By TEDxCharleston Eight million tons. That’s a lot of plastic to swallow, and a lot of straws to bear even if you’re the world’s oceans (yes, who knew we use 300 million plastic straws a day?). Or rather, especially if … Continue reading →

By David Suzuki David Suzuki Foundation The fossil fuel era must end, or it will spell humanity’s end. The threat isn’t just from pollution and accelerating climate change. Rapid, wasteful exploitation of these valuable resources has also led to a … Continue reading →

Simon Scarr and Marco Hernandez at Reuters created Drowning in Plastic, visualizing the amount of plastic bottles we consume, recycle and throw away every hour, day, month, year and decade.

Around the world, almost 1 million plastic bottles are purchased every minute. As the environmental impact of that tide of plastic becomes a growing political issue, major packaged goods sellers and retailers are under pressure to cut the flow of the single-use bottles and containers that are clogging the world’s waterways.

Plastic production has surged in the last 50 years, leading to widespread use of inexpensive disposable products that are having a devastating effect on the environment. Images of plastic debris-strewn beaches and dead animals with stomachs full of plastic have sparked outrage.

Polyethylene terephthalate (PET) bottles are commonly used for soft drinks and mineral water, but can also be used in other household or personal care products. Data from Euromonitor International, shows that more than 480 billion of these bottles were sold last year alone. That’s almost 1 million every minute, as shown in the animation at the top of this page. The illustrations below show what that pile of plastic would look like if it was collected over a longer period of time.

The visuals of massive piles of plastic bottles next to recognizable landmarks helps provide context and scale to readers.

They also provided a nice Sankey Diagram showing the fate of most plastic bottles is to end up in the landfill.

Found on FlowingData

We investigate quasistatic evolution in finite plasticity under the assumption that the plastic strain is compatible. This assumption is well-suited to describe the special case of dislocation-free plasticity and entails that the plastic strain is the gradient of a plastic deformation map. The total deformation can be then seen as the composition of a plastic and an elastic deformation. This opens the way to an existence theory for the quasistatic evolution problem featuring both Lagrangian and Eulerian variables. A remarkable trait of the result is that it does not require second-order gradients.

We could blame the enormous — and justifiable — success of the Lego flicks for the existence of Playmobil: The Movie, but that would be unfair to all the shameless knockoffs and cinematic coattail riders.…

An ion-conductive thermoplastic compositions contains a partially acetalated polyvinyl alcohol, at least one support electrolyte and at least one plasticizer. The partially acetalated polyvinyl alcohol contains two different acetal units. Electrochromic laminated glass systems produced using the ion-conductive compositions and a method for producing the systems are also provided.

Plasticizing system which can be used in particular for the plasticizing of a tire diene elastomer composition containing, in combination: a plasticizing hydrocarbon resin, the glass transition temperature of which is greater than 0° C.; anda tri- or pyromellitate ester corresponding to the formula (I): in which the R radicals, which are identical or different, represent a hydrocarbon radical and the R' radical represents hydrogen or COOR group. Also, a rubber composition incorporating the plasticizing system and the use of such a composition for the manufacture of a tire or tire semi-finished product made of rubber, in particular of a tire tread, exhibiting an improved wear resistance without having a detrimental affect on its wet grip.

Structured films containing multi-walled carbon nanotubes (“MWCNTs”) have enhanced mechanical performance in terms of strength, fracture resistance, and creep recovery of polyimide (“PI”) films. Preferably, the loadings of MWCNTs can be in the range of 0.1 wt % to 0.5 wt %. The strength of the new PI films dried at 60° C. increased by 55% and 72% for 0.1 wt % MWCNT and 0.5 wt % MWCNT loadings, respectively, while the fracture resistance increased by 23% for the 0.1 wt % MWCNTs and then decreases at a loading of 0.5 wt % MWCNTs. The films can be advantageously be created by managing a corresponding shift in the annealing temperature at which the maximum strength occurs as the MWCNT loadings increase.

