insulted Balasaheb and Savarkar, says Amit Shah

After releasing the BJP’s manifesto for the November 20 Maharashtra Assembly polls, Mr Shah also said his party will not allow religion-based reservation in the country.




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Baba Siddique murder case: Shooter Shivkumar, four others arrested from U.P.

Four others, namely Anurag Kashyap, Gyan Prakash Tripathi, Akash Srivastava and Akhilendra Pratap Singh, have been arrested for sheltering Shivkumar and helping him flee to Nepal






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United States, UNESCO, and International Relations through Cultural Heritage

United States, UNESCO, and International Relations through Cultural Heritage United States, UNESCO, and International Relations through Cultural Heritage

jacksonl




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Understated and Sometimes Contentious: A Perspective on the US-Australia Alliance in Southeast Asia

Understated and Sometimes Contentious: A Perspective on the US-Australia Alliance in Southeast Asia Understated and Sometimes Contentious: A Perspective on the US-Australia Alliance in Southeast Asia

jacksonl




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Indian-origin scientist discovers protein function that may treat age-related diseases




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Drone technology is expected to revolutionise India's marine fisheries sector




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IIT Madras, ISRO to study spacecraft & launch vehicle-related thermal management




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NVivo Workshop: Part 1: Getting Started | Nov. 14

Link to Notice




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K'taka rain fury: Bengaluru worst hit; CM says 'closely monitoring rain-related disasters'




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1,079 houses inundated as heavy rain wrecks havoc in Bengaluru




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Kannada Rajyotsava celebrated with much fervour in Karnataka; PM, HM, CM greet people




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1924 Congress meet in Belagavi: Obama invited for joint Assembly session by K'taka govt




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Karnataka bans glass-coated string for flying kites




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Telangana: BR Naidu appointed TTD Board chairman




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Telangana government adopted Indiramma as role model: Revanth Reddy




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T'gana to constitute dedicated panel for survey on Backward Class quota




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Vijayawada-Srisailam seaplane trial run conducted successfully




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Nominated posts filled after screening 30,000 applications: Chandrababu Naidu




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Kerala bypolls: Voting date for Palakkad Assembly seat shifted to Nov 20




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Get Started in AI and NFTs with the Limewire API (Sponsored)

AI media creation has expanded to incredible video art and a host of other important improvements, and LimeWire is leading the way in creating an awesome interface for the average user to become an AI artist. Limewire has just released its Developer API, a method for engineers like us to create dynamic AI art on […]

The post Get Started in AI and NFTs with the Limewire API (Sponsored) appeared first on David Walsh Blog.




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Europa PIX: Maguire to Manchester United's rescue

IMAGES from the Europa League matches played on Thursday




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EPL PIX: Brighton stun Spurs; Chelsea, United held

IMAGES from the Premier League matches played across England, on Sunday.




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PIX: Manchester United register big win!

United are six-times League Cup winners, most recently lifting the trophy in 2022-23 with Ten Hag at the helm.




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PIX: Man United log first Europa League win

The win leaves United in 15th place in the Europa League standings on six points from four games.




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EPL PIX: United thrash Leicester; Ipswich stun Spurs

IMAGES from the English Premier League matches played on Sunday.




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CMS Info Systems reports 8% increase in consolidated net profit at ₹91 crore

The company said slower consumption, elections and intense rains in the first half (H1) of FY25, which impacted realisations




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Bharti Airtel Q2 preview: Consolidated net profit expected to grow multifold

According to analysts, industry-leading ARPU and support from other businesses bode well for Airtel’s revenue growth during the quarter




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With Trump win, DoT gears up to sort out issues related to Elon Musk’s Starlink

The department of telecommunications is looking into security aspects while considering the demands made by two American companies — Starlink and Amazon (project Kuiper), say sources




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Deconstructive annulation mediated one-pot synthesis of xanthene derivatives

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00093E, Paper
Balasubramaniyam Manikandan, Subbiah Thamotharan, Olivier Blacque, Subramaniapillai Selva Ganesan
One-pot, two-step methodology utilized for the sequential C–O/C–N cleavage followed by intramolecular/intermolecular annulation reaction.
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Synthesis of 3,5-disubstituted isoxazoles by domino reductive Nef reaction/cyclization of β-nitroenones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00232F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Ehtisham Ibraheem Khan, Tomas Lighuen Cassini, Marino Petrini, Alessandro Palmieri
β-Nitroenones were converted into 3,5-disubstituted isoxazoles via a domino reaction promoted by tin(II) dichloride. The protocol efficiently works under both microwave and flow conditions.
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A water mediated multicomponent reaction for the synthesis of novel spirooxindole derivatives and their antifungal activity

