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Formation of Fe(III)–As(V) complexes: effect on the solubility of ferric hydroxide precipitates and molecular structural identification

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00024H, Paper
Qiantao Shi, George E. Sterbinsky, Shujuan Zhang, Christos Christodoulatos, George P. Korfiatis, Xiaoguang Meng
Soluble Fe(III)–As(V) complexes were found at both acidic and neutral conditions, which significantly change the solubility of ferric oxides.
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Nanoparticulate zero valent iron interaction with dissolved organic matter impacts iron transformation and organic carbon stability

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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00197J, Paper
Yanlong Wang, Kun Yang, Daohui Lin
Although there is an increasing use of nanoparticulate zero-valent iron (nZVI) in the remediation of contaminated soil and water environments, there is still little understanding of the mechanisms of interaction...
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Multivariate analysis of the exposure and hazard of ceria nanomaterials in indoor aquatic mesocosms

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01439J, Paper
Mohammad Nassar, Mélanie Auffan, Catherine Santaella, Armand Masion, Jérôme Rose
Associating mesocosm experimentations with multivariate analyses to identify the parameters governing the behavior and impact of nanomaterials on aquatic ecosystems.
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Silica Nanoparticles Alleviate Mercury Toxicity via Immobilization and Inactivation of Hg(II) in Soybean (Glycine max)

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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00091D, Paper
Yunyun Li, Nali Zhu, Xujun Liang, Xu Bai, Lirong Zheng, Jiating Zhao, Yu-Feng Li, Zhiyong Zhang, Yuxi Gao
Mercury (Hg) pollution is a worldwide concern. Silica nanoparticles (Nano-SiO2) can be released into ecosystems through natural and anthropogenic (engineered Nano-SiO2) processes. Here, the influence of two sizes (30 nm...
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Development and application of a ratiometric nanosensor for measuring pH inside the gastrointestinal tract of zooplankton

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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01300H, Paper
Open Access
Adam Davis, Fatima Nasser, Jamie R Lead, Zongbo Shi
The pH within the gastrointestinal (GI) tract of zooplankton regulates the bioavailability of nutrients and inorganic toxins (metals, nanoparticles) and the breakdown of ingested food. However, measuring the spatial distribution...
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Dominant effect of the grain size of the MAPbI3 perovskite controlled by the surface roughness of TiO2 on the performance of perovskite solar cells

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CrystEngComm, 2020, 22,2718-2727
DOI: 10.1039/D0CE00169D, Paper
Methawee Nukunudompanich, Gekko Budiutama, Kazuma Suzuki, Kei Hasegawa, Manabu Ihara
The surface roughness of the c-TiO2 layer help controls the perovskite grain size without any other parameter. The direct effect of perovskite grain size on PSC performance is clarified.
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Static disorder in a perovskite mixed-valence metal–organic framework

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CrystEngComm, 2020, 22,2859-2865
DOI: 10.1039/D0CE00119H, Paper
Ines E. Collings, Paul J. Saines, Mirko Mikolasek, Tiziana Boffa Ballaran, Michael Hanfland
Effects of A-site and M-site substitutions on the structural properties of perovskite dimethylammonium iron formate.
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Melting point–solubility–structure correlations in chiral and racemic model cocrystals

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CrystEngComm, 2020, 22,2766-2771
DOI: 10.1039/D0CE00014K, Paper
Ornella E. Y. Kilinkissa, Krishna K. Govender, Nikoletta B. Báthori
Comparison of chiral and racemic binary cocrystals showed that the chiral building block limits the formation of certain intermolecular interactions, decreases the packing efficiency, lowers the melting point and increases aqueous solubility.
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Discovery of new polymorphs of the tuberculosis drug isoniazid

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CrystEngComm, 2020, 22,2705-2708
DOI: 10.1039/D0CE00440E, Communication
Keke Zhang, Noalle Fellah, Alexander G. Shtukenberg, Xiaoyan Fu, Chunhua Hu, Michael D. Ward
Two new metastable polymorphs of the tuberculosis drug isoniazid, considered monomorphic for sixty years, were discovered using melt crystallization and nanoscale confinement.
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Investigation on the interconversion from DMF-solvated to unsolvated copper(II) pyrazolate coordination polymers

