Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00029C, Paper

Open Access

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Jake Seymour, Ekaterina Gousseva, Frances Towers Tompkins, Lewis Parker, Najaat Alblewi, Coby James Clarke, Shusaku Hayama, Robert Palgrave, Roger Bennett, Richard Paul Matthews, Kevin R. J. Lovelock
Using a combination of liquid-phase experimental X-ray spectroscopy experiments and small-scale calculations we have gained new insights into the speciation of halozincate anions in ionic liquids (ILs). Both core and...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01842G, Research Article

Sha Jianchun, Wang Qiang, Li Xue, Liu Zhoulin, Bao Jiaxin, Li Lianhui, Tian Jie, Chen Weilong, Liu Wenhong, Zhang Zhiqiang
Aqueous Mg–air batteries are promising candidates for large-scale energy storage, but their practical application is significantly hindered by water-induced parasitic reactions and the chunk effect.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02385D, Review Article

Jiayu Li, Ertai Na, Xudong Liang, Qihua Liang, Meihong Fan, Hui Chen, Guodong Li, Xiaoxin Zou
With the development of science and technology, the demand for reliable and efficient gas sensors in various applications, ranging from environmental monitoring to industrial safety, is increasing. In particular, MOS...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01691B, Research Article

Meng-Jia Shang, Han-Han Lu, Qiang Liu, Ren-He Zhou, Hui-Ying Sun, Zhen Shao, Liang Zhao, Yin-Shan Meng, Tao Liu
The development of single-chain magnets with reversible and adjustable properties is of great significance for achieving high-density information storage and switching devices with multi-stimuli responsiveness whilst remains a challenging task....
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01824A, Research Article

Qianyi Chen, Zhenjie Lun, Dongdan Chen, Yongsheng Sun, Puxian Xiong, Siyun Li, Shanhui Xu, Zhongmin Yang
A defect engineering strategy mediated by the structural cationic substitution is proposed and experimentally demonstrated for ultra-broadband emission in a garnet Y₃Sc₂Al₃O₁₂:B³⁺ phosphor.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01996B, Research Article

Alexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan
Tetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02230K, Research Article

Yifei Li, Senyao Meng, Ping Wang, Miao He, Jiasai Yao, Cheng Yang, Fangzhou Mo, Jiang Li, Zhenxing Li
The crystal facet of CeO2 is crucial in governing the catalytic performance. However, studies on the relationship between the photocatalytic oxidation performance of CeO2 and its crystal facets are scarce....
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Inorg. Chem. Front., 2024, 11,7930-7935
DOI: 10.1039/D4QI01965B, Research Article

Dipanwita Palit, Debasish Manna
TET enzymes play a key role in epigenetic regulation by oxidizing 5-methylcytosine, impacting gene expression and DNA methylation. Here, we report a chemical model of the TET enzyme which selectively and catalytically oxidize 5-hydroxymethylcytosine.
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Inorg. Chem. Front., 2024, 11,7966-7978
DOI: 10.1039/D4QI02373K, Research Article

Pawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorazy
Dysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.
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Inorg. Chem. Front., 2024, 11,7822-7830
DOI: 10.1039/D4QI02027H, Research Article

Haisheng Wei, Jing Li, Xiaorui Yan, Tiantian Liu, Kairui Li, Dan Feng, Yujing Ren
Benefiting from the long-range synergistic effect between Pt_n clusters and Zn₁ single atoms, Pt_n@Zn₁-N–C displays superior catalytic performance in selective hydrogenations.
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Inorg. Chem. Front., 2024, 11,8025-8036
DOI: 10.1039/D4QI01804D, Research Article

Fangyuan Yu, Qifa Lin, Xiangfu Zeng, Ping Zhou, Xiao Wu, Cong Lin, Chunlin Zhao, Min Gao, Tengfei Lin, Xingan Jiang, Laihui Luo, Qiwei Zhang
Sr/Er was codoped in KNN ceramics to induce the coexistence of O and T phases, resulting in improving optical transparency, maintaining moderate ferroelectricity, inducing excellent PC behavior and fluorescence temperature sensing performance.
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Inorg. Chem. Front., 2024, 11,7853-7859
DOI: 10.1039/D4QI01547A, Research Article

Li-Ling Zhang, Hua Huang, Qingran Ding, Hui-Ping Xiao, Qing-Yan Liu, Yu-Ling Wang
Crystal structures and optoelectronic performance of hybrid two-dimensional lead bromide halide perovskites are elaborately regulated by pyridyl cations, which achieve a significantly enhanced birefringence of 0.315 (550 nm) for crystal 2.
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Inorg. Chem. Front., 2024, 11,7775-7792
DOI: 10.1039/D4QI01978D, Review Article

