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Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00097H, Review Article
Matthew J. Evans, Cameron Jones
This review summarises advances in the chemistry of low-oxidation state and hydrido group 2 metal complexes, focussing on their use for the reductive activation of feed-stock gaseous small molecules, and their subsequent transformation into value added products.
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Visible photons as ideal reagents for the activation of coloured organic compounds

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01129A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lorenzo Di Terlizzi, Luca Nicchio, Stefano Protti, Maurizio Fagnoni
In search for the perfect wave(length). This review is dedicated to recent efforts in the development of visible light driven photochemical strategies occurring in coloured organic compounds.
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Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01050C, Review Article
Qiaoqiao Zhang, Yong Wang, Pierre Braunstein, Jian-Ping Lang
Olefinic coordination polymers were used as universal single crystal platforms for precise organic synthesis, in situ mechanism exploration and photochemical applications.
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Contact-electro-catalysis (CEC)

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00736G, Review Article
Ziming Wang, Xuanli Dong, Wei Tang, Zhong Lin Wang
Contact-electro-catalysis (CEC) is an emerging field that utilizes electron transfer occurring at the liquid–solid and even liquid–liquid interfaces because of the contact-electrification effect to stimulate redox reactions.
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Squaramide-based receptors in anion supramolecular chemistry: insights into anion binding, sensing, transport and extraction

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Chem. Soc. Rev., 2024, 53,3952-3975
DOI: 10.1039/D3CS01165H, Review Article
Open Access
Giacomo Picci, Riccardo Montis, Vito Lippolis, Claudia Caltagirone
Squaramides are a class of extremely versatile receptors for anion recognition, sensing, transport and extraction.
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Ferrari buoyed by pace after Australian GP practice

By www.thehindu.com
Published On :: Sat, 23 Mar 2024 00:47:00 +0530

Leclerc's team mate Carlos Sainz was third quickest in FP2 on his return to racing two weeks after appendicitis surgery


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Indian Racing Festival | Chennai dazzles under lights with action-packed races

By www.thehindu.com
Published On :: Mon, 02 Sep 2024 00:54:34 +0530

The on-track drama was exciting, and barring a minor incident during the first Indian Racing League race, the event passed off without hiccups.


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Actor Ajith Kumar to take part in endurance racing

By www.thehindu.com
Published On :: Tue, 22 Oct 2024 13:37:08 +0530

Indian actor Ajith Kumar to compete in endurance racing as team owner and principal driver of Ajith Kumar Racing


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India vs Great Britain Olympics quarterfinal: Everyone gathered around and worked on the tactics, says Craig Fulton

By www.thehindu.com
Published On :: Sun, 04 Aug 2024 18:31:09 +0530

“Sreejesh is a legend, he is one of the best we have. He is saving us from day one. But when you ask him, he will say it was a team effort, so team first, then individuals,” said Harmanpreet.


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Title holders India to open women's ACT campaign against Malaysia

By www.thehindu.com
Published On :: Wed, 09 Oct 2024 01:57:10 +0530

India won the tournament in 2016 in Singapore before reclaiming the title in Ranchi last year


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Extreme weather for kids : lessons and activities all about hurricanes, tornadoes, blizzards, and more! / Matthew Cappucci ; illustrated by Stephanie Hathaway

By darius.uleth.ca
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Cappucci, Matthew, author


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Sifting through fact, fiction and passion in a business plan

By www.thehindubusinessline.com
Published On :: Sun, 17 Dec 2023 21:01:00 +0530

The many challenges in envisioning the first business plan of a start-up


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Fund thesis: AI is the X-factor 

By www.thehindubusinessline.com
Published On :: Sun, 19 May 2024 21:01:00 +0530

Why VC firm Good Capital wants to be an early investor in AI-powered businesses


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Mild boroxazolidone formation and dissociation: Application toward target identification of bioactive molecules