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00370K, Paper
Corrado Di Nicola, Alessia Tombesi, Marco Moroni, Rebecca Vismara, Fabio Marchetti, Riccardo Pettinari, Luca Nardo, Guglielmo Vesco, Simona Galli, Silvia Casassa, Luciano Pandolfo, Claudio Pettinari
Enlarging the family of CPs with the {Cu(μ-pz)2} building unit: synthesis, thermal behaviour, crystal structure and spectroscopic properties of [Cu(μ-4-Xpz)2(μ-DMF)]n (4-Xpz = 4-Xpyrazolate, X = H, Cl, Br, I) and the non-solvated counterparts.
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Supramolecular association of M2+⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication
Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, Pt2+; L2 = dinaphthoylmethanido−), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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Mesoporogen-free synthesis of hierarchical HZSM-5 for LDPE catalytic cracking

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00255K, Paper
Yunhao Zang, Jinying Wang, Jianfeng Gu, Jiangying Qu, Feng Gao
Herein, a mesoporogen-free, and steam-assisted route is proposed to synthesize highly crystalline hierarchical HZSM-5 using Stöber silica spheres as the precursor. The effect of crystallization time on the morphology and...
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Role of Surface Phenomena on the Reaction of Molecular Solids: the Diels-Alder Reaction on Pentacene

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00269K, Paper
Selma Piranej, Michael A. W. Shelhart Sayers, Gregory J. Deye, Sergey N. Maximoff, Jonathan P. Hopwood, Haejun Park, Jean G. Slavsky, Jacob Ciszek
Reactivity trends for molecular solids cannot be explained exclusively through topochemical phenomenon (i.e. diffusivity, reaction cavities) or electronic structure of the molecules. As an example of this class, Diels-Alder reactions...
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Crystal nucleation of salicylamide and a comparison with salicylic acid

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00168F, Paper
Shubhangi Kakkar, K. Renuka Devi, Michael Svärd, Åke Rasmuson
Nucleation behaviour of salicylamide in different solvents was determined and compared with salicylic acid, attempting to progress the rationalization of the influence of the solvent and solute on crystal nucleation of organic compounds in solution.
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A novel synthesis of YVO4:Ln3+ (Ln = Eu, Sm, and Dy) porous/hollow submicro-ellipsoids and their luminescence properties

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00526F, Paper
Shuang Zhao, Baiqi Shao, Yang Feng, Senwen Yuan, Langping Dong, Liang Zhang, Hongpeng You
A novel synthesis strategy of porous/hollow YVO4 submicro-ellipsoids with multicolor emissions has been developed based on the high structural matching of LYH and YVO4.
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Self-assembled natLiCl–CeCl3 directionally solidified eutectics for thermal neutron detection

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/C9CE01884K, Communication
Shuangliang Cheng, Rachel E. Hunneke, Mengkun Tian, Eric Lukosi, Mariya Zhuravleva, Charles L. Melcher, Yuntao Wu
We developed novel LiCl–CeCl3 eutectic scintillators that are capable of detecting thermal neutrons.
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Design, screening, and properties of novel solvates of azoxystrobin based on isomorphism

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00204F, Paper
Zhi-Ping Shi, Guo-Bin Ren, Ming-Hui Qi, Zhong Li, Xiaoyong Xu
Based on reported isomorphism of Azoxystrobin (AZO) solvates, five novel AZO solvates, including dimethyl succinate solvate (AZO-DMS), ethyl butyrate solvate (AZO-EB), thiophene solvate (AZO-TP), furan solvate (AZO-FN), and 1,2-diethoxyethane solvate...
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The effect of deuteration-levels in solution and temperature on the segregation coefficient of deuterium content in rapid-grown K(DxH1-x)2PO4 crystals using Raman spectroscopy

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00386G, Paper
Jinxin Huang, Zongqi Wang, Bing Teng, Hong Liu, Xixi Zheng, Shaohua Ji
A series of K(DxH1-x)2PO4 (DKDP) crystals with different saturating temperature and deuteration levels were grown by point-seed rapid growth method. The correlation between deuterium segregation coefficient and temperature and deuterium...
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First Preparation of Microporous AFY-type MeAPO by Topotactic Pillaring of Lamellar Aluminophosphate Precursor

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00644K, Communication
Kazuyuki Maeda, Kentaro Wakui, Kyosuke Arakawa, Atsushi Kondo
Topotactic pillaring of lamellar aluminophosphate (ALPO) layers with zinc cations is used to prepare microporous zincoaluminophosphate (ZnAPO) with AFY-type framework for the first time. This approach should be promising for...
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Diminishing accessibility of electrophilic nickel(II) centres due to incorporation of a methylene spacer in the pendant side arm of a series of heterotrinuclear nickel(II)/sodium complexes: a DFT study using a homodesmotic equation