The invention provides a method for preventing discoloration of pyrithione-containing materials, in particular plastic materials or other material such as paints, coatings, adhesives or textiles which are exposed to an outdoor environment. The method is likewise suited for preventing discoloration of other pyrithione-containing materials such as personal care compositions like shampoos. A discoloration inhibitor that includes dehydroacetic acid or a salt thereof is added to the pyrithione-containing material. The discoloration is prevented without the addition of a cyclic organic phosphoric acid ester or an organic phosphite. Use of the discoloration inhibitor does not interfere with the antimicrobial effect of the pyrithione.

The invention relates to a method for producing thermoplastic molding compounds, comprising: A) 40 to 99 wt % of at least one thermoplastic polymer, B) 1 to 60 wt % of a flame-proofing agent component containing an expandable graphite, and C) 0 to 60 wt % of further additives, by melt-mixing components A), B) and C) in a screw-type extruder, wherein the screw-type extruder, along the feed direction, comprises, in the following order, at least one dosing zone, a plastifying zone, a homogenizing zone, a second dosing zone, and a discharge zone, in that the dosing takes place into the screw-type extruder having the length L, wherein the length L is defined as the section starting with the first dosing unit for adding components A, B and/or C and ending, in the feed direction, at the discharge opening, a melt is generated after adding components A, B and C in the range of 0 liter to 0.15 liter in a first method step in the presence of component B1), and in a second method step, after the addition of component B1) in the range of 0.5 liter to 0.95 liter, component B1) is mixed into said melt, wherein said method offers technical advantages.

An environmentally beneficial process for utilizing waste drill cuttings from oil and gas exploration. The waste drill cuttings (20) are used as a filler and combined with plastic to provide a plastic based product (26) in the plastics industry. In an embodiment the cuttings are thermally treated and formed into pellets. In a further embodiment the cuttings are treated and mixed with recycled plastic to be formed into pellets. The pellets are then used in the manufacture of rigid plastic products such as bollards, planters, benches and decking.

A decoration piece has: a design piece made of thermoplastic synthetic resin formed with a design and having an outer profile line; a lower layer; and a dye migration preventing layer arranged between the design piece and the lower layer, said dye migration preventing layer having an outer profile same as that of said design piece, said dye migration preventing layer capable of being adhered to both said design piece and the lower layer, said dye migration preventing layer capable of preventing any migrating of dye. The dye migration preventing layer includes a dye migration preventing film made of ethylene-vinyl alcohol copolymer or polyamide MXD6, or a dye migration preventing film made of polyvinylidene chloride.

Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin characterized by being derived from a reaction between a 5-membered cyclic carbonate polysiloxane compound represented by the below-described formula (1) and an amine compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin. wherein A means

An apparatus and method for the shaping of plastics material pre-forms into plastics material containers with at least one blow moulding station which is arranged on a conveying device rotatable about a pre-set axis of rotation (D). The blow moulding station has a blow mould and this blow mould forms a cavity in the interior of which the plastics material pre-forms are capable of being expanded by being acted upon with a gaseous medium to form the plastics material containers, with a stressing device, which acts upon the plastics material pre-forms with the gaseous medium in order to expand them, and with a clean room, which surrounds the blow moulding station at least in part. The clean room is bounded off from an environment by at least two walls which are movable relative to one another.

A process is disclosed for producing plastic materials by providing a biology based feedstock and reacting the biology based feedstock to form a feedstock capable of reaction to form the plastic material, wherein the plastic material is selected from polystyrene and polyethylene terephthalate (PET).

The present invention relates to a crosslinked lignin comprising a lignin structure having methylene or ethylene linking groups therein crosslinking between phenyl ring carbon atoms, wherein said crosslinked lignin is crosslinked to an extent that it has a number-average molecular weight of at least 10,000 g/mol, is melt-processible, and has either a glass transition temperature of at least 100° C., or is substantially soluble in a polar organic solvent or aqueous alkaline solution. Thermoplastic copolymers containing the crosslinked lignin are also described. Methods for producing the crosslinked lignin and thermoplastic copolymers are also described.

Oil compositions having a high concentration of polyunsaturated fatty acids are described for use in various applications including use as drying oils, in ink compositions and coating compositions. Oil compositions wherein the double bonds of the fatty acids are substantially epoxidized are described and used as plasticizers and thermal stabilizers for various halogenated polymer compositions.

