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Multifunctional zeolite film enables stable high-voltage operation of LiCoO2 cathode

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04370G, Paper
Zezhou Lin, Yiran Ying, Zhihang Xu, Gao Chen, Xi Gong, Zehua Wang, Daqin Guan, Leqi Zhao, Mingyang Yang, Ke Fan, Tiancheng Liu, Hao LI, Honglei Zhang, Huangxu Li, Xi Zhang, Ye Zhu, Zhou-Guang Lu, Zongping Shao, Peiyu Hou, Haitao Huang
Increasing upper cut-off voltage is a useful way for enhancing specific capacity of LiCoO2 (LCO) cathode and the energy density of corresponding lithium-ion batteries (LIBs), while the main challenge is...
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Row over CPI(M) leader E.P. Jayarajan’s yet to be published autobiography

Jayarajan clarifies that though he is working on an autobiography, it remains unfinished, and no one has been authorised to publish or distribute it




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E.P. Jayarajan’s ‘autobiography’ row: publishing house remains tight lipped, refuses to clear the air

Jayarajan claims that circulating excerpts from his ‘autobiography’ are baseless nonsense and asserts that he had not granted publishing rights for his autobiography to any establishment




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Tata Power Renewable Energy unveils 126 MW Omkareshwar floating solar project, setting new global standards

With this project, TPREL’s total renewable capacity reaches 10.9 GW, reinforcing its position in India’s journey towards a greener energy future.




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Germany to hold snap elections on February 23 as coalition crumbles under economic strain




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South Korea to double marine protection zone, address climate change




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Affordable generics will stay relevant amid a premiumisation trend: Bhushan Akshikar

GSK will keep its existing portfolios while entering areas like oncology, said company officials at its centenary celebrations




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UN report warns nitrous oxide emissions impact public health




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But this blog goes up to eleven

So that Trent Walton went and redesigned his blog. And it is responsive. And on top of all that? It is sexy.

I’ve been admiring the Paravel team’s work for some time, and especially their dabblings in responsive design; if you haven’t seen the Do Lectures site, give it a whirl. It’s visually and technically impressive, and is a joy to browse at any resolution.

But that’s not all: given Trent’s penchant for full-width, type-heavy headings, he and the team at Paravel decided to knock out FitText, a jQuery plugin to create full-width, scaleable headlines from, well, your headlines. I can’t wait to give this a whirl.

Of course, in the middle of this cornucopia of goddamned fantastic things, Trent has to go and drop beats like this:

My love for responsive centers around the idea that my website will meet you wherever you are—from mobile to full-blown desktop and anywhere in between.

Emphasis mine. That sentence—that sentiment—is so good, I want it tattooed on my knuckles.

(Hrm. Wonder if there’s a jQuery plugin for that.)




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Rejuvenating manganese-based rechargeable batteries: fundamentals, status and promise

J. Mater. Chem. A, 2024, 12,8617-8639
DOI: 10.1039/D4TA00466C, Review Article
Weizhai Bao, Hao Shen, Yangyang Zhang, Chengfei Qian, Dingyu Cui, Jingjie Xia, He Liu, Cong Guo, Feng Yu, Jingfa Li, Kaiwen Sun
Energy storage devices with advanced rechargeable batteries are highly demanded by our modern society.
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Crystal reconstruction and defect healing enabled high-quality Sb2Se3 films for solar cell applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00734D, Paper
Qi Zhao, Bo Che, Haolin Wang, Xiaoqi Peng, Junjie Yang, Rongfeng Tang, Changfei Zhu, Tao Chen
A post-sulfurization technique has been developed to refine Sb2Se3 crystallization. This process enables high-quality Sb2Se3 with a smooth surface, large compact crystal grains and benign [hkl] growth orientation. It also mitigates the device VOC deficit, owing to the healed deep level defects.
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Identifying lithium difluoro(oxalate)borate as a multifunctional electrolyte additive to enable high-voltage Li4Ti5O12 lithium-ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00750F, Paper
Ou Ka, Fang Cheng, Lang Wen, Xiaoqu Wang, Ting Wang, Xinyu Zeng, Wen Lu, Liming Dai
Lithium difluoro(oxalate)borate (LiDFOB) is identified as a multifunctional electrolyte additive, stabilizing the electrolyte and protecting the electrodes, to enable the LiNi0.5Mn1.5O4//Li4Ti5O12 battery with an excellent performance at 3.50 V.
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Correction: Super-adsorbent hydrogel for removal of methylene blue dye from aqueous solution