Tianshu Zhang, Yijun Qian, Changyong Zhang, Tao Qian, Chenglin Yan
This review overviews the recent advances in electrodialysis (ED) in extracting critical metals from spent battery leachate. In addition, strategies and challenges regarding ED techniques toward battery recycling are pointed out.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02162B, Research Article

Ni-Ya Li, Xin-Yu Wang, Pei-Xuan Zhang, Ning-Ning Zou, Wen Qiu, Yu-Fei Xing, Yun-Jian Wang, Xiao-Yan Tang, Dong Liu
A unique coordination polymer can transform between comb-like and ladder-like bistable structures through reversible single-crystal-to-single-crystal photoreaction and exhibit photo-switchable fluorescence.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02343A, Research Article

Yu-Xuan Zhang, Yi-Jie Ma, Yu-Jia Zhao, Zi-Yan Wang, Cai-Xia Yu, Xiaoqiang Li, Lei-Lei Liu
Exploration of non-noble-metal-based catalysts with high catalytic activity and selectivity is significant for driving innovation in green chemistry and technology. Herein, we report a facile synthesis of two-dimensional (2D) NiCo-MOF...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article

Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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Lab Chip, 2024, 24,2049-2057
DOI: 10.1039/D3LC00707C, Paper

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Fumiaki Yokoyama, André Kling, Petra S. Dittrich
A microdevice with narrow winding channels is introduced to trap and culture single bacterial cells. It is used to study growth patterns of the cells and to monitor secretion of extracellular vesicles under treatment with an antibiotic drug.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00891F, Paper

Yu-Hsiang Hsu, Wen-Chih Yang, Yi-Ting Chen, Che-Yu Lin, Chiou-Fong Yang, Wei-Wen Liu, Subhashree Shivani, Pai-Chi Li
The DC-MPS device uses a velocity V-clamp to create a partition with a steep concentration gradient for simultaneously developing vasculogenic vessels and a tumor. It enables vessel–tumor interaction to develop a tumor model with angiogenic vessels.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00131A, Paper

Fahima Akther, Hedieh Fallahi, Jun Zhang, Nam-Trung Nguyen, Hang Thu Ta
An atherothrombosis-on-chip model to evaluate thrombosis risk and patient-specific treatment strategy.
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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC01062G, Paper

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Steven A. Soper, Chathurika Rathnayaka, Indu Chandrasoma, Junseo Choi, Katie Childers, Maximillian Chibuike, Khurshed Akabirov, Farhad Shiri, Adam R Hall, Collin J McKinney, Matthew David Verber, Sunggook Park
We report the generation of ~8 nm dual in-plane pores fabricated in a thermoplastic via nanoimprint lithography (NIL). These pores were connected in series with nanochannels, one of which served...
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Lab Chip, 2024, 24,2237-2252
DOI: 10.1039/D3LC00694H, Paper

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Nilay Vora, Prashant Shekar, Taras Hanulia, Michael Esmail, Abani Patra, Irene Georgakoudi
We present a deep-learning enabled, label-free flow cytometry platform for identifying circulating tumor cell clusters in whole blood based on the endogenous scattering detected at three wavelengths. The method has potential for in vivo translation.
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Lab Chip, 2024, 24,2262-2271
DOI: 10.1039/D4LC00055B, Paper

Kawin Khachornsakkul, Ruben Del-Rio-Ruiz, Lita Chheang, Wenxin Zeng, Sameer Sonkusale
A carbon dots and dopamine-imprinted polymer was immobilized onto a distance-based paper channel for simultaneous detection of three cytokine biomarkers without requiring expensive reagents and instruments.
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Lab Chip, 2024, 24,2327-2334
DOI: 10.1039/D4LC00176A, Paper

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Aravind M, Sajan D. George
Adhesive contrast contact lens fabricated by selective lubricant grafting splits tear film on specified zone by secretion and blinking. Integrating the contact lens with the spectroscopic technique offers an efficient platform for biomolecule sensing.
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Lab Chip, 2024, 24,2306-2316
DOI: 10.1039/D3LC01045G, Paper

Sabah H. Al-Jaf, Sameera Sh. Mohammed Ameen, Khalid M. Omer
On-site monitoring of ions in drinking water is essential for safeguarding public health, ensuring high water quality, and preserving the ecological balance of aquatic ecosystems.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00159A, Paper

Lixue Liang, Xueying Wang, Dong Chen, Palaniappan Sethu, Guruprasad A. Giridharan, Yanxia Wang, Yu Wang, Kai-Rong Qin
The best pulsation frequency mode of the RBP would be one that changes every 2–3 times of the cardiac cycle. The proposed in vitro microfluidic model could provide an effective platform to select the best working mode of the RBP for heart failure.
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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00291A, Paper