Thermoplastic composition and articles containing UV absorbers that protect the articles contents from harmful UV radiation are disclosed as well as methods for making the thermoplastic articles and methods for using the articles to contain and protect materials sensitive to UV radiation. The UV absorbers contain oxazolone and/or azine functional groups that absorb UV radiation and prevent its transmission into the article. Many of the compounds are novel compositions of matter. The generally clear thermoplastic articles of this disclosure are particularly useful for containing a variety of UV sensitive consumer products that would otherwise have to be packaged in opaque containers.

Disclosed is a general methodology to create nano fibers of therapeutic molecules that have a dual role, as both the delivery vehicle and the drug itself. It is shown that with proper molecular design, the integration of enzymatic reaction and self-assembly provides a powerful method to create molecular hydrogels of clinically-used therapeutics without compromising their bioactivities. In addition, the results disclosed herein demonstrate enzyme-instructed self-assembly as a facile strategy for generating the supramolecular hydrogels of molecules that inherently have poor solubility in water. For example, by covalently connecting paclitaxel with a motif that is prone to self-assemble, a hydrogel of paclitaxel can be formed without compromising the activity of the paclitaxel.

A plastic pencil comprising a writing core, an interlayer coating material placed about the writing core, a porous casing enclosing the interlayer coating material on the writing core and a covering applied to the exterior surface of the porous casing.

The invention relates to a method for producing a plastics material article, said method including the extruding of a tube-shaped parison and the re-forming of the parison into a hollow body within a blow mold by applying differential pressure. The method includes initially a first expanding and partial shaping of the parison with the blow mold not completely closed. Then at least one opening is provided on the circumference of the pre-expanded parison. In a further step at least one part to be built-in is introduced through the opening into the interior of the partially shaped plastics material article. In a final step the blow mold is closed completely and the blow molding of the plastics material article is completed.

A hand tool for inserting a large variety of connector components into narrow plastic irrigation piping is disclosed. This tool is an improved and progressive development of my previous Israeli patent no: 152089 in that it is designed to work with a large variety of connector components and is designed to accommodate both sizes of narrow spaghetti piping, whereas the previous patent could accommodate only a single size of narrow piping. The tool as shown in FIG. 2 has a body onto which all the elements are connected and the body is configured to sit comfortably in the palm of the hand. When pressing down on the handle, the grips secure the narrow piping and cause a connector component, deployed in appropriate recess provided in the tool to be easily inserted into the narrow piping.

A surgical instrument including a handle portion, a body portion, a movable handle, a tool assembly, a drive beam and a closure apparatus is disclosed. At least one of the closure apparatus and a contact surface of the tool assembly include a plastic surface. The body portion extends distally from the handle portion. The movable handle is located on the handle portion and is in mechanical cooperation with a drive member. The tool assembly includes an anvil, a cartridge assembly and a contact surface. The drive beam includes a proximal engagement portion and is configured to engage a portion of the drive member. The closure apparatus is configured to engage the contact surface of the tool assembly. At least a partial actuation of the movable handle moves the closure apparatus distally into engagement with the contact surface to approximate the anvil and the cartridge assembly.

A surgical instrument including a handle portion, a body portion, a movable handle, a tool assembly, a drive beam and a closure apparatus is disclosed. At least one of the closure apparatus and a contact surface of the tool assembly include a plastic surface. The body portion extends distally from the handle portion. The movable handle is located on the handle portion and is in mechanical cooperation with a drive member. The tool assembly includes an anvil, a cartridge assembly and a contact surface. The drive beam includes a proximal engagement portion and is configured to engage a portion of the drive member. The closure apparatus is configured to engage the contact surface of the tool assembly. At least a partial actuation of the movable handle moves the closure apparatus distally into engagement with the contact surface to approximate the anvil and the cartridge assembly.

A surgical instrument including a handle portion, a body portion, a movable handle, a tool assembly, a drive beam and a closure apparatus is disclosed. At least one of the closure apparatus and a contact surface of the tool assembly include a plastic surface. The body portion extends distally from the handle portion. The movable handle is located on the handle portion and is in mechanical cooperation with a drive member. The tool assembly includes an anvil, a cartridge assembly and a contact surface. The drive beam includes a proximal engagement portion and is configured to engage a portion of the drive member. The closure apparatus is configured to engage the contact surface of the tool assembly. At least a partial actuation of the movable handle moves the closure apparatus distally into engagement with the contact surface to approximate the anvil and the cartridge assembly.

