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Fluorination of antimonene hexagons

Chem. Commun., 2024, 60,13336-13339
DOI: 10.1039/D4CC03423F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michael Fickert, Rebeca Martinez-Haya, Diego López-Alcalá, Frank Hauke, José J. Baldoví, Andreas Hirsch, Gonzalo Abellán
Fluorination of two-dimensional antimonene hexagons synthesized through colloidal synthesis has been reached using CF4 plasma through a reactive ion etching process.
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Catalytic asymmetric Michael and Nef-type sequential reaction of nitroolefin with azlactone to construct oxazole-fused succinimide

Chem. Commun., 2024, 60,13384-13387
DOI: 10.1039/D4CC04858J, Communication
Rui Weng, Yuqiao Zhou, Yaqin Zhang, Xiaoming Feng, Xiaohua Liu
A series of oxazole-fused succinimides bearing vicinal quaternary carbon centers were synthesized via catalytic asymmetric Michael addition and Nef-type sequential reactions of nitroolefins with azlactones.
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Expedient (3+3)-annulation of carbonyl ylides with azaoxyallyl cations: formal access to oxa-benzo[c]azepin-3-ones

Chem. Commun., 2024, 60,13368-13371
DOI: 10.1039/D4CC04946B, Communication
Kshitiz Verma, Hemanga Bhattacharyya, Sharajit Saha, Tharmalingam Punniyamurthy
Cascade C–C/C–N bond formation of carbonyl ylides with azaoxyallyl cations generated in situ using Rh-catalysis has been accomplished in the presence of a base at room temperature.
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Moringa honey: How Italian bees are helping farmers in sweet enterprise

Moringa honey is among the most popular varieties of floral nectar in the food sector. Farmer and beekeeper N Dhandayuthapani is one of those in the Cauvery delta reaping the benefit of combining apiary with agriculture




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Paneer makhni burger, anyone?

Everything from tofu to mutton ghee roast is fair game now 




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The structural, electronic and thermodynamic properties of the designed p-benzoquinone based dicationic ionic liquids: insight from DFT–GD3 and QTAIM

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00119B, Paper
Hossein Roohi, Sajedeh Habibipour, Khatereh Ghauri
In this work, physicochemical properties of the dicationic ionic liquids [BTAD][A1–8]2 ([BTAD]2+ = [p-C6O2(N3H2)2]2+ and A1–8 = [CH3CO2], [CF3CO2], [N(CN)2], [CF3SO3], [ClO4], [BF4], [NTf2] and [PF6]) were theoretically investigated.
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Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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Self-assembled superstructures derived from suitably substituted phenanthro[9,10-d] imidazole-based Zn(II)/Cd(II) complexes for selective detection of acetone

New J. Chem., 2024, 48,7456-7468
DOI: 10.1039/D4NJ00450G, Paper
Mallayasamy Siva, Sheethal Sasi, Priya Rana, Raj Kumar Bera, Yuvaraj Sivalingam, Priyadip Das
Newly synthesized (L1)2M, (L2)2M, and (L3)2M (M = Zn(II)/Cd(II)) self-assembled into well-ordered superstructures and exhibited promising potential for developing a new class of sensor devices for human health monitoring and environmental safety measurements.
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Design of Fe and N co-decorated biomass-derived hierarchical porous carbon frameworks with boosted oxidase-like activity for hydroquinone detection

New J. Chem., 2024, 48,7197-7204
DOI: 10.1039/D4NJ00509K, Paper
Han Zhang, Xiaodan Qi, Zhifei Wang, Lihua Jin, Yehua Shen
An Fe and N co-decorated biomass-derived porous carbon framework with boosted oxidase-like activity was prepared and applied to sensitive hydroquinone detection.
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Hydroquinone colorimetric sensing based on core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites as oxidase mimics

New J. Chem., 2024, 48,7323-7333
DOI: 10.1039/D4NJ00284A, Paper
Xuefang Lei, Yujin Li, Peiqing Guo, Mingzhu Qiu, Rang Meng, Shaohui Li, Dongxia Zhang, Nali Chen, Xibin Zhou
The core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites were successfully synthesized by co-precipitation method, and CeO2 was uniformly dispersed on the shell layer with the help of nitrogen-doped graphene quantum dots (N-GQDs).
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Oxazoline amino acid bioconjugates: one-pot synthesis and analysis of supramolecular interactions

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00995A, Paper
Marija Bakija, Berislav Perić, Srećko I. Kirin
Oxazoline amino acid bioconjugates were synthesized; the relative stability of a supramolecular dimer of a tris-derivative was investigated using mean absolute error values (MAE), derived from 1H NMR experiments and DFT calculations.
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Facile synthesis of spiro-pyrazolone-tetrahydrofurans/pyrans: ipso-cyclization of arylidene pyrazolones with haloalcohols

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00447G, Paper
Kavyashree Kuppayya Gond, Mahagundappa Rachappa Maddani
Facile synthesis of spiro-pyrazolone-tetrahydrofurans & pyrans by base-mediated cascade ipso-cyclization of haloalcohols & arylidine pyrazolones is realised. Features include brief reaction time, practicality, good yields and mild reaction conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Introducing Keras Hub: Your one-stop shop for pretrained models

KerasHub is a new unified library for pretrained models fostering a more cohesive ecosystem for developers.