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05370B, Communication
Toya Tabei, Kyoko Nagasawa-Goto, Yohei Saito
We successfully found that boroxazolidone can dissociate under aqueous conditions, which were applicable to a solution containing proteins. The immobilization of a newly synthesized diarylborinic acid on beads enabled the...
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Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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Varied CO2 photoreduction activity over UiO-66-NH2 with different aggregation morphology

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04919E, Communication
Shuran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guangjuan Xu, Wei Xie, Na Xu, Yanhong Xu, Yaqian Lan
UiO-66-NH2 with different aggregation morphology are prepared to verify the morphology of photocatalysts could influence the charge transfer. Among them, UiO-66-NH2 with the poor aggregation exhibits superior performances over CO2...
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Separation of Rare Earth Elements and Nickel Harnessing Electrochemistry and Reactive CO2 Capture and Mineralization

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04632C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akanksha Srivastava, Prarabdh Jain, Greeshma Gadikota, Prince Ochonma, Christopher Noe, Tianhe Yin
The aim is to probe the chemical mechanisms underlying the use of multifunctional solvents to simultaneously capture and convert CO2 into insoluble Rare Earth Element (REE)-carbonates, while forming soluble complexes...
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Alkenylation of unactivated alkanes: synthesis of Z-alkenes via dual Co-TBADT catalysis

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04651J, Communication
Vetrivelan Murugesan, Anagha Syam, Guru Vigknesh Anantharaj, Ramesh Rasappan
Hydroalkylation of terminal alkynes using unactivated alkanes under dual Co-TBADT catalysts is reported. Our cobalt-HAT catalysis achieves the desired Z alkene with excellent regio- and diastereoselectivity via C–H activation.
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Carboxylative cyclization of atmospheric CO2 with alkynol catalyzed by a 1-methylhydantoin anion-functionalized ionic liquid via chelative interactions

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03586K, Communication
Yujun Guo, Tingting Chen, Yingjie Xu
[1-MHy]− acts as a “pincer ligand” to form chelative interactions with –OH to enhance MBY activation, thus ensuring efficient [P4442][1-MHy]-catalyzed reaction of atmospheric pressure CO2 with MBY under metal- and solvent-free conditions.
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Visible light-activated polyphenol–Al3+ coordination for ambient and quantitative xylose-to-furfural conversion

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication
Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al3+ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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Directed nucleophilic aromatic substitution reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04912H, Communication
Yasuyuki Nitta, Takashi Nishikata, Michinori Sumimoto, Yusei Nakashima
In this study, we discovered a directed nucleophilic aromatic substitution reaction, "directed SNAr (dSNAr)", in the reaction of ortho-iodobezamides and amine in the presence of pyridine. The reaction proceeded ortho-specifically...
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From one to two: In-site constructing C3N5-Poly (triazine imide) heterojunction for enhanced O2 activation

By pubs.rsc.org
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05077K, Communication
Shiling Xu, Ziheng Yang, Laiqing Zhang, Xiaorui Zhang, Zikang Zeng, Wenxuan Wang, Yujun Liang, Lan Yuan, Chuang Han
A novel C3N5-Poly (triazine imide) (PTI) heterojunction was designed and constructed by thermal polymerization process, which featured with intimated S-scheme interface coupling and exhibited a predominant performance for H2O2 production....
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Recent Advances in Photochemical Strain-Release Reactions of Bicyclo[1.1.0]butanes

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05108D, Highlight
Xiang Zhou, Ye Hu, Yao Huang, Yang Xiong
Bicyclo[1.1.0]butanes (BCBs) are attractive compounds for their beautiful “butterfly” conformations, distinctive properties, and novel reactivities. As soon as the first example had been synthesized, a wide range of strain-release reactions...
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Catalytic asymmetric Michael and Nef-type sequential reaction of nitroolefin with azlactone to construct oxazole-fused succinimide