J. Mater. Chem. A, 2024, 12,9242-9246
DOI: 10.1039/D4TA90061H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao-Sai Hu, Rui Liang, Guoxing Sun
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Soft-oxometalates (SOMs): crafting the pillars of a sustainable future

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07580J, Review Article
Nidhi Kumari, Soumyajit Roy
Soft-oxometalates as a tool of chemical science for designing sustainable solutions.
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A review of noble metal-free high entropy alloys for water splitting applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00690A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hamzah Kamaruddin, Zhang Jianghong, Liang Yu, Wei Yuefan, Huang Yizhong
Nano-sized high entropy alloy (HEA) catalysts have attracted much attention as extraordinary electrocatalysts in water-splitting applications, i.e., the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER).
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Photothermal conversion enabled temperature modulation for the growth of complex polymorphic architectures of calcium carbonate

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00802B, Paper
Boning Shi, Lifu Zhang, Zeda Yang, Jiangnan Deng, Shun An, Benwei Fu, Chengyi Song, Peng Tao, Tao Deng, Wen Shang
As a highly efficient and eco-friendly heat generation approach, photothermal conversion process has been applied to many important areas such as desalination and medical treatments. We explored in this work...
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Prolonging exciton diffusion length via manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells over 19% efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00594E, Paper
Wang Ke, Fuwen Zhao, Yufan Zhu, Yi He, Zesheng Liu, Xiao Han, Qi Ai, Xingxing Shen, Bao Li, Jianqi Zhang, Yuze Lin, Chun-Ru Wang, Dan He
The limited exciton diffusion length (LD) of organic semiconductors constraints exciton dissociation in pseudo-planar heterojunction (PPHJ) organic solar cells (OSCs), which is deemed as the bottleneck issue hampering the further...
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Rapid in situ growth of high-entropy oxide nanoparticles with reversible spinel structures for efficient Li storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA08101J, Paper
Open Access
Siyu Zhu, Wei Nong, Lim Jun Ji Nicholas, Xun Cao, Peilin Zhang, Yu Lu, Mingzhen Xiu, Kang Huang, Gang Wu, Shuo-Wang Yang, Junsheng Wu, Zheng Liu, Madhavi Srinivasan, Kedar Hippalgaonkar, Yizhong Huang
Using laser radiation, high-entropy nanoparticles were rapidly fabricated on conductive carbon. The high-entropy nanomaterials with reversible spinel structures exhibit better cycling and rate performances in LIBs.
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Probing the potential of Al2CO/SiC heterostructures for visible light driven photocatalytic water splitting using first-principles strategies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00885E, Paper
Amina Shehbaz, Abdul Majid, Hira Batool, Mohammad Alkhedher, Sajjad Haider, Kamran Alam
Photocatalytic water splitting is a sustainable and eco-friendly method for renewable energy production. The fabrication of an efficient photocatalyst based on two-dimensional (2D) interfaces with suitable band offsets is at...
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A sacrificial separator facilitating in situ creation of a durable CEI layer and tailoring lithium dendrites for practical lithium metal batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01234H, Paper
Sung Joon Park, Yun Jeong Choi, Jaemun Cheon, Hyungjun Kim, Jong-Won Lee, Taeeun Yim, Ki Jae Kim
The TBB–PE separator can form a robust and uniform boron-rich CEI (cathode electrolyte interphase) layer on the cathode surface via electrochemical oxidation as well as inhibit the growth of lithium dendrites by anion anchoring.
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Scalable preparation of flexible heterogeneous graphene oxide structures for high performance wet power generation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01819B, Paper
Yu Gao, Xiaoming Cai, Yuzhou Zhao, Wentian Huang, Jian Lv, Jie Wang, Zhenliang Hao, Huiming Liang, Honglin Tan, Jinming Cai
Moisture-driven energy generation (MEG) has attracted great attention in recent years, and the interaction of functionalized nanomaterials with water offers the possibility of MEG. However, current MEG devices require specific...
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Bi-intercalated vanadium pentoxide synthesized via hydrogen peroxide-induced phase transition for highly stable cathode in aqueous zinc ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07984H, Paper
Jian-an Chen, Xuejun Hou, Xueli Wang, Chunxia Wang, Jiawei Wen, Yongjie Bu, Guoyong Huang, Tiantian Cao, Shengming Xu
Operating principle of aqueous zinc-ion batteries (ZIBs).
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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Renewable Aromatic Hydrocarbons from Waste Cooking Oil over Hierarchical Imidazole Supported Zeolite

