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Size-dependent electrocatalytic hydrogen evolution activity of arrays of edge-like defects in MoS2 crystals patterned by focused ion beam

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA05885B, Paper
Cláudia de Lourenço, Ana Beatriz Sorana de Araujo, Leonardo Hideki Hasimoto, Isaque A.A. Feitosa, Matheus Felipe Fagundes das Neves, Jefferson Bettini, Tarcísio Micheli Perfecto, Tulio C. R. Rocha, Thiago J.A. Mori, Edson R. Leite, Murilo Santhiago
Introducing surface defects on molybdenum disulfide (MoS2) crystals plays a crucial role in enhancing the electrocatalytic activity toward the hydrogen evolution reaction (HER). Despite the remarkable progress in this area,...
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Electropolymerized Organic N/P Bipolar Cathode Toward High Energy and High Power Density Sodium Dual-Ion Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07077A, Paper
Weisheng Zhang, Chen-Xing Zhang, Xianhe Chen, H.J. Yin, Wenli Hu, Shilin Mei, Chang-Jiang Yao
Sodium dual ion batteries (SDIBs) have received considerable attention recently for large-scale energy storage systems due to their low cost and inherent safety. Nevertheless, SDIBs remain a subject of investigation,...
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Bifunctional conjugated polymer photocatalysts for visible light water oxidation and CO2 reduction: function- and site-selective hybridisation of Ru(II) complex catalysts

J. Mater. Chem. A, 2024, 12,30279-30288
DOI: 10.1039/D4TA04014G, Paper
Kotaro Ishihara, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Shunsuke Nozawa, Akinori Saeki, Ryu Abe
Function-/site-selective hybridisation of two specific Ru(II) complex catalysts on donor–acceptor conjugated polymers enables bifunctional visible-light water oxidation and CO2 reduction.
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Revealing a synergistic orbital coupling adsorption mechanism of the oxygen reduction reaction in dual-atom catalysts

J. Mater. Chem. A, 2024, 12,30676-30684
DOI: 10.1039/D4TA05099A, Paper
Yangfan Liu, Yejun Li, Xinghan Liu, Jinming Li, Gufei Zhang, Jun Gong, Yanbin Jiang, Zhou Li
A synergistic adsorption mechanism of the oxygen evolution reaction for the dual atom catalysts (DACs) was proposed, which dominates the adsorption strength of intermediate species, potential determining step, and catalytic activity of DACs.
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Effects of hydrothermal etching and conversion on photocatalytic hydrogen evolution and overall water splitting with nanoparticulate and mesoporous TiO2 and SrTiO3/TiO2 composites

J. Mater. Chem. A, 2024, 12,30768-30782
DOI: 10.1039/D4TA03416C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lion Schumacher, Jana Timm, Roland Marschall
Hydrothermal treatment of mesoporous photocatalysts in diluted NaOH solution or H2O might be a simple and promising strategy to improve photocatalytic activities in general, as we show for TiO2 and SrTiO3/TiO2 composites.
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Enhanced electrocatalytic overall alkaline water splitting induced by interfacial electron coupling of Mn3O4 nano-cube@CeO2/γ-FeOOH nanosheet hetero-structure

J. Mater. Chem. A, 2024, 12,30783-30797
DOI: 10.1039/D4TA05336B, Paper
Debasish Ghosh, Dimple K. Bora, Asit Baran Panda
Mn3O4@CeO2/γ-FeOOH hetero-structure showed interfacial electron coupling induced superior bifunctional electrocatalytic activity suitable for AEM electrolyser.
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Catalytic kinetic growth of a half-metallic hexagonal boron nitride-graphene lateral heterostructure using transition metal single-atom catalysts on Rh(111)

J. Mater. Chem. A, 2024, 12,30498-30507
DOI: 10.1039/D4TA05741D, Paper
Yandi Zhu, Weihu Li, Xiaoyan Ren, Lili Zhang, Xingju Zhao, Shunfang Li
Transition metal single-atom catalysts (TM = Mn, Zr, Nb, Mo, Hf, Ta, and W) promote growth of a h-BN-G heterostructure on C-dimer-unpreferred Rh(111).
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A soft molecular single-source precursor approach to synthesize a nanostructured Co9S8 (pre)catalyst for efficient water oxidation and biomass valorization

