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Industrial, jewellery parks coming up in Machilipatnam, says Minister
Kollu Ravindra appeals to youngsters to grab the opportunities coming their way to set up various industrial units in the district
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Govt. is focused on creating conducive environment for industrial growth in Andhra Pradesh, says Finance Minister Keshav
A sum of ₹3,127 crore has been allocated to the sector in the 2024-25 Budget, he says, adding that the government has been able to rekindle interest among investors to make Andhra Pradesh their investment destination of choice
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Awareness programme on SC and ST (Prevention of Atrocities) Act organised in Srikakulam district
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Child mauled to death by stray dogs in A.P.’s NTR district
Vijayawada Parliament Member, Kesineni Sivanath, SCPCR Chairman Kesali Appa Rao expressed concern over the death of the boy, directs VMC, Panchayat Raj officials to take steps to prevent dog menace
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Kurnool district students excel in belt grading competitions
Out of the total 28 participating students, 14 children participated in Yellow category, 13 in Yellow-1 category and one child in Green-1 category
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Reliance Industries to invest ₹65,000 crore in A.P. to set up compressed biogas projects
The project will result in the creation of 2.50 lakh jobs, and earn an estimated ₹57,650 crore in taxes and duties for Andhra Pradesh over a period of 25 years, according to the Memorandum of Understanding signed on Tuesday
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A strike, and Tamil Nadu’s challenge
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Maharashtra elections 2024: Six in 10 Maharashtrians relate more to the national identity than the regional
Two in 10 believe that they are Maharashtrian first, Indian later. A little over one-sixth of the respondents favoured both identities equally.
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The maximum principle [electronic resource] / Patrizia Pucci, James Serrin
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Number theory [electronic resource] : an introduction via the distribution of primes / Benjamin Fine, Gerhard Rosenberger
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Riemannian geometry and geometric analysis [electronic resource] / Jurgen Jost
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Positivity [electronic resource] / Karim Boulabiar, Gerard Buskes, Abdelmajid Triki, editors
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Number theory and combinatorics [electronic resource] : a collection in honor of the mathematics of Ronald Graham / edited by Bruce M. Landman, Florian Luca, Melvyn B. Nathanson, Jaroslav Nešetřil, and Aaron Robertson.
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Two electric buggies damaged in fire at Pilikula
Before the firemen could reach the spot, the personnel put off the fire by pouring water. The two buggies were completely damaged
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Kannada Ratha gets rousing welcome in Udupi district
Ratha with Kannada Jyothi has been touring Karnataka ahead of the Mandya sahitya sammelana
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Traffic restrictions in place till 10 a.m. of November 10 for Mangalore Marathon
The Mangalore Marathon comprises of 42K, 32K, 21K, 10K, 10K students run, 5K, 5K student run and 2K Gammat run between Mangala Stadium and Tannirbhavi second beach
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Palakkad division commissions first of 30 electric lifting barriers at level-crossing gates
LC gate at Jokatte and LC gates between Mangaluru Central and Kannur to be upgraded to EOLBs in a phased manner
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Left alliance triumphs in University of Hyderabad students’ union election
The Dalit Students Union, Ambedkar Students’ Union, Student Federation of India and Bahujan Students’ Front emerged victorious with the National Students’ Union of India winning a consolatory Sports Secretary’s post
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Trump’s triumph: What it means for study-abroad aspirants from India
While Trump has been virulent against illegal immigration, how he deals with legal immigration will be more important for study abroad aspirations of Indians.
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Mohenjo Daro: Tries the audience’s patience
The very straight, simple and oft-repeated tale of foster parents, mistaken identity, good vs evil is just another fantasy, a mishmash of many such larger than life epics.
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Waarrior Savitri: Boring skin and sex show
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'Hannah Gadsby: Douglas' review: After 'Nanette', the extraordinary mind of Gadsby strikes again
The Australian’s charisma lies in her ability to be excruciatingly vulnerable to an audience with a swagger that’s both self-assured and relatable
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Shriram Properties to quadruple profit, triple revenue by FY27
“Shriram Properties will embrace the new era under the banner SPLNxT to reposition the brand; enhance focus on mid-market and mid-premium segments, and accelerate growth”
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Tribal art, a focal point
‘Thinking Hands’, an exhibition of craft collectibles in Bengaluru, reinforces the growing interest in contemporary Indian tribal art among serious collectors
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Photocatalytic hydrotrichloromethylation of unactivated alkenes with chloroform
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01496K, Research Article
DOI: 10.1039/D4QO01496K, Research Article
Dawei Gong, Caiyu Gao, Qixuan Li, Yufei Li, Lina Zhao, Degong Kong
Trichloromethyl compounds are essential constituents in synthetic and medicinal chemistry.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
Trichloromethyl compounds are essential constituents in synthetic and medicinal chemistry.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01698J, Research Article
DOI: 10.1039/D4QO01698J, Research Article
Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen Xu
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01841A, Research Article
DOI: 10.1039/D4QO01841A, Research Article
Xunhua Wang, Jianhua Wang, Xiaoxun Li
A gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.