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00256C, Paper
Min Zhang, Liang Shi, Li Chen, Zhengyu Liu, Ting Zhao, Chunyin Zhu, Liuqing Yang
A total of 27 novel spirooxindoles were synthesized through a water mediated three-component reaction of isatin, 4-aminocoumarin, and 1,3-cyclodicarbonyl compounds. Several compounds showed excellent antifungal activity against Physalospora piricola.
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Dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00190G, Paper
Kai-Cheng Yang, Shi-Lu Zheng, Zhong Wen, Yu-Shan Zhang, Hai-Liang Ni, Long Chen
A HOTf or Fe(OTf)3-catalyzed dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes was developed, which represents a brand-new procedure for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones.
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Selective recognition between aromatics and aliphatics by cage-shaped borates supported by a machine learning approach

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00408F, Paper
Open Access
Yuya Tsutsui, Issei Yanaka, Kazuhiro Takeda, Masaru Kondo, Shinobu Takizawa, Ryosuke Kojima, Akihito Konishi, Makoto Yasuda
Exploration of a Lewis acid with high selectivity for hydrocarbon moieties is assisted by a machine learning approach. Molecular polarizability is an essential factor, leading to design guidelines for Lewis acid catalysts with dispersion forces.
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An efficient synthesis of mono-, di-, and tri-substituted 1,3-thiazoles employing functionalized thioamides as thiocarbonyl precursors

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00229F, Paper
Kalleshappa Sheela, Chikkappaiahnayaka Santhosh, Krishna Ravi Singh, Kalleshappa Sharath, Maralinganadoddi P. Sadashiva
Herein, we report an efficient strategy to synthesize functionalized 1,3-thiazoles using alkyl 2-amino-2-thioxoacetates.
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Correction: Recent progress of core-substituted naphthalenediimides: highlights from 2010

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB90045F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sheshanath V. Bhosale, Sidhanath V. Bhosale, Suresh K. Bhargava
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HFIP-mediated C-3-alkylation of indoles and synthesis of indolo[2,3-b]quinolines & related natural products

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00414K, Paper
Auqib Rashid, Waseem I. Lone, Preeti Dogra, Showkat Rashid, Bilal A. Bhat
An expeditious metal free C-3 alkylation of indoles and its NIS-mediated deviation to indolo[2,3-b]quinolines is reported. Applications of these strategies in accessing bioactive natural products have also been demonstrated.
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DMSO promoted catalyst-free oxidative C–N/C–O couplings towards synthesis of imidazoles and oxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00383G, Paper
Debasish Bera, Rajib Sarkar, Tiyasa Dhar, Pinaki Saha, Prasanta Ghosh, Chhanda Mukhopadhyay
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C–N coupling and C–O coupling under oxidant-free conditions are outlined.
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Synthesis of alkenylphosphine oxides via Tf2O promoted addition–elimination of ketones and secondary phosphine oxides

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00318G, Communication
Jiangkai Ma, Lianjie Wang, Anjiang Qiao, Zhongxian Li, Fengqian Zhao, Junliang Wu
An efficient method for the synthesis of alkenylphosphine oxides via the addition-elimination of SPOs to ketones has been developed. The reaction exhibits good yields and compatibility. Several conversions have also proven the value of this method.
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Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00442F, Communication
Fuxin Li, Hui Liu, Wanyu Xing, Qingju Zhang, Liming Wang
Here we report an efficient electrochemical nickel-catalyzed cross-coupling reaction for the synthesis of S-glycosides from preactivated phenols and ketones.
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Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
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Synthesis of alkynyl sulfides via base-promoted nucleophilic ring-opening of α-bromostyrene sulfonium salt

Org. Biomol. Chem., 2024, 22,2953-2957
DOI: 10.1039/D4OB00203B, Communication
Junqi Zhou, Ziyu Wang, Hanmiao Xu, Mengke Su, Jian Wen
An effective method for synthesizing various alkynyl sulfides has been developed using tetramethylene sulfoxide as a sulfur source through base-promoted nucleophilic ring-opening reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry