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Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
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Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial

Dalton Trans., 2020, 49,5722-5729
DOI: 10.1039/D0DT00778A, Paper
Wan Wu, Tiantian Yao, Ye Xiang, Hao Zou, Yi Zhou
Nano-scale MOF composite materials prepared by combining inorganic semiconductors with controllable pore structures and functional active sites for the effective removal of organic dyes will exhibit more excellent adsorption activity.
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Photo-reduction enables catalyst regeneration in Fenton reaction on an Fe2O3-decorated TiO2 nanotube-based photocatalyst

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00670J, Paper
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
Active Fe2+ sites of TNT(Pd)/Fe2O3 with a unique electronic structure for the Fenton reaction can be self-generated.
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A novel self-assembled-derived 1D MnO2@Co3O4 composite as a high-performance Li-ion storage anode material

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00980F, Paper
Zongtang Li, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuanhao Gao, Helin Niu
Manganese dioxide (MnO2) is a high-performance anodic material and applied widely in lithium-ion batteries (LIBs).
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Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01177K, Paper
To Van Nguyen, Le The Son, Vu Van Thuy, Vu Dinh Thao, Masahito Hatsukano, Koichi Higashimine, Shinya Maenosono, Sang-Eun Chun, Tran Viet Thu
We report the synthesis of manganese-doped nickel cobalt oxide (Mn-doped NiCo2O4) nanoparticles (NPs) by an efficient hydrothermal and subsequent calcination route.
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Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper
Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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Mitsubishi to work on CO2 to methanol




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Integration of aerobic granulation and UV/H2O2 processes in a continuous flow system for the degradation of sulfolane in contaminated water

Environ. Sci.: Water Res. Technol., 2020, Advance Article
DOI: 10.1039/C9EW01048C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Faizan Khan, Linlong Yu, Jordan Hollman, Joo Hwa Tay, Gopal Achari
Aerobic granulation and UV/H2O2 in a continuous flow-through reactor can effectively degrade emerging contaminates, such as sulfolane.
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Nanophotonics, Nanooptics, Nanobiotechnology, and Their Applications: Selected Proceedings of the 6th International Conference Nanotechnology and Nanomaterials (NANO2018), August 27-30, 2018, Kyiv, Ukraine.

Online Resource




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Minimization of Pt-electrocatalyst deactivation in CO2 reduction using a polymer electrolyte cell

React. Chem. Eng., 2020, Advance Article
DOI: 10.1039/D0RE00083C, Paper
Shofu Matsuda, Shigehisa Tamura, Shota Yamanaka, Yuuki Niitsuma, Yoshitsugu Sone, Minoru Umeda
An effective poisoning elimination method for CH4 production from CO2 reduction using a Pt/C electrocatalyst in a polymer electrolyte cell has been established by controlling the Pt–CO/Pt–H ratio and re-arranging the surface adsorption.
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Optimization of the direct synthesis of dimethyl ether from CO2 rich synthesis gas: closing the loop between experimental investigations and model-based reactor design

React. Chem. Eng., 2020, 5,949-960
DOI: 10.1039/D0RE00041H, Paper
Open Access
Nirvana Delgado Otalvaro, Markus Kaiser, Karla Herrera Delgado, Stefan Wild, Jörg Sauer, Hannsjörg Freund
Kinetic modeling, model-based optimization and experimental validation for the direct DME synthesis.
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Nano-TiO2 promoted CaO-based high-temperature CO2 sorbent: Role of crystal level properties on efficiency of the CO2 sorption

React. Chem. Eng., 2020, Accepted Manuscript
DOI: 10.1039/D0RE00124D, Paper
Sanat Chandra Maiti, Chinmay Ghoroi
This work investigates the multi-cycle CO2 sorption, and the kinetics of the carbonation reaction of nano-TiO2 promoted CaO synthesized from commercially available micron size CaCO3. The morphology of the CaCO3...
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Effect of ceria morphology on the performance of MnOx/CeO2 catalysts in catalytic combustion of N,N-dimethylformamide

Catal. Sci. Technol., 2020, 10,2473-2483
DOI: 10.1039/C9CY02384D, Paper
Fengying Huang, Dongsheng Ye, Xiaohan Guo, Wangcheng Zhan, Yun Guo, Li Wang, Yunsong Wang, Yanglong Guo
MnOx/CeO2 catalysts were prepared by a deposition–precipitation method, through loading MnOx into ceria supports with different morphologies (nanorods (NRs), nanocubes (NCs) and nano-octahedrons (NOs)).
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Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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Hydroxyl groups attached to Co2+ on the surface of Co3O4: a promising structure for propane catalytic oxidation

Catal. Sci. Technol., 2020, 10,2573-2582
DOI: 10.1039/D0CY00265H, Paper
Kun Chen, Wenzhi Li, Zean Zhou, Qifu Huang, Yang Liu, Qiuyan Duan
Co3O4 catalysts with three specific morphologies (nanocubes, nanosheets, and nanooctahedra) were prepared using simple preparation methods and tested for catalytic combustion of propane under the same reaction conditions.
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The direct decomposition of NO into N2 and O2 over copper doped Ba3Y4O9

Catal. Sci. Technol., 2020, 10,2513-2522
DOI: 10.1039/D0CY00194E, Paper
Siman Fang, Atsushi Takagaki, Motonori Watanabe, Tatsumi Ishihara
Both NO decomposition activity and long-term stability increase significantly after the introduction of Cu into Ba3Y4O9.
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Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
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Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Origin of CO2 as the main carbon source in syngas-to-methanol process over Cu: theoretical evidence from a combined DFT and microkinetic modeling study