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CrystEngComm, 2020, 22,2970-2977
DOI: 10.1039/D0CE00251H, Paper
Prasanata Kumar Bhaumik, Abhisek Banerjee, Tamal Dutta, Sudipta Chatterjee, Antonio Frontera, Shouvik Chattopadhyay
The ethoxy groups have a dual effect in hindering the attack of the pseudo-halides on the nickel(II) centre and also in stabilizing the complex by intra-molecular interactions.
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Influence of lamellar thickness on the transformation of isotactic polybutylene-1/carbon nanotube nanocomposites

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CrystEngComm, 2020, 22,2990-2997
DOI: 10.1039/D0CE00112K, Paper
Yan-Kai Li, Yu-Ge Wang, Cui-Liu Fu, You-Liang Zhu, Zhan-Wei Li, Zhao-Yan Sun
The crystallization transformation from form II to form I in PB-1/CNT materials is mainly influenced by the lamellar thickness.
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Step-by-step: uncommon SCSC transformation accompanied by stepwise change in the binding of a particular ligand within a mononuclear complex upon stepwise desolvation

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CrystEngComm, 2020, 22,2895-2899
DOI: 10.1039/D0CE00379D, Communication
Andrey V. Gavrikov, Andrey B. Ilyukhin, Pavel S. Koroteev
Uncommon SCSC transformation when desolvation induces subtle changes within a mononuclear complex, namely a stepwise change in the binding of a particular ligand.
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A theoretical insight on the rigid hydrogen-bonded network in the solid state structure of two zinc(II) complexes and their strong fluorescence behaviors

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CrystEngComm, 2020, 22,3005-3019
DOI: 10.1039/D0CE00125B, Paper
Ipsita Mondal, Tanmoy Basak, Snehasis Banerjee, Shouvik Chattopadhyay
A reduced Schiff base used as a fluorescence chemo-sensor for selective detection of zinc(II). Strong fluorescence behaviors of two zinc(II) complexes are correlated with the presence of a rigid hydrogen-bonded network in their solid state structure.
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Solution and calorimetric thermodynamic study of a new 1:1 sulfamethazine – 3- methylsalicylic acid co-crystal

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00498G, Paper
Dipali Ahuja, Michael Svärd, Matteo Lusi, Ake Rasmuson
A new 1:1 co-crystal of sulfamethazine (API, SMT) and 3-methylsalicylic acid (coformer, 3mSA) has been synthesized and its crystal structure solved by single crystal X-ray diffraction (XRD). The co-crystal has...
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3C–, 4H–, and 6H–SiC crystal habitus and interfacial behaviours in high temperature Si-based solvents

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00521E, Paper
Taka Narumi, Didier Chaussende, Takashi Yoshikawa
Solution growth of SiC is a promising process for producing high-quality SiC crystals; however, control over the morphology of the growth interface under rapid growth conditions is a critical issue....
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The impact of positional isomerism on electronic and photochromic properties of 1D zinc-based naphthalene diimide coordination polymers

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00025F, Paper
Pengfei Hao, Huihui Zhu, Yue Pang, Junju Shen, Yunlong Fu
The positional isomeric DPNDI ligands can effectively modulate the interfacial contacts of electron donors/acceptors and the efficiency of electronic/photochromic properties.
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Peculiarities of Br⋯Br bonding in crystal structures of polybromides and bromine solvates

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00288G, Paper
Anna V. Vologzhanina, Petr A. Buikin, Alexander A. Korlyukov
Analysis of supramolecular associates formed by Br⋯Br interactions in crystals of 204 polybromide and bromine-containing compounds has been carried out.
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Solvatomorphism and phase transformation of CL-20: probing properties and investigating mechanisms

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00059K, Paper
Bochen Pan, Zhanzhong Wang, Yichun Shen, Liangxiao Wei, Hongyuan Wei, Leping Dang
Five novel CL-20 solvates were prepared and fully characterized, and the solvate formation and phase transformation processes were systematically investigated.
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Chirality and Stereoisomerism of Organic Multicomponent Crystals in the CSD

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00403K, Paper
Open Access
Eline Grothe, hugo meekes, Rene de Gelder
With the current interest in multicomponent crystals containing chiral residues, a wide variety of studies could benefit from a comprehensive inventory of chirality in multicomponent crystals. We combined computational approaches...
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Two Co-based MOFs assembled from an amine-functionalized pyridinecarboxylate ligand: inorganic acid-directed structural variety and gas adsorption properties