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00416G, Paper
Bipul Sarkar, Bhanu Joshi, Omvir Singh, Ankit Agrawal, Neha Dhiman, Bhanu Prasad Vempatapu, Navin Gopinathan , Anjan Ray
Unlike coal, oil, or natural gas, waste cooking oil (WCO) acts as a renewable source of carbon. It can be converted into energy, fuels, and fine chemicals, instead of being...
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Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
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A full metal-free flexible ammonium-ion battery with biodegradable hydrogel electrolyte

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00249K, Paper
Abhishek Paudel, Ajalynn N. Crum, Ying Wang
In this work, a full flexible metal-free battery is developed using a QSS hydrogel electrolyte sandwiched between a PANI anode and PPy cathode enabling the battery to operate and maintain its performance while bent or twisted.
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In situ construction of a double perovskite heterostructure with exsolved FeNi3 alloy nanoparticles for CO2 electrolysis in solid oxide electrolysis cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07820E, Paper
Xiaoyu Wang, Haibo Hu, Caiyue Xie, Yifei Wang, Haowei Li, Xifeng Ding
FeNi3 nanoparticles anchored on the (PrBa)0.95Fe1.6Ni0.4O6−δ double perovskite enhance the electrochemical performance and durability in direct CO2 electrolysis.
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Multifunctional buried interface modification for efficient and stable SnO2-based perovskite solar cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00108G, Paper
Rui Wu, Junhua Meng, Yiming Shi, Zhengchang Xia, Chunxia Yan, Lisheng Zhang, Wenkang Liu, Jinliang Zhao, JinXiang Deng, Xing Wang Zhang
Buried interface modification with multiple roles is key to boost the performance of perovskite solar cells (PSCs). Herein, a multifunctional passivator, N-(2-hydroxyethyl) ethylene diamine triacetic acid trisodium salt (HEDTA-3Na), is...
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Highly stable photovoltaic effects in A2+–Zr4+ (A = Ca, Sr, Ba) co-doped BiFeO3 films with self-polarization

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00649F, Paper
Lei Shi, Wenyue Zhao, Zhao Wang, Wenjing Hua, Xiaoxia Yang, Weidong Fei, Yu Zhao
The photovoltaic responses and temperature stabilities of A2+–Zr4+ (A = Ca, Sr, Ba) composite doped BiFeO3 films with self-polarization were enhanced in the R to MA phase transition.
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Molecular-polaron-coupling-enhanced photocatalytic CO2 reduction on copper phthalocyanine/NiMgFe layered double hydroxide nanocomposites

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07538A, Paper
Yuexian Li, Wenli Su, Xiaoyan Wang, Jun Lu, Wenkai Zhang, Shuo Wei
We built CuPcS/NiMgFe-LDHs composites and probed the unique photogenerated-carrier transfer mechanism. A series of long-range Forster energy transfers prolonged the lifetime of photogenerated carriers to match the timescale of surface reaction.
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Machine Learning Enabled Exploration of Multicomponent Metal Oxides for Catalyzing Oxygen Reduction in Alkaline Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01884B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xue Jia, Hao Li
Low-cost metal oxides have emerged as promising candidates used as electrocatalysts for oxygen reduction reaction (ORR) due to their remarkable stability under oxidizing conditions, particularly in alkaline media. Recent studies...
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Highly selective and high-performance sulfonated poly(ether ether ketone)-based hybrid membrane enabled by complexed UiO-66-NH2 and sulfonated graphitic carbon nitride for vanadium flow battery

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00988F, Paper
Caiyuan Zhao, Haixia Wang, Lang Li, Liping Liu, Xinrui Cui, Haifeng Shi
A series of sulfonated poly(ether ether ketone) (SPEEK) hybrid membranes (SPEEK/NF) with a constant 1 wt% complexed nanofillers (NF) comprising of UiO-66-NH2 and sulfonated graphitic carbon nitride (s-g-C3N4) are prepared...
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Plasticity tunable artificial synapses based on organic electrochemical transistors with aqueous electrolytes

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03569K, Paper
Ruhua Wu, Miao Xie, Yuhua Cheng, Dan Zhao, Liang-Wen Feng, Jianhua Chen, Wei Huang
By regulating ion transporting kinetics and ion diffusion distances in organic mixed ionic–electronic conductor channels, highly tunable short- and long-term plasticity are obtained in vOECTs with aqueous electrolytes.
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Pi-extended hypervalent iodine macrocycles and their supramolecular assembly with Buckminsterfullerene

