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Electrode process regulation for high-efficiency zinc metal anodes

J. Mater. Chem. A, 2024, 12,30169-30189
DOI: 10.1039/D4TA05143B, Review Article
Longkun Wu, Xinyan Zhu, Zhi Peng, Zekun Zhang, Ningning Zhao, Bin Li, Jing Zhu, Lei Dai, Ling Wang, ZhangXing He
Regulation strategies for zinc anode ion deposition.
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Revealing a synergistic orbital coupling adsorption mechanism of the oxygen reduction reaction in dual-atom catalysts

J. Mater. Chem. A, 2024, 12,30676-30684
DOI: 10.1039/D4TA05099A, Paper
Yangfan Liu, Yejun Li, Xinghan Liu, Jinming Li, Gufei Zhang, Jun Gong, Yanbin Jiang, Zhou Li
A synergistic adsorption mechanism of the oxygen evolution reaction for the dual atom catalysts (DACs) was proposed, which dominates the adsorption strength of intermediate species, potential determining step, and catalytic activity of DACs.
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Effects of hydrothermal etching and conversion on photocatalytic hydrogen evolution and overall water splitting with nanoparticulate and mesoporous TiO2 and SrTiO3/TiO2 composites

J. Mater. Chem. A, 2024, 12,30768-30782
DOI: 10.1039/D4TA03416C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lion Schumacher, Jana Timm, Roland Marschall
Hydrothermal treatment of mesoporous photocatalysts in diluted NaOH solution or H2O might be a simple and promising strategy to improve photocatalytic activities in general, as we show for TiO2 and SrTiO3/TiO2 composites.
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Enhanced electrocatalytic overall alkaline water splitting induced by interfacial electron coupling of Mn3O4 nano-cube@CeO2/γ-FeOOH nanosheet hetero-structure

J. Mater. Chem. A, 2024, 12,30783-30797
DOI: 10.1039/D4TA05336B, Paper
Debasish Ghosh, Dimple K. Bora, Asit Baran Panda
Mn3O4@CeO2/γ-FeOOH hetero-structure showed interfacial electron coupling induced superior bifunctional electrocatalytic activity suitable for AEM electrolyser.
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Catalytic kinetic growth of a half-metallic hexagonal boron nitride-graphene lateral heterostructure using transition metal single-atom catalysts on Rh(111)

J. Mater. Chem. A, 2024, 12,30498-30507
DOI: 10.1039/D4TA05741D, Paper
Yandi Zhu, Weihu Li, Xiaoyan Ren, Lili Zhang, Xingju Zhao, Shunfang Li
Transition metal single-atom catalysts (TM = Mn, Zr, Nb, Mo, Hf, Ta, and W) promote growth of a h-BN-G heterostructure on C-dimer-unpreferred Rh(111).
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A soft molecular single-source precursor approach to synthesize a nanostructured Co9S8 (pre)catalyst for efficient water oxidation and biomass valorization

J. Mater. Chem. A, 2024, 12,30522-30533
DOI: 10.1039/D4TA05436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Basundhara Dasgupta, Suptish Ghosh, Carsten Walter, Markus S. Budde, Georg J. Marquardt, Han-Hsu Chen, Markus G. M. Breithaupt, Tolga Yilmaz, Christoph Garmatter, Tamanna Ahamad, Ingo Zebger, Matthias Driess, Prashanth W. Menezes
A nanocrystalline Co9S8 (pre)catalyst derived from a novel {CoIIS4} complex is reported for the oxygen evolution reaction (OER) and selective biomass valorization. During OER, Co9S8 reconstructs completely into a CoOOH active phase via S-leaching.
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Machine learning for deconstructing contributions of atomic characterizations to achieve hybridization-determined electron transfer in a perovskite catalyst

J. Mater. Chem. A, 2024, 12,30722-30728
DOI: 10.1039/D4TA05018E, Paper
Jun Zhu, Mengdan Song, Qiling Qian, Yang Yue, Guangren Qian, Jia Zhang
Machine learning deconstructed the atomic contribution of a perovskite to catalytic toluene decomposition and found that wider hybridization resulted in smaller impedance, faster electron transfer speed, and enhanced catalytic activity.
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3D soft lithiophilic current collector of Ag-CuNW/MWCNT@melamine foam enables dendrite-free lithium metal anodes

J. Mater. Chem. A, 2024, 12,30601-30610
DOI: 10.1039/D4TA05955G, Paper
Song-Bai Xiang, Xiyu Zhang, Yue Hou, Wenjing Li, Chengri Yin, Zhenxing Yin
A 3D soft current collector with excellent lithiophilicity was obtained by constructing a conductive Ag-CuNW/MWCNT network on a melamine foam, which can effectively reduce the local current density and guide the uniform Li deposition.
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Modulating the band gap of a pyrazinoquinoxaline-based metal–organic framework through orbital hybridization for enhanced visible light-driven CN bond construction

J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper
Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped carbon nanotubes for stable Zn–air batteries with ultra-high power densities