By pubs.rsc.org
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Chem. Commun., 2024, 60,13384-13387
DOI: 10.1039/D4CC04858J, Communication
Rui Weng, Yuqiao Zhou, Yaqin Zhang, Xiaoming Feng, Xiaohua Liu
A series of oxazole-fused succinimides bearing vicinal quaternary carbon centers were synthesized via catalytic asymmetric Michael addition and Nef-type sequential reactions of nitroolefins with azlactones.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Ultrafine PtCo alloy nanoparticles integrated into porous N-doped nanosheets for durable oxygen reduction reaction

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Chem. Commun., 2024, 60,13432-13435
DOI: 10.1039/D4CC04661G, Communication
Baoliang Chen, Lei Zhao, Zhaozhao Zhu, Pei Xiong, Zhao Li, Jun Song Chen, Lanlan Li, Rui Wu
The PtCo–CoNC–P catalyst, featuring sub-3 nm small-size PtCo alloy nanoparticles integrated into a porous nitrogen-doped nanosheet, exhibits exceptional durability after 30 000 cycles of accelerated durability tests.
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Investigations of the interactions between ZnO nanorods and H2 with 17O NMR spectroscopy

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05371K, Communication
Benteng Song, Fang Wang, Qin Zhu, Ling-Hai Xie, Luming Peng
Schematic diagram for the interaction of H2 with ZnO nanorods under different conditions.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Axial oxygen-bridged FeN4O/NC produced by ultrafast joule heating for efficient oxygen reduction reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05604C, Communication
Feng Liu, Xinyu Guo, Yan Zhong, Shaqi Fu, Jingsha Li, Chunmei Zhang, Heng Zhang, Fenghui Ye, Shuai Yuan, Chuangang Hu, Chunxian Guo
Herein, we report an atomically dispersed Fe-N-C catalyst with axial oxygen ligands (FeN4O/NC) firstly synthesized by ultrafast joule heating. The formation of oxygen species between FeN4 and graphene, which offers...
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Laccase-catalyzed tyrosine click reaction with 1-methyl-4-arylurazole: rapid labeling on protein surfaces

By pubs.rsc.org
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03802A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keita Nakane, Chizu Fujimura, Shogo Miyano, Zhengyi Liu, Tatsuya Niwa, Hafumi Nishi, Tetsuya Kadonosono, Hideki Taguchi, Shusuke Tomoshige, Minoru Ishikawa, Shinichi Sato
Our study shows efficient tyrosine labeling using 1-methyl-4-arylurazole (MAUra) with laccase under mild conditions. This method achieves a high efficiency (kcat/Km = 7.88 × 104 M−1 s−1), selectively targeting exposed tyrosine sites on proteins.
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In silico investigation of the interaction between α-synuclein aggregates and organic supramolecular assemblies

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Published On ::

Mol. Syst. Des. Eng., 2024, 9,1155-1166
DOI: 10.1039/D4ME00071D, Paper
Laura Le Bras, Yves L. Dory, Benoît Champagne
An α-synuclein aggregate with the PreNAC and NACore areas, responsible for the aggregation, highlighted.
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DORA-XGB: An improved enzymatic reaction feasibility classifier trained using a novel synthetic data approach

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Mol. Syst. Des. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4ME00118D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yash Chainani, Joseph Ni, Kevin Shebek, Keith Tyo, Linda J. Broadbelt
Retrobiosynthesis tools harness the inherent promiscuities of enzymes for the de novo design of novel biosynthetic pathways to key small molecules. Many existing pathway search algorithms rely on exhaustively enumerating...
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Development of xanthan gum-based solid desiccants for the extraction of water vapors from humid air

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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00134F, Paper
Hemant Mittal, Ali Al Alili, Saeed M. Alhassan, Naved I. Malek, Md. Didarul Islam
A xanthan gum-acrylamide desiccant with interconnected capillary channels was prepared and showed 1.38 g g−1 water adsorption at 90% RH and 25 °C, retaining 70% capacity over 20 cycles, proving its effectiveness as a salt-free desiccant.
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Exogenous analogues of substance P trigger pseudo-allergic reactions through activation of MRGPRX2