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04251D, Paper
Krishna Pandey, Samsul Arafin, Grayson Venus, Eli Jones, Yachu Du, Mina Dumre Pandey, Tahir Awais, Lichang Wang, Kyle N. Plunkett
Hypervalent iodine based macrocycles with enlarged aromatic cores can form extended supramolecular assemblies with Buckminsterfullerene.
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The Mushroom Color Atlas: An Interactive Web Site Lets You Explore the Incredible Spectrum of Colors Created from Fungi

Enter the Mushroom Color Atlas, and you can discover the “beautiful and subtle colors derived from dyeing with mushrooms.” Featuring 825 colors, each associated with different types of mushrooms, the interactive atlas lets you appreciate the broad spectrum of colors latent in the fungi kingdom. The shades, tints, and hues will surprise you. Julie Beeler, […]




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A New 3D Scan, Created from 25,000 High-Resolution Images, Reveals the Remarkably Well-Preserved Wreck of Shackleton’s Endurance

Photos on this page courtesy of the Falklands Maritime Heritage  Few who hear the story of the Endurance could avoid reflecting on the aptness of the ship’s name. A year after setting out on the Imperial Trans-Antarctic Expedition in 1914, it got stuck in a mass of drifting ice off Antarctica. There it remained for ten months, […]




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Children’s Day: public meet, rally led by girls to be held in Thiruvananthapuram

25,000 students from 200 schools will be part of the rally




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Hope SC will hold accountable those who reduced homes to rubble: Mehdi

“I hope that the court will hold accountable those who have committed these crimes, and have reduced homes to rubble.”




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Vegetable prices sky-rocket in October, food inflation at 10.87%, CPI at 6.21 %




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Public Sector Banks records strong performance in 1st half of FY25




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Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024




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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri




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An Efficient All-Visible Light-Activated Photoswitches Based on Diarylethenes and CdS Quantum Dots

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06110A, Edge Article
Open Access
Kezhou Chen, Jiayi Liu, Joakim Andréasson, Bo Albinsson, Tiegen Liu, Lili Hou
All-visible light-activated diarylethene (DAE) photoswitches are highly attractive for applications in smart photoresponsive materials. Photocyclization of DAE via the low-lying excited triplet state through triplet energy transfer (TET) from a...
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Synthesis of highly condensed phospholes by Lewis acid-assisted dehydrogenative Mallory reaction under visible light irradiation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05657D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ikki Kamiyoshi, Yuki Kojima, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano
A photo-promoted oxidative cyclization, that is, Mallory reaction of 2,3-diarylbenzophopholes has been developed. With an assistance of Bi(OTf)3 Lewis acid, the reaction proceeds smoothly under visible light irradiation even without...
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No gaps in management of biodegradable waste, Kerala tells NGT




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Iran executes in public a serial rapist convicted in dozens of cases

Iran’s state media say authorities have executed in public a man convicted of raping dozens of women over two decades




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A photoswitchable CENP-E inhibitor with single blue-green light to control chromosome positioning in mitotic cells

RSC Med. Chem., 2024, 15,3795-3799
DOI: 10.1039/D4MD00458B, Research Article
Kazuya Matsuo, Takashi Kikukawa, Tomonori Waku, Akio Kobori, Nobuyuki Tamaoki
A photoswitchable centromere-associated protein E (CENP-E) inhibitor based on the 4-methylaminoazobenzene photoswitch is reported, which is characterized with cistrans photoisomerization with blue-green light and fast thermal relaxation.
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Pyridinyl 4-(2-oxoalkylimidazolidin-1-yl)benzenesulfonates and their hydrochloride salts as novel water soluble antimitotic prodrugs bioactivated by cytochrome P450 1A1 in breast cancer cells

RSC Med. Chem., 2024, 15,3728-3745
DOI: 10.1039/D4MD00476K, Research Article
Vincent Ouellette, Chahrazed Bouzriba, Atziri Corin Chavez Alvarez, Quentin Bruxelles, Geneviève Hamel-Côté, Sébastien Fortin
New water soluble antimitotic CYP1A1-activated prodrugs named PYRAIB-SOs and their hydrochlorides targeting breast cancers.
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Advances in Detecting Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) Using Molecular Receptors and Nanostructured Assemblies

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00661E, Review Article
Avijit Kumar Das
The detection and quantification of non-steroidal anti-inflammatory drugs (NSAIDs) are crucial due to their widespread use and potential impact on human health and the environment. This review provides a comprehensive...
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