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00602E, Paper
Dongyang Xu, Panpan Wu, Bo Yang
A theoretical study combining DFT and microkinetic modeling provides evidence that CO2 is the main carbon source in methanol synthesis from syngas (CO, CO2 and H2) over Cu.
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Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Ru nanoparticles supported on amorphous ZrO2 for CO2 methanation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00233J, Paper
Hironori Nagase, Rei Naito, Shohei Tada, Ryuji Kikuchi, Kakeru Fujiwara, Masahiko Nishijima, Tetsuo Honma
The influence of support materials and preparation methods on CO2 methanation activity was investigated using Ru nanoparticles supported on amorphous ZrO2 (am-ZrO2), crystalline ZrO2 (cr-ZrO2), and SiO2. Among them, Ru/am-ZrO2...
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Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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Hierarchical Z-scheme 1D/2D architecture with TiO2 nanowires decorated by MnO2 nanosheets for efficient adsorption and full spectrum photocatalytic degradation of organic pollutants

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00419G, Paper
Jiejing Zhang, Yajie Hu, Hong Zheng, Pengyi Zhang
Constructing composite photocatalysts with efficient photocatalytic activity, wide optical response range and excellent stability has great significance for the removal of organic pollutants in water. Herein, we report a novel...
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A biodegradable CO2-based polymeric antitumor nanodrug via a one-pot surfactant- and solvent-free miniemulsion preparation

Biomater. Sci., 2020, 8,2234-2244
DOI: 10.1039/C9BM01931F, Paper
Qiaojie Luo, Xiaojun Li, Ying Wang, Jianfang He, Qiao Zhang, Pengfei Ge, Xia Cai, Qiang Sun, Weipu Zhu, Zhiquan Shen, Xiaodong Li
A biodegradable CO2-based polymeric nanodrug is obtained via a surfactant- and solvent-free miniemulsion preparation, which can be concentrated at tumor site by EPR and releases the encapsulated drug through pH responsiveness.
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Wrinkle-induced highly conductive channels in graphene on SiO2/Si substrate

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR01406K, Paper
Ruisong Ma, Jiajun Ma, Jiahao Yan, Liangmei Wu, Wei Guo, Shuai Wang, Qing Huan, Lihong Bao, Sokrates T Pantelides, Hong-Jun Gao
Graphene wrinkle is a quasi-one-dimensional structure and can alter the intrinsic physical and chemical activity, modify the band structure and introduce transport anisotropy in graphene thin films. However, their quasi-one-dimensional...
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Boosting the photocatalytic CO2 reduction of metal–organic frameworks by encapsulating carbon dots

Nanoscale, 2020, 12,9533-9540
DOI: 10.1039/D0NR01696A, Paper
Shumin Li, Kang Ji, Meng Zhang, Cangshuang He, Jin Wang, Zhengquan Li
Small carbon dots as cocatalysts were loaded in MOF particles for CO2 reduction and their location effect was explored.
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A new perspective of lanthanide metal–organic frameworks: tailoring Dy-BTC nanospheres for rechargeable Li–O2 batteries

Nanoscale, 2020, 12,9524-9532
DOI: 10.1039/D0NR00866D, Paper
Dan Liu, Xinmin Zhang, Yan-Jie Wang, Shuyan Song, Lifeng Cui, Hongbo Fan, Xiaochang Qiao, Baizeng Fang
Nanoscaled lanthanide metal–organic frameworks (Ln-MOFs), Dy-BTC nanospheres, are explored as an O2 electrode, which demonstrate an ultrahigh discharge capacity and long cycling life.
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Mild generation of surface oxygen vacancy on CeO2 for improved CO2 photoreduction activity.

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR00717J, Paper
Min Wang, Meng Shen, Xixiong Jin, Jianjian Tian, Yajun Zhou, Yiran Shao, Lingxia Zhang, Yongsheng Li, Jianlin Shi
The vacancy defects of semiconductor photocatalysts play a key role in enhancing their photocatalytic CO2 reduction activity. In this work, CeO2 was chosen as a model catalyst and oxygen vacancy...
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Synthesis of monodisperse water-stable surface Pb-rich CsPbCl3 nanocrystals for efficient photocatalytic CO2 reduction

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02917C, Communication
Jingrun Zhu, Yihua Zhu, Jianfei Huang, Lu Hou, Jianhua Shen, Chunzhong Li
Surface Pb-rich lead halide perovskite nanocrystals (NCs) with high stability and monodispersity in water have been synthesized using a general and convenient liquid-solid-interpenetration (LSI) method. In this process, water molecules...
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Characterization of HfO₂ films for flash memory applications




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Effect of sno2 roughness and cds thickness on the performance of cds/cdte solar cells




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An investigation of tio2-znfe2o4 nanocomposites for visible light photocatalysis




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Self-potential anomalies and CO2 flux on active volcanoes




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Application and modeling of TiO2-supported gold nanoparticles for CO preferential oxidation in excess hydrogen




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Thermochemical treatment of TiO2 nanoparticles for photocatalytic applications




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Effects of Zn doping and high energy ball milling on the photocatalytic properties of TiO₂




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Laser remote sensing of trace chemical species using 10.6 μm CO₂ laser enhanced breakdown spectroscopy and differential absorption lidar




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Enhanced co2 storage in confined geologic formations




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Effect of catalyst preparation conditions on the performance of eggshell cobalt/sio2 catalysts for fischer-tropsch synthesis




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Geochemical modeling of co2 sequestration in dolomitic limestone aquifers




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Investigation of the optimal dissolved co2 concentration and ph combination for the growth of nitrifying bacteria