J. Mater. Chem. A, 2024, 12,30798-30809
DOI: 10.1039/D4TA04194A, Paper
Manigandan Ramadoss, Hesheng Yu, Anand Rajkamal, Gun Jin Yun, Ziheng Zhang, Chengtao Yang, Fei Ma, Yu Wu, Chen Daiqian, Yuanfu Chen
Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped CNT deliver comparable OER behavior to RuO2, better ORR performance than Pt/C, and better ZAB performance than Pt/C–RuO2, due to the nanoarchitecture and abundant active sites.
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Unsaturated coordination modulation and enlarged pore size in nanoflower-like metal organic frameworks for enhanced lithium–oxygen battery performance

J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper
Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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Multifunctional characteristics of a one-dimensional bimetallic oxyhydroxide nanorod-coupled polyaniline interface for accelerated water and urea electrolysis

J. Mater. Chem. A, 2024, 12,30743-30756
DOI: 10.1039/D4TA05082G, Paper
Niranjanmurthi Lingappan, Sandhiya Lakshmanan, Wonoh Lee
Designing an efficient and durable electrocatalyst is central to hydrogen production technologies such as hydrogen evolution reaction, oxygen evolution reaction, and urea oxidation reaction.
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Optimization of the electron transfer kinetics between a photoanode and biocathode for enhanced carbon-neutral pollutant removal in photocatalytic fuel cells

J. Mater. Chem. A, 2024, 12,30371-30379
DOI: 10.1039/D4TA05290K, Paper
Xiaofei Gu, Jianyu Han, Zhi Wang, Yixin Hong, Tianyi Huang, Yafeng Wu, Yuanjian Zhang, Songqin Liu
A PFC system with collaborative dynamics between the photoanode and biocathode is constructed for using solar energy to efficiently convert refractory organic pollutants into green fuel and generate electricity.
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Synthesis of a Cu@ZnO1−x/Al2O3 catalyst with high-density ZnO1−x–Cu interfacial sites for enhanced CO2 hydrogenation to methanol

J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper
Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
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A review on instability factors of mono- and divalent metal ion batteries: from fundamentals to approaches

J. Mater. Chem. A, 2024, 12,30190-30248
DOI: 10.1039/D4TA05386A, Review Article
Elmira Kohan, Roushan Khoshnavazi, Mir Ghasem Hosseini, Abdollah Salimi, Mehdi Salami-Kalajahi
Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.
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An azo-receptor immobilized mesoporous honeycomb silica framework as a solid-state chromogenic sensor for capturing ultra-trace cadmium ions from environmental/industrial samples

J. Mater. Chem. A, 2024, 12,30567-30581
DOI: 10.1039/D4TA04574B, Paper
Anju P. Veedu, Balasurendran Jeyakumar, Akhila Maheswari Mohan, Satheesh Kuppusamy, Pitchaiah K. Chinaraga, Manjula Muthurathinam, C. V. S. Brahmananda Rao, Sivaraman Nagarajan, Prabhakaran Deivasigamani
A solid-state naked-eye sensor composed of a mesoporous honeycomb structured silica monolith impregnated with a DMTHBD receptor offers a simple, rapid and eco-benign approach for the selective sensing of trace Cd2+, with brilliant color transitions.
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Sulfur-doped g-C3N4/V2C MXene Schottky junctions for superior photocatalytic H2 evolution

J. Mater. Chem. A, 2024, 12,30429-30441
DOI: 10.1039/D4TA05929H, Paper
Haitao Wang, Jipeng Fan, Jing Zou, Yujie Zheng, Dingsheng Wang, Jizhou Jiang
An advanced sulfur-doped g-C3N4/V2C MXene (SCN/V2C) Schottky junction HER photocatalyst was prepared via vacuum ball milling and subsequent annealing.
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Electrochemical synthesis of wormcast-like Pd-based polycrystalline high entropy aggregates for methanol water co-electrocatalysis

J. Mater. Chem. A, 2024, 12,30757-30767
DOI: 10.1039/D4TA06304J, Paper
Yaxing Liu, Wenhao Ding, Jiaxin Liu, Guizhe Zhao, Weiyin Li, Yaqing Liu
A wormcast-like nanostructure of PdFeCoNiCu-pHENs with enriched grain boundary defects was synthesized via electrodeposition. This work opens new possibilities for designing advanced nanomaterials aimed at efficient electrochemical energy conversion.
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Tracking the active phase and reaction pathway of the OER mediated by an MnMoO4 microrod electro(pre)-catalyst

J. Mater. Chem. A, 2024, 12,30810-30820
DOI: 10.1039/D4TA05985A, Paper
Anubha Rajput, Ankita Kumari, Hirak Kumar Basak, Dibyajyoti Ghosh, Biswarup Chakraborty
MnMoO4 is a barely explored material for the electrocatalytic oxygen evolution reaction (OER) and in situ tracking of the reactive intermediates and final active species during the OER in an alkaline pH lacks a sequential study.
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One-pot spatial engineering of multi-enzymes in metal–organic frameworks for enhanced cascade activity

J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper
Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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Dual solar-driven hydrogen evolution and alcohol oxidation with CdS quantum dot-sensitized photocatalysts prepared by the SILAR methodology