Nana Jin, Fan Jiang, Fengzhen Yang, Ying Ding, Ming Liao, Yanbin Li, Jianhan Lin
A colorimetric biosensor was elaboratively designed for fast, sensitive and multiplex bacterial detection on a single microfluidic chip using immune magnetic nanobeads for specific bacterial separation, immune gold@platinum palladium nanoparticles...
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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00105B, Critical Review

Shanqing Huang, Weixiong Shi, Shiyu Li, Qian Fan, Chaoyong Yang, Jiao Cao, Lingling Wu
Cells are the fundamental building blocks of living systems, exhibiting significant heterogeneity. The transcriptome connects the cellular genotype and phenotype, and profiling single-cell transcriptome is critical for uncovering distinct cell...
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00985H, Paper

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Nan Jia, Tianyang Deng, Charles Larouche, Tigran Galstian, André Bégin-Drolet, Jesse Greener
We report a flow sensitive birefringent in-channel chitosan micromembrane. Using a simple cross-polarizer and a calibration curve, the membrane functions as a flow rate meter, which also works as a feedback element for a flow control system.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00132J, Paper

Oriana G. Chavez-Pineda, Roberto Rodriguez-Moncayo, Alan M. Gonzalez-Suarez, Pablo E. Guevara-Pantoja, Jose L. Maravillas-Montero, Jose L. Garcia-Cordero
A microfluidic platform isolates leukocytes from blood efficiently, offering diagnostic and immunotherapeutic potential. Enhanced by a handheld pressure controller, it enables near-patient testing and integration with downstream assays.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00193A, Paper

Marti Z. Hua, Shenmiao Li, M. S. Roopesh, Xiaonan Lu
A QD-MIP based microfluidic device to detect mycotoxin in food.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00016A, Paper

Ethan J. Lockhart, Lisa F. Horowitz, Adán Rodríguez, Songli Zhu, Tran Nguyen, Mehdi Mehrabi, Taranjit S. Gujral, Albert Folch
A microfluidic platform was developed that hydrodynamically traps microdissected cuboids for selective drug treatments and isolates conditions with thermoplastic valves.
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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00400K, Paper

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Sergio Carrillo De Hert, Rafael Lopez-Rodriguez, Michael Di Maso, Jonathan McMullen, Steven Ferguson
Continuous flow chemical photoreactors have emerged as a highly attractive platform, garnering considerable attention in both industry and academia. Utilizing thin channels, these reactors offer a promising solution for achieving...
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00237G, Communication

Linjiang Zhu, Yuxin Wang, Linyan Pan, Enyong Lin, Jiayan Wang, Xiaolong Chen
A simple and cost-effective one-pot three-enzyme cascade reaction for high-yield production of L-5-methyltetrahydrofolate, including dihydrofolate reductase, tetrahydrofolate-dependent methyltransferase and alcohol dehydrogenase.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00346B, Paper

Qifeng Yang, Liping Liang, Ning Xu, Yang Li, Zhihui Wang, Dadong Shen, Yiming Mo
A cerium-mediated electrooxidation method was developed for synthesizing vitamin K₃ in a green and efficient manner. A systematic technoeconomic analysis was provided to understand its potential for practical implementation.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00438H, Paper

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Michael Prieschl, David Cantillo, C. Oliver Kappe, Gabriele Laudadio
A scalable C–O bond formation via continuous-flow Ni-electrocatalysis was developed, enabling the gram-scale preparation of a key delamanid intermediate, a pharmaceutical used to treat multidrug-resistant tuberculosis.
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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00328D, Paper

Naoto Tsubouchi, Yuuki Mochizuki
The volatilization of Li, Ni, Co, and Mn during chlorination treatment of LNO, LCO, and LMO (model materials for used LIB cathode material) was investigated with the aim of developing...
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Soft Matter, 2024, 20,3044-3052
DOI: 10.1039/D3SM01694C, Paper

Animesh Pal, Nilanjan Dey
The compartmentalization effect of microheterogeneous systems, like surfactant aggregates, showcases altered optoelectronic properties of a perylene diimide-based chromogenic dye (PDI-Ala) compared to bulk water.
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Soft Matter, 2024, 20,3271-3282
DOI: 10.1039/D3SM01522J, Paper

Quentin Chaboche, Gerardo Campos-Villalobos, Giuliana Giunta, Marjolein Dijkstra, Marco Cosentino Lagomarsino, Vittore F. Scolari
Depletion forces arising from molecular crowding compact single polymers. Simulations lead to a unified description. Collapse is governed by the packing fraction of crowders and the ratio of crowder to monomer size, and can be hindered by jamming.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00298A, Paper