J. Mater. Chem. A, 2024, 12,30522-30533
DOI: 10.1039/D4TA05436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Basundhara Dasgupta, Suptish Ghosh, Carsten Walter, Markus S. Budde, Georg J. Marquardt, Han-Hsu Chen, Markus G. M. Breithaupt, Tolga Yilmaz, Christoph Garmatter, Tamanna Ahamad, Ingo Zebger, Matthias Driess, Prashanth W. Menezes
A nanocrystalline Co9S8 (pre)catalyst derived from a novel {CoIIS4} complex is reported for the oxygen evolution reaction (OER) and selective biomass valorization. During OER, Co9S8 reconstructs completely into a CoOOH active phase via S-leaching.
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Machine learning for deconstructing contributions of atomic characterizations to achieve hybridization-determined electron transfer in a perovskite catalyst

J. Mater. Chem. A, 2024, 12,30722-30728
DOI: 10.1039/D4TA05018E, Paper
Jun Zhu, Mengdan Song, Qiling Qian, Yang Yue, Guangren Qian, Jia Zhang
Machine learning deconstructed the atomic contribution of a perovskite to catalytic toluene decomposition and found that wider hybridization resulted in smaller impedance, faster electron transfer speed, and enhanced catalytic activity.
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Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped carbon nanotubes for stable Zn–air batteries with ultra-high power densities

J. Mater. Chem. A, 2024, 12,30798-30809
DOI: 10.1039/D4TA04194A, Paper
Manigandan Ramadoss, Hesheng Yu, Anand Rajkamal, Gun Jin Yun, Ziheng Zhang, Chengtao Yang, Fei Ma, Yu Wu, Chen Daiqian, Yuanfu Chen
Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped CNT deliver comparable OER behavior to RuO2, better ORR performance than Pt/C, and better ZAB performance than Pt/C–RuO2, due to the nanoarchitecture and abundant active sites.
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Optimization of the electron transfer kinetics between a photoanode and biocathode for enhanced carbon-neutral pollutant removal in photocatalytic fuel cells

J. Mater. Chem. A, 2024, 12,30371-30379
DOI: 10.1039/D4TA05290K, Paper
Xiaofei Gu, Jianyu Han, Zhi Wang, Yixin Hong, Tianyi Huang, Yafeng Wu, Yuanjian Zhang, Songqin Liu
A PFC system with collaborative dynamics between the photoanode and biocathode is constructed for using solar energy to efficiently convert refractory organic pollutants into green fuel and generate electricity.
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Synthesis of a Cu@ZnO1−x/Al2O3 catalyst with high-density ZnO1−x–Cu interfacial sites for enhanced CO2 hydrogenation to methanol

J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper
Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
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A black zirconia cathode coating layer enabling facile charge diffusion and surface lattice stabilization for lithium-ion batteries

J. Mater. Chem. A, 2024, 12,30667-30675
DOI: 10.1039/D4TA05179C, Paper
Yoo Jung Choi, Sungbin Jang, Hongjun Chang, Youjin Kim, Suji Kim, Ga Yoon Kim, Juho Lee, Janghyuk Moon, Jinsoo Kim, Won-Hee Ryu
Black ZrO2−x is coated onto a Ni-rich cathode via solvent-free shearing, enhancing charge transfer, reducing gas evolution, and preventing cracking. It lowers Li-ion transfer barriers and mitigates oxygen release through strong Zr–O hybridization.
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Sulfur-doped g-C3N4/V2C MXene Schottky junctions for superior photocatalytic H2 evolution

J. Mater. Chem. A, 2024, 12,30429-30441
DOI: 10.1039/D4TA05929H, Paper
Haitao Wang, Jipeng Fan, Jing Zou, Yujie Zheng, Dingsheng Wang, Jizhou Jiang
An advanced sulfur-doped g-C3N4/V2C MXene (SCN/V2C) Schottky junction HER photocatalyst was prepared via vacuum ball milling and subsequent annealing.
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Electrochemical synthesis of wormcast-like Pd-based polycrystalline high entropy aggregates for methanol water co-electrocatalysis

J. Mater. Chem. A, 2024, 12,30757-30767
DOI: 10.1039/D4TA06304J, Paper
Yaxing Liu, Wenhao Ding, Jiaxin Liu, Guizhe Zhao, Weiyin Li, Yaqing Liu
A wormcast-like nanostructure of PdFeCoNiCu-pHENs with enriched grain boundary defects was synthesized via electrodeposition. This work opens new possibilities for designing advanced nanomaterials aimed at efficient electrochemical energy conversion.
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Tracking the active phase and reaction pathway of the OER mediated by an MnMoO4 microrod electro(pre)-catalyst

J. Mater. Chem. A, 2024, 12,30810-30820
DOI: 10.1039/D4TA05985A, Paper
Anubha Rajput, Ankita Kumari, Hirak Kumar Basak, Dibyajyoti Ghosh, Biswarup Chakraborty
MnMoO4 is a barely explored material for the electrocatalytic oxygen evolution reaction (OER) and in situ tracking of the reactive intermediates and final active species during the OER in an alkaline pH lacks a sequential study.
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Dual solar-driven hydrogen evolution and alcohol oxidation with CdS quantum dot-sensitized photocatalysts prepared by the SILAR methodology