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00475H, Paper
Zhenzhen Jiang, Ping Zhou, Tingting Xu, Lihui Fan, Simin Hu, Jingxian Chen, Yabing He
A pair of Co-based MOFs exhibited inorganic acid-driven structural diversities, and one of them displayed the C2H2 separation and purification potential.
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A crystalline solid adduct of sulfathiazole-amantadine: The first dual-drug molecular salt containing both antiviral and antibacterial ingredients

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00368A, Paper
Ling-Yang Wang, Yueming Yu, Ming-Chao Yu, Yan-Tuan Li, Zhi-Yong Wu, Cui-Wei Yan
The first molecular salt concurrently combining antibacterial drug sulfathiazole (SFZ) and antiviral constituent amantadine (ATD) is designed and successfully synthesized via salification strategy. The precise structure of the newly obtained...
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Facile One–pot Solvothermal Synthesis of CdTe Nanorods and Their Photoelectrical Properties

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00459F, Communication
Binnian Zhong, Weifeng Kang, Zhiwei Zhang, Linhui Zhang, Bin Ma
Uniform CdTe NRs were synthesized by a one-pot PVP-assisted solvothermal process under mild conditions. By adjusting the amounts of the surfactant, reducing agent and the reaction temperature, CdTe NRs with...
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A Malayalam song from Italy to beat the pandemic

By www.thehindu.com
Published On :: Sat, 09 May 2020 14:56:28 +0530

As Italians sing on their balconies to keep their morale high, this priest renders 'Aayiram Kannumayi' from the 1984 film 'Nokketha Doorathu Kannum Nattu'


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Uncertainty shocks and business cycle research [electronic resource] / Jesús Fernández-Villaverde, Pablo A. Guerrón-Quintana

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Medicaid physician fees and access to care among children with special health care needs [electronic resource] / Pinka Chatterji, Sandra Decker, Jason U. Huh

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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A method to construct geographical crosswalks with an application to US counties since 1790 [electronic resource] / Fabian Eckert, Andrés Gvirtz, Jack Liang, Michael Peters

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Information acquisition, efficiency, and non-fundamental volatility [electronic resource] / Benjamin M. Hébert, Jennifer La'O

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Confirmatory bias in health decisions [electronic resource] : evidence from the MMR-Autism controversy / Mengcen Qian, Shin-Yi Chou, Ernest K. Lai

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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Beyond basis basics [electronic resource] : leverage demand and deviations from the law of one price / Todd M. Hazelkorn, Tobias J. Moskowitz, Kaushik Vasudevan

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Does race matter for police use of force? [electronic resource] : Evidence from 911 calls / Mark Hoekstra, CarlyWill Sloan

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Advance market commitments [electronic resource] : insights from theory and experience / Michael Kremer, Jonathan D. Levin, Christopher M. Snyder

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Forward guidance and household expectations [electronic resource] / Olivier Coibion, Dimitris Georgarakos, Yuriy Gorodnichenko, Michael Weber

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Media competition and news diets [electronic resource] / Charles Angelucci, Julia Cagé, Michael Sinkinson

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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Trade, globalization and poverty [electronic resource] / edited by Elias Dinopoulos [and others]

By darius.uleth.ca
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London ; New York : Routledge, 2008


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Assessing the suitability of the Longitudinal and International Study of Adults for the estimation of intergenerational income mobility [electronic resource] / by Gaëlle Simard-Duplain and Xavier St-Denis

By darius.uleth.ca
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Ottawa : Statistics Canada = Statistique Canada, 2020


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Charity and mutual aid in Europe and North America since 1800 [electronic resource] / edited by Bernard Harris and Paul Bridgen

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New York : Routledge, 2007


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The coronavirus and the Great Influenza Pandemic [electronic resource] : lessons from the "Spanish Flu" for the coronavirus's potential effects on mortality and economic activity / Robert J. Barro, José F. Ursúa, Joanna Weng

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Cambridge, Mass. : National Bureau of Economic Research, 2020


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What will be the economic impact of COVID-19 in the US? [electronic resource] : Rough estimates of disease scenarios / Andrew Atkeson

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2020


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The macroeconomics of epidemics [electronic resource] / Martin S. Eichenbaum, Sergio Rebelo, Mathias Trabandt

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Cambridge, Mass. : National Bureau of Economic Research, 2020


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The postcolonial politics of development [electronic resource] / Ilan Kapoor

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London ; New York : Routledge, 2008


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