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ04581A, Paper
Yi Shan, Jiayu Lu, Na Li, Xiaoxue Mo, Cheng Wang, Huaizhen He
This article reports that exogenous analogues of the neuropeptide substance P can activate MRGPRX2 to trigger pseudo-allergic reactions.
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From byproducts to NLO-active dyes: catalyst-free transfer hydrogenation in the modular synthesis of merocyanines

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00820K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Zou, Yi Pan, Di Zhang, Jie Zhang, Weilong Chen, Hongyan Sun, Kai-Chung Lau, Jingdong Luo
Direct transfer hydrogenation from a strong electron donor to highly polarizable hemicyanines was discovered in the synthesis of push–pull chromophores. The reaction mechanism and experimental results were elucidated using DFT calculations.
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A novel Eu3+ activated Ca3Zn3Te2O12 tellurate red phosphor for white LEDs with high color stability and color purity

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01281J, Paper
Feiyan Xie, Junqiang Gu, Dekang Xu, Qiancheng Xiong, Jinyu Yang, Xiangjian Ou, Dawei Wen
Research into red phosphors with a high color rendering index is particularly compelling, given the absence of a red component in the spectrum of commercial phosphor-converted white light-emitting diodes, which...
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Effect of ammonia addition on dispersion and activity of supported copper species on porous silica-alumina hollow spheres for catalytic decomposition of nitrous oxide

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Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00808A, Paper
Tetsuo Umegaki, Takeru Nakamura, Yoshiyuki Kojima
This work investigated influence of ammonia addition in the immersion process of active species on dispersion and activity of copper supported porous hollow silica-alumina spheres catalysts for decomposition of nitrous...
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A Novel In-Syringe Cloud Point Extraction Method for the Determination of Cadmium and Lead in Human Hair Samples

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00335G, Paper
Hesane Zolfaghari, Seyed Mosayeb Daryanavard, Aqil Gholamshahzadeh
The measurement of contaminant elements, especially cadmium and lead, in biological samples typically requires time-consuming sample preparation methods that consume organic solvents that are harmful to humans and the environment....
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Isolation and characterization of novel degradation products in Fenoverine by LC-QTOF-MS/MS, LC-MSn and 2D-NMR

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ05623F, Paper
Krishnam Raju CH, Shanmukha Kumar Jagarlapudi, Yesudas Kada, Sanath Kumar Goud Palusa
This study investigates the degradation profile of Fenoverine (FEN), an antispasmodic drug, following the International Conference on Harmonization (ICH) Q1A (R2) guidelines. FEN is stable in the presence of light,...
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Exploring the impact of a cetyltrimethylammonium bromide surfactant on the electrochemical performance of tungsten oxide thin films

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05635J, Paper
Munazza Razzaq, Muhammad Saifullah, Ramzan Akhtar, Muhammad Jawad Khan, Zahid Imran, Muhammad Rehan, Ahsan Jamal, Sajid Iqbal, Mohsin Ali Raza Anjum, Sheeraz Mehboob
A WO3 thin film prepared with a CTAB/Na2WO4·2H2O molar ratio of 2.451 exhibits considerably improved current density, charge storage capacity, and diffusion kinetics.
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Synthesis, anticancer activity and molecular simulation of N-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)thioureas containing pyrimidine ring

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Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00209A, Paper
Vu Ngoc Toan, Nguyen Dinh Thanh, Do Son Hai, Nguyen Minh Tri
A series of thioureas 7a-k containing pyrimidine and D-glucose moiety have been synthesized through the reaction between substituted 2-aminopyrimidines 3a-k and tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate 6. The yields achieved were 55‒77%. The...
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Tailoring of novel morpholine-sulphonamide linked thiazole moiety as dual targeting DHFR/DNA gyrase inhibitors: Synthesis, antimicrobial, antibiofilm activities and DFT with molecular modelling studies