J. Mater. Chem. A, 2024, 12,30885-30891
DOI: 10.1039/D4TA03559C, Paper
Vasilis Nikolaou, Deborah Romito, Clément Maheu, Jonathan Hamon, Eric Gautron, Florian Massuyeau, Pierre-Emmanuel Petit, Stéphane Jobic, Fabrice Odobel
The first use of the successive ionic layer adsorption and reaction (SILAR) method to grow CdS quantum dots on TiO2 nanoparticles, achieving efficient photocatalytic alcohol oxidation and H2 evolution without catalysts or sacrificial donors.
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Achieving dynamic stability of single-crystal low-Co Ni-rich cathode material for high performance lithium batteries

J. Mater. Chem. A, 2024, 12,30831-30841
DOI: 10.1039/D4TA04698F, Paper
Adil Saleem, Leon L. Shaw, Mehwish Khalid Butt, Javed Rehman, Arshad Hussain, Zawar Hussain, Rashid Iqbal, Muhammad Kashif Majeed
The demand for high-energy-density lithium-ion batteries (LIBs) has driven intensive research into cathode materials that exhibit both superior performance and stability over multiple charge–discharge cycles.
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Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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Interfacial charge transfer modulation in laser-synthesized catalysts for efficient oxygen evolution

J. Mater. Chem. A, 2024, 12,30269-30278
DOI: 10.1039/D4TA06794K, Paper
Dong Hyeon Lee, Rahul Kerkar, Deepak Arumugam, Jayaraman Theerthagiri, Shankar Ramasamy, Soorathep Kheawhom, Myong Yong Choi
This study introduces a NiFe LDH-based catalyst via pulsed laser irradiation in liquids and microwave methods, achieving superior oxygen evolution performance. In situ electrode casting optimizes the catalyst for water-splitting applications.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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Room-temperature thermochemical water splitting: efficient mechanocatalytic hydrogen production

J. Mater. Chem. A, 2024, 12,30906-30918
DOI: 10.1039/D4TA04650A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Takuya Yamamoto, Sho Ashida, Nanami Inubuse, Shintaro Shimizu, Yui Miura, Tomoya Mizutani, Ken-ichi Saitow
We report the accidental discovery and subsequent investigation of room-temperature thermochemical water splitting in a ball mill. High-purity H2 (>99%) was produced using water and/or seawater feedstocks in a compact (∼50 cm) low-power reactor.
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Development and application of Few-shot learning methods in materials science under data scarcity

J. Mater. Chem. A, 2024, 12,30249-30268
DOI: 10.1039/D4TA06452F, Review Article
Yongxing Chen, Peng Long, Bin Liu, Yi Wang, Junlong Wang, Tian Ma, Huilin Wei, Yue Kang, Haining Ji
Machine learning, as a significant branch of artificial intelligence, shortens the cycle of material discovery and synthesis by exploring the characteristics of data.
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Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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Oxygen-defective ruthenium oxide as an efficient and durable electrocatalyst for acidic oxygen evolution reaction

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06592A, Paper
Jingwei Wang, Lejuan Cai, Zhipeng Yu, Hao Tan, Xinyi Xiang, Kaiyang Xu, Yang Chao, Sitaramanjaneya Mouli Thalluri, Fei Lin, Haoliang Huang, Chenyue Zhang, Yang Zhao, Wenlong Wang, Lifeng Liu
Proton exchange membrane water electrolysis (PEMWE) is considered a promising technology for green hydrogen production in combination with renewable energy. However, the high cost and particularly the scarcity of iridium...
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Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article
Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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Enhanced oxygen exchange kinetics and long-term stability of Ruddlesden-Popper phase Pr4Ni3O10+δ cathode for solid oxide fuel cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01845A, Paper
Saim Saher, Affaq Qamar, Chou Yong Tan, Singh Ramesh, Walied Alfraidi
This research explores the intricacies of oxygen exchange kinetics in Pr4Ni3O10+δ (PNO), aiming to assess its potential as a viable cathode material for solid oxide fuel cell applications. Utilizing a...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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Machine learning aided design of high performance copper-based sulfide photocathodes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06128D, Paper
Yuxi Cao, Kaijie Shen, Yuanfei Li, Fumei Lan, Zeyu Guo, Kelu Zhang, Kang Wang, Feng Jiang
With the help of machine learning algorithms, we developed software that can predict the performance of copper-based sulfide photocathodes and this system shows excellent accuracy of up to 96%.
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Efficient hydrogen isotope separation utilizing photocatalytic capability