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The content of this RSS Feed (c) The Royal Society of Chemistry
A gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes
Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01848F, Research Article
DOI: 10.1039/D4QO01848F, Research Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tobias B. Tischer, Zulema Fernandez, Lorenz Borsdorf, Constantin Daniliuc, Shigehiro Yamaguchi, Soichiro Ogi, Gustavo Fernandez
Supramolecular polymers are often investigated for highly symmetric and planar molecules, such as typically explored BF2-substituted BODIPY dyes . However, it is surprising that the possibility of desymmetrizing the sp3...
The content of this RSS Feed (c) The Royal Society of Chemistry
Supramolecular polymers are often investigated for highly symmetric and planar molecules, such as typically explored BF2-substituted BODIPY dyes . However, it is surprising that the possibility of desymmetrizing the sp3...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction
Org. Chem. Front., 2024, 11,6426-6436
DOI: 10.1039/D4QO01551G, Research Article
DOI: 10.1039/D4QO01551G, Research Article
Mao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long Zhao
A cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.
The content of this RSS Feed (c) The Royal Society of Chemistry
A cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Asymmetric synthesis of (aza)flavanones by the evolution of CarOx ligands
Org. Chem. Front., 2024, 11,6444-6449
DOI: 10.1039/D4QO01345J, Research Article
DOI: 10.1039/D4QO01345J, Research Article
Juan Yang, Wenlong Kong, Mingxin Chang, Jixing Lai, Shengkun Li
Amino-pyridine-oxazoline (NHPyOx) is conceived as an unprecedented model via the core-emulating optimization of CarOx ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry
Amino-pyridine-oxazoline (NHPyOx) is conceived as an unprecedented model via the core-emulating optimization of CarOx ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives
Org. Chem. Front., 2024, 11,6319-6326
DOI: 10.1039/D4QO01368A, Research Article
DOI: 10.1039/D4QO01368A, Research Article
Yu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming Wang
A variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.
The content of this RSS Feed (c) The Royal Society of Chemistry
A variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes
Org. Chem. Front., 2024, 11,6470-6476
DOI: 10.1039/D4QO01532K, Research Article
DOI: 10.1039/D4QO01532K, Research Article
Xiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu Li
A novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.
The content of this RSS Feed (c) The Royal Society of Chemistry
A novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis
Org. Chem. Front., 2024, 11,6534-6557
DOI: 10.1039/D4QO01686F, Review Article
DOI: 10.1039/D4QO01686F, Review Article
Jinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun Xie
This review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.
The content of this RSS Feed (c) The Royal Society of Chemistry
This review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.
The content of this RSS Feed (c) The Royal Society of Chemistry
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A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01388C, Research Article
DOI: 10.1039/D4QO01388C, Research Article
Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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The content of this RSS Feed (c) The Royal Society of Chemistry
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides
Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01844C, Research Article
DOI: 10.1039/D4QO01844C, Research Article
Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
The content of this RSS Feed (c) The Royal Society of Chemistry
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation
Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01963F, Highlight
DOI: 10.1039/D4QO01963F, Highlight
Yingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie Wu
As the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...
The content of this RSS Feed (c) The Royal Society of Chemistry
As the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01771D, Research Article
DOI: 10.1039/D4QO01771D, Research Article
Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
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The content of this RSS Feed (c) The Royal Society of Chemistry
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Integrating electrocatalysis with biocatalysis for asymmetric synthesis
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01899K, Highlight
DOI: 10.1039/D4QO01899K, Highlight
Yuqi Lin, Jiage Yu, Ke-Yin Ye
This highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.
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The content of this RSS Feed (c) The Royal Society of Chemistry
This highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy
The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said
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Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district
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Telangana set to unveil new industrial sectoral policies
Electric Mobility and Storage, Electronics, Life Sciences, Defence and Aerospace sectors to get new growth guiding documents as some existing policies have become outdated and those in other States are superior, senior official
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District Consumer Commission dismisses complaint against Google Pay due to lack of evidence
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CM Revanth Reddy announces resolve to complete pending projects of Palamuru district
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Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat
The new order comes into effect from November 11 until further notice, said the commissioner