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ05774G, Paper
Moaz M. Abdou, Essam Eliwa, Mohamed Abdel Reheim, Ahmed Abu-Rayyan, Shimaa M. Abd El-Gilil, Mohammed Abu-Elghait , Mohamed H. Sharaf, Mohamed Kalaba, Ahmed Halawa, Walid Elgammal
Herein, the chemical synthesis of new thiazoles-based benzenesulfonamide-linked morpholine 4a,b–7 via late-stage thiazolation of the corresponding thiosemicarbazone 3 was reported. The skeletal formulas of the new compounds were confirmed by...
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Impact of Cr doping on the structural and optoelectronic properties of a CsPbIBr2 perovskite solar cell

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New J. Chem., 2024, 48,7205-7212
DOI: 10.1039/D4NJ00681J, Paper
M. I. Khan, Ali Mujtaba, Saddam Hussain, Asif Hussain, Dalil Bulayis N AlResheedi, Zainab Mufarreh Elqahtani, El Sayed Yousef, Norah Alwadai
The Cr–CsPbIBr2 device showed enhanced performance, with increased grain size, reduced energy band gap, and elevated efficiency from 9.64% to 12.06%.
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Adsorption behavior of chloramphenicol on an activated carbon from pomelo peel using KHCO3 activator

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New J. Chem., 2024, 48,7081-7091
DOI: 10.1039/D3NJ05838G, Paper
Haixia Li, Hai Zhu, Junqiang Qiu, Danning Zheng, Lifang Gao, Dan Zhou, Dan Xu
The pomelo peel-based activated carbon as a high-performance adsorbent for chloramphenicol is synthesized by KHCO3 activator through a solid pyrolysis method.
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Ligand-free ultrasmall palladium nanoparticle catalysis for the Mizoroki–Heck reaction in aqueous micelles

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New J. Chem., 2024, 48,7102-7110
DOI: 10.1039/D3NJ05715A, Paper
Xiaojun Luo, Siyuan Wu, Linxi Hou, Xin Ge
A simple and sustainable strategy is proposed to construct a nanoreactor by connecting micelles with in-situ prepared ultrasmall Pd NPs to efficiently catalyze the Mizoroki-Heck reaction.
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Effects of silylene ligands on the catalytic activity of [PSiP] pincer cobalt(II) chloride for N2 silylation

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New J. Chem., 2024, 48,7334-7339
DOI: 10.1039/D4NJ00883A, Paper
Min Zhang, Yanhong Dong, Qingshuang Li, Xiaoyan Li, Hongjian Sun
Three silyl [PSiP] pincer cobalt(II) chlorides [(2-Ph2PC6H4)2MeSiCo(Cl)(PMe3)] (1), [(2-iPr2PC6H4)2MeSiCo(Cl)(PMe3)] (2) and [(2-Ph2PC6H4)2MeSiCo(Cl)(LSi:)] (LSi: = {PhC(NtBu)2}SiCl) (3) were used as catalysts for dinitrogen silylation was studied.
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Mechanochemical synthesis of biphenyl-derived organic fluorescent materials via solvent-free and ligand-free oxidative homocoupling reactions

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New J. Chem., 2024, 48,7356-7361
DOI: 10.1039/D4NJ00886C, Paper
Zefeng Li, Caihang Zhang, Yingxuan Zheng, Ping Deng, Yan Yu
The palladium-catalyzed solvent-free and ligand-free oxidative homocoupling reactions of aryl boronic acids via ball-milling are developed to synthesize a series of biphenyl-derived organic fluorescent materials.
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Rhodium-catalysed homo-coupling of terminal alkynes: divergent synthesis of bioactive 1,3-diynes and conjugated enediynes

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New J. Chem., 2024, 48,7517-7523
DOI: 10.1039/D4NJ00366G, Paper
Yijie Xiao, Lijie Lv, Nanxuan Luo, Peirui Zhao, Yao Chen, Zhangshun Luo, Houhua Yin, Yi He, Shenyou Nie
C(sp)–C(sp) cross-coupling of terminal alkynes represents a robust tool for building biologically active 1,3-diynes although confronted with huge challenges regarding selectivity control.
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