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA07355J, Paper
Linzhen Wu, Sifan Zeng, Weiwei Wang, Shengtai Zhang, Hongbo Li, Xiaosong Zhou
An N–O–C3N4 catalyst for catalytic hydrogen isotope separation.
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Vertical Macroporous Chitosan Aerogel Adsorbents for Simple and Efficient Enhancement of Atmospheric Water Harvesting and Air Dehumidification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07005D, Paper
Zhiguang Guo, Changhui Fu, Yuxuan He, Anhui Yu, Guangyi Tian, Danyan Zhan, Huimin Zhang
Adsorption-based atmospheric water harvesting (SAWH) has become one of the effective methods to extract water from the air in arid regions due to its high efficiency and low energy consumption....
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Synergetic Effects from a High-Entropy NASICON-type Cathode for Advanced Sodium-Ion Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06950A, Paper
Shouyue Wang, Taiding Xu, Huitao Leng, Shengyu Liang, Wei Zhang, Yuheng Jin, Jingxia Qiu, Sheng Li
Na3V2(PO4)3 (NVP) is recognized as one of the most promising NASICON-type cathodes for sodium-ion storage. Enhancing electronic conductivity and further ensuring long-term structural stability when activating the high-voltage V⁴⁺/V⁵⁺ redox...
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Ternary NiFeCo-Glycerolate Catalysts: Rational Design for Improved Oxygen Evolution Reaction Efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06455K, Paper
Irlan Santos Lima, Josué M. Gonçalves, Lúcio Angnes
Catalysts capable of overcoming the bottleneck of water splitting, known as the oxygen evolution reaction (OER), are indispensable to the expansion of renewable energy systems. Thus, we report the synthesis...
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Bears pivot to another potential location for Chicago stadium

The Bears can't get their effort to muster political support — and taxpayer money — for a new stadium off the ground.




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Matrimony Certificate Process and Via the internet Marriage Firm

Marriage certificate procedure Whether you are looking for a long term relationship or maybe a marriage, it is crucial to know the legal techniques online brides and the way to apply for a marital relationship certificate. This doc will function as your resistant of valid matrimony and will provide you with a number of other […]




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Mother board Meeting Application – How it Can Benefit Your company

Board meeting software helps boards deal with their get togethers online within a secure environment. It makes the process of arranging, building daily activities, taking votes, drafting mins and distributing these documents simple for all stakeholders. It also decreases the amount of period admins invest in these tasks. Choosing the best table management software is […]




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Top20 International Locations To get a International Partner And As to why

Articles Use Communication Tools So why Choose Zoosk For International Dating? The most beneficial Locations To Seek Out Love — And Lust — Depending on Science If you’re looking at ladies for marriage, you better strive single russian women your fortune with deliver order woman sites. In the listing supplied above, you can actually pick […]




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Board Communication and Meeting Solutions

Making decisions is simpler with meetings and board communication. It is vital for every board to maintain transparency, a diversity of opinion and a focus on decision-making. Board members are under pressure to produce outcomes and this requires a constant flow of information between members. Luckily, technology can enhance the way we communicate. With a […]




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On-line Technologies and Games Mainly because an Educational Tool

Online systems and video games more helpful hints often get a bad hiphop from father and mother and educators who make an effort to pull kids away from the screens and encourage them to carry out more educational or much healthier activities. Yet , what if we embraced the technology and allowed children to play […]




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Budget 2024: Archaeological Survey gets ₹140.38-crore capital budget allocation

The allocation towards revenue expenditure unchanged at around ₹1,000 crore 




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Safeena Hussain and Educate Girls continue to transform lives

Her relentless pursuit of this mission garnered her NGO, Educate Girls, the businessline Changemaker Award 2023 for Social Transformation




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Stop food firms from catching them young

It’s not ‘business as usual’ for food companies anymore



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Assam Higher Secondary Education Council(AHSEC) result to be declared tomorrow : Where to check Results

The Assam Higher Secondary Education Council (AHSEC) will be declared the results of the Higher Secondary (HS) examinations on 9 May 2024. Assam state education minister Ranoj Pegu informed on Wednesday, 7 May 2024. Assam Higher Secondary Education Council (AHSEC) will declare HS Exam Results-2024 tomorrow at 9 AM. The official Press Release will be […]

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2-wheeler electrification: challenges and opportunities




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A tale of three developers — will the law catch up?




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Legal complications have slowed the bankruptcy process




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IIM-A fees and the crisis in liberal education




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‘MGNREGS allocation should be no less than ₹1 lakh crore’