Xingyue Sun, Haiyi Liang, Lina Ye
By comparing the mechanical properties between salt-treated hydrogels and air-dried hydrogels, the synergistic effect in energy transfer and dissipation arising from increases in polymer fraction and cross-linking plays an indispensable role in toughening SN hydrogels.
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RSC Adv., 2024, 14,12142-12146
DOI: 10.1039/D3RA08682H, Paper

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Xiao-Jing Hu, Yu-Lin Li, Hai-Xiong Liu, Shao-Ming Ying, Qi Yin, Tian-Fu Liu
Based on the excellent diclofenac sodium (DCF) removal capacity of MOF-808, a free-standing mixed-matrix membrane composed of polyacrylonitrile and MOF-808 was fabricated and used to remove DCF from water via an easily accessible filtration method.
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RSC Adv., 2024, 14,12360-12371
DOI: 10.1039/D3RA08538D, Paper

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Vo Pham Hoang Huy, Chung Wung Bark
Ultraviolet C (UVC) photodetectors have garnered considerable attention because the detection of UVC is critical for preventing skin damage in humans, monitoring environmental conditions, and detecting power aging in military applications.
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RSC Adv., 2024, 14,12496-12512
DOI: 10.1039/D4RA00578C, Paper

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Ramesh Kumar, Jayato Nayak, Somnath Chowdhury, Sashikant Nayak, Shirsendu Banerjee, Bikram Basak, Masoom Raza Siddiqui, Moonis Ali Khan, Rishya Prava Chatterjee, Prashant Kumar Singh, WooJin Chung, Byong-Hun Jeon, Sankha Chakrabortty, Suraj K. Tripathy
Assessment of the performance of linear and nonlinear regression-based methods for estimating in situ catalytic CO₂ transformations employing TiO₂/Cu coupled with hydrogen exfoliation graphene (HEG) has been investigated.
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RSC Adv., 2024, 14,12438-12448
DOI: 10.1039/D4RA01265H, Paper

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Nguyen Phu Hung, Nguyen Van Duy, Chu Thi Xuan, Dang Thi Thanh Le, Chu Manh Hung, Han Jin, Nguyen Duc Hoa
The ternary component consisting of SnO₂ nanowires/Pd–NiO nanorods is employed to enhance the acetone gas sensor performance utilizing the synergistic effects of the p–n heterojunction between the p-type NiO and the n-type SnO₂, as well as the catalytic spillover effect of Pd nanoparticles.
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RSC Adv., 2024, 14,12397-12406
DOI: 10.1039/D3RA08900B, Paper

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Nuno Marques, Santanu Jana, Manuel J. Mendes, Hugo Águas, Rodrigo Martins, Shrabani Panigrahi
The long-term performance of metal halide perovskite solar cells (PSCs) can be significantly improved by tuning the surface characteristics of the perovskite layers.
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RSC Adv., 2024, 14,12417-12427
DOI: 10.1039/D4RA01551G, Paper

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Sravani Kaja, Ashin Varghese Mathews, Amit Nag
Enhancement factors of 110 and 18 for metal-enhanced fluorescence and metal-enhanced SOG, respectively, are obtained from polymer coated gold nanorod cores adsorbed with Eosin Y.
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RSC Adv., 2024, 14,12349-12359
DOI: 10.1039/D3RA07066B, Paper

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Fariba Ghaffari, Mohammed Taghi Zafarani-Moattar, Hemayat Shekaari
In recent times, there has been considerable interest in utilizing aqueous biphasic systems (ABSs) containing natural deep eutectic solvents (NADESs) for the extraction of various substances.
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RSC Adv., 2024, 14,12600-12611
DOI: 10.1039/D4RA01061B, Paper

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Ehsan Dinpanah, Moslem Mansour Lakouraj, Ebrahim Fooladi, Vahid Hasantabar
Despite of all the developments in DNA microarray technology, there is not sufficient knowledge about protein abundance or their function in processes such as proteolysis, phosphorylation.
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RSC Adv., 2024, 14,12772-12780
DOI: 10.1039/D4RA00994K, Paper

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Misbah ul Ain, Asma, Rizwan Ullah, Zanjbeel Fatima, Ahsan Illahi, Waqqar Ahmed
Gold nanoworms (NWs), synthesized in a one-step reaction with size controlled by pH, show tunable plasmon peaks in the near-infrared. Finite element analysis validates their optical properties, and they exhibit sensitive refractive index sensing.
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