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Sharing our latest differential privacy milestones and advancements

Google is committed to investing in privacy-enhancing technologies (PETs) to ensure user data privacy, improving products like Google Home and Google Search.




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Karnataka Tourism | One State, many worlds, and a missed opportunity 

Lack of sustained marketing and promotion, adequate infrastructure, besides administrative shortcomings are among the reasons pointed out for tourism in Karnataka not taking off the way it has in other popular States




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Sister, friend, mother, and colleague all rolled into one

When a friend, sibling or parent doubles up as a colleague or business partner, work gets merrier




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An all-woman night walk takes over one of Bengaluru’s oldest lanes

The women-led tour through the lanes of Chickpet not just showcased the neighbourhood’s distinctive nightlife, but also aimed to create more safe spaces for women to walk at night, and reclaim the streets




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Alleviation of Cadmium-Induced Oxidative Damage through Application of Zinc Oxide Nanoparticles and Strigolactones in Solanum lycopersicum L.

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00796K, Paper
Vaseem Raja, Karanpal Singh, Sami Ullah Qadir, Jagpreet Singh, Ki-Hyun Kim
In this research, zinc oxide nanoparticles (ZnO NPs) are bio-synthesized using Mangifera indica leaf extract as a sustainable capping and stabilizing source. The spherical morphology, crystallinity, and average size (17.97...
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A novel one-dimensional Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructure fabricated by a single-nozzle electrospinning technique and its low color drift property at high temperature

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00149D, Paper
Shanshan Cong, Zhuang Tian, Hongquan Yu, Sai Xu, Lihong Cheng, Baojiu Chen, Tianshuo Liu
1D Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructures were fabricated by a simple single-nozzle electrospinning method. These materials exhibit excellent luminescent stability and lower color drift performance at high temperatures.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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Elon Musk apologises as Twitter takes more storage space on phone

Musk pointed out that the Twitter app occupies 9.52 GB of phone storage




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New York City bans use of TikTok on city-owned phones

Joins US federal government, majority of states in banning the social media app on security concerns




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Three reasons why HTC One has a headstart




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Civil Aviation Ministry notifies operational guidelines for drone PLI scheme

The PLI scheme will be only for the companies that are involved in the manufacture of drone and drone components in India




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My one and only telegram, hic!




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One night in Varanasi




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Video | One of the best places for non-veg food on highway - Selvi Mess in Salem




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Focus on One Health approach at veterinary science congress




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Supreme Court sceptical about Kerala Police demand for Malayalam actor Siddique’s phone from 2016

Extending the interim anticipatory bail granted to the actor, Supreme Court lists the case for next week for detailed arguments




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Kumily, one of the major stopovers enroute to Sabarimala, continues to lack essential amenities




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Demonetisation hits PM’s flagship crop insurance scheme

Lakhs of farmers, who are already reeling under drought and crop failure, have missed the deadline to avail of the scheme, which ended on November 9




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Stand united against demonetisation: Uddhav to traders




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The labor demand and labor supply channels of monetary policy [electronic resource] / Sebastian Graves, Christopher K. Huckfeldt, Eric T. Swanson

Cambridge, MA. : National Bureau of Economic Research, 2024




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Maharashtra Assembly election: Mahim — one Assembly seat, 3 Senas and wait for another 'sonrise'

High-stakes triangular contest in Mumbai’s Mahim Assembly seat among Shiv Sena, Opposition Shiv Sena (UBT), and MNS




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Bandra West seat: BJP's Mumbai chief Shelar seeks third term from one-time Cong bastion

It has some of the poshest houses in the city, mainly in Bandra West and Khar, as well as teeming slum colonies apart from middle class localities of Santacruz




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Baba Siddique murder case: One more arrested

Gaurav Vilas Apune, a resident of Karvenagar locality of Pune city, is the 16th person to be arrested in the case




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Honeywell’s not-for-profit arm says it has funded over 40 deeptech start-ups

In FY24, HHSIF supported 13 innovations—eight start-ups and five EIR programs—with a focus on agri-tech, clean-tech, health-tech, and green-tech initiatives




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What Happened To Sunny Leone?

Sunny Leone shocked everyone when she posted a bloodied picture of herself on social media.




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Sunny Leone Welcomes Ganpati

Film folk celebrated Ganesh Chaturthi with gusto over the weekend, and posted pictures on social media.




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'No One Like You, Kareena'

Dia writes a letter... Mouni sends a postcard...Kapil twins with family...




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Swara's Daughter Turns One

Swara Bhasker and Fahad Ahmad's little daughter Raabiyaa celebrated her first birthday on September 23, and the parents shared pictures on social media.




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'Why Didn't We Meet Sooner?'

Parineeti Chopra and Raghav Chadha are celebrating their first wedding anniversary in the Maldives.





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How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power? How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

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Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

jacksonl




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One for the road




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Clean facts on cyclones and climate change

Higher sea surface temperatures hold out the threat of more cyclones and deep depressions in the Bay of Bengal and Arabian Sea.




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Drone technology is expected to revolutionise India's marine fisheries sector




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No longer one-sided beneficiary of alliance with US: South Korean National Security Advisor