J. Mater. Chem. A, 2024, 12,30885-30891
DOI: 10.1039/D4TA03559C, Paper
Vasilis Nikolaou, Deborah Romito, Clément Maheu, Jonathan Hamon, Eric Gautron, Florian Massuyeau, Pierre-Emmanuel Petit, Stéphane Jobic, Fabrice Odobel
The first use of the successive ionic layer adsorption and reaction (SILAR) method to grow CdS quantum dots on TiO2 nanoparticles, achieving efficient photocatalytic alcohol oxidation and H2 evolution without catalysts or sacrificial donors.
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Achieving dynamic stability of single-crystal low-Co Ni-rich cathode material for high performance lithium batteries

J. Mater. Chem. A, 2024, 12,30831-30841
DOI: 10.1039/D4TA04698F, Paper
Adil Saleem, Leon L. Shaw, Mehwish Khalid Butt, Javed Rehman, Arshad Hussain, Zawar Hussain, Rashid Iqbal, Muhammad Kashif Majeed
The demand for high-energy-density lithium-ion batteries (LIBs) has driven intensive research into cathode materials that exhibit both superior performance and stability over multiple charge–discharge cycles.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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Interfacial charge transfer modulation in laser-synthesized catalysts for efficient oxygen evolution

J. Mater. Chem. A, 2024, 12,30269-30278
DOI: 10.1039/D4TA06794K, Paper
Dong Hyeon Lee, Rahul Kerkar, Deepak Arumugam, Jayaraman Theerthagiri, Shankar Ramasamy, Soorathep Kheawhom, Myong Yong Choi
This study introduces a NiFe LDH-based catalyst via pulsed laser irradiation in liquids and microwave methods, achieving superior oxygen evolution performance. In situ electrode casting optimizes the catalyst for water-splitting applications.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics

J. Mater. Chem. A, 2024, 12,30872-30884
DOI: 10.1039/D4TA05266H, Paper
Haijiao Lin, Hui Wang, Yongguang Yang, Yuxuan Zhang, Ling Li, Youwei Zhao, Wenming Zhang
Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics.
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Room-temperature thermochemical water splitting: efficient mechanocatalytic hydrogen production

J. Mater. Chem. A, 2024, 12,30906-30918
DOI: 10.1039/D4TA04650A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Takuya Yamamoto, Sho Ashida, Nanami Inubuse, Shintaro Shimizu, Yui Miura, Tomoya Mizutani, Ken-ichi Saitow
We report the accidental discovery and subsequent investigation of room-temperature thermochemical water splitting in a ball mill. High-purity H2 (>99%) was produced using water and/or seawater feedstocks in a compact (∼50 cm) low-power reactor.
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Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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Oxygen-defective ruthenium oxide as an efficient and durable electrocatalyst for acidic oxygen evolution reaction

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06592A, Paper
Jingwei Wang, Lejuan Cai, Zhipeng Yu, Hao Tan, Xinyi Xiang, Kaiyang Xu, Yang Chao, Sitaramanjaneya Mouli Thalluri, Fei Lin, Haoliang Huang, Chenyue Zhang, Yang Zhao, Wenlong Wang, Lifeng Liu
Proton exchange membrane water electrolysis (PEMWE) is considered a promising technology for green hydrogen production in combination with renewable energy. However, the high cost and particularly the scarcity of iridium...
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Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article
Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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Efficient hydrogen isotope separation utilizing photocatalytic capability

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA07355J, Paper
Linzhen Wu, Sifan Zeng, Weiwei Wang, Shengtai Zhang, Hongbo Li, Xiaosong Zhou
An N–O–C3N4 catalyst for catalytic hydrogen isotope separation.
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Ternary NiFeCo-Glycerolate Catalysts: Rational Design for Improved Oxygen Evolution Reaction Efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06455K, Paper
Irlan Santos Lima, Josué M. Gonçalves, Lúcio Angnes
Catalysts capable of overcoming the bottleneck of water splitting, known as the oxygen evolution reaction (OER), are indispensable to the expansion of renewable energy systems. Thus, we report the synthesis...
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Brief Tales About Love And Relationships & Romantic

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Deal Making Software program for Capital raising and Private Collateral Firms

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Freebet 10 ZŁ za instalację nowej programów FUKSIARZa

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What to anticipate in a Plank Portal Program Comparison

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Articles What it could be like as being a foreign female in China and tiawan Humorous approaches to express like The profiles are all genuine with real Chinese photos and never any of those retouched https://top10chinesedatingsites.net/jiayuan-review/ photos. Many Chinese singles here are also fluent in their English speaking and writing abilities which makes it convenient […]




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Selecting the Best Digital Data Review Platform

There are plenty of conditions in which external functions will need to assessment a company’s data. If it’s due diligence partners, legal advice or auditors, the management team must be prepared to share the right info with these external stakeholders without reducing confidentially. Look for a VDR that offers page-level tracking to see that has […]




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Budget 2024: Archaeological Survey gets ₹140.38-crore capital budget allocation

The allocation towards revenue expenditure unchanged at around ₹1,000 crore