A device for joining a plastic part to a second part with an insert adapted to thread into the plastic part. The insert includes a longitudinal body with outer threads, a hole in the longitudinal body with female threads, and an annular flange. Protrusions and recesses on the bottom of the annular flange alternate in a radial pattern. The insert is threaded into an opening in the plastic part. The protrusions and recesses of the insert interact with the plastic part to resist over rotation of the insert. The opening in the plastic part may include a hole and a counter bore portion. The counter bore includes protrusions and recesses. The protrusions and recesses alternate in a radial pattern. When the insert is threaded into the opening, the protrusions and recesses of the insert interact with the protrusions and recesses of the plastic part and resist over rotation.

A connecting arrangement is provided between a plastic component with at least two mutually adjacent and at least approximately parallel walls and another structural element, having at least one force-transmission element which is adhesively bonded to the plastic component via an adhesive bond on the plastic component in frusto-conical or spherical-segment-shaped depressions in the mutually adjacent walls of the plastic component. The force-transmission element has a carrying structure for the other structural element. With the exception of a possibly provided coating, the force-transmission element is composed only of metallic material and has a plate which is adapted to the depression in the outer wall of the plastic component, which outer wall is adjacent to the other structural element. The edge of the plate rests with interposition on the outer wall in the surrounding region of the depression, wherein the plate is connected via a web to an end section of the force-transmission element, which end section is adapted to the depression in the other inner wall of the plastic component. The depression is configured in the outer wall without a bottom to such an extent that the end section of the force-transmission element can be inserted through the outer wall into the recess of the inner wall.

The invention relates to a plastic screw plug (6) for attaching a rail to a sleeper, in particular concrete sleeper, having an essentially cylindrical plug body which has at the head end a stem region (7) which preferably adjoins a plug crown (8) toward the bottom, and in the continuation of which stem region (7) has an outer thread (9) with which it can be turned out of or into the sleeper, and is provided with an inner thread (10) underneath the stem region (7) in order to receive a sleeper screw. The intention is to improve such a plastic screw plug, in particular, with regard to its operating properties such as uniform application of force into the sleeper, simpler mounting and replaceability, reduction of the risk of fracturing, and additionally to permit it to be used in a variable way. For this purpose, the stem region (7) has on the inside, in the junction with the inner thread (10), a shoulder (13) which reduces the internal diameter over part of the length of the stem region (7) and extends in a spiral shape over at least part of the circumference.

A contacting-type conductivity sensor includes an electrically-insulative plastic body and a plurality of electrodes. The plurality of conductive electrodes is disposed in the plastic body. Each electrode is constructed of plastic and fused with the electrically-insulative plastic body. A method of manufacturing the conductivity sensor is provided along with a single-use bioreactor employing the sensor.

A writing kit including a plastic sheet, a binding and a case with a closing element to hold the plastic sheet in the case. The case has at least one hole at a center portion of the case and the sheet has at least one hole in the sheet. A binding comprising a flexible cord is laced through the hole in the sheet and the case and a clasp slidingly engages the cord.

Disclosed is a plastic film with concealed tearable strip, which includes a film body; at least one first tearable strip having two sides respectively forming first and second joint sections; and at least one second tearable strip having two sides respectively forming a third joint section and an internal tear line. The first and second tearable strips each have one side connected to the film body. The first joint section has two sides each forming a tear line. The third joint section has one side forming at least one tear line. The third joint section and the internal tear line have inside faces respectively coupled to the first and second joint sections, whereby the first and second tearable strips are respectively located at outside and inside of the film body and the second tearable strip is concealed at the inside of the film body.

A fluid actuator includes a housing having a fluid chamber providing a first friction surface. An actuating member is arranged in the fluid chamber and has a second friction surface slideably engaging the first friction surface. The actuating member is configured to slide within the chamber between first and second positions. An insert is constructed from a first thermoplastic material and provides one of the first and second friction surfaces. A body structurally supports the insert and provides one of the housing or actuating member. The body is constructed from a second thermoplastic material molded about the insert and including short reinforcing fibers.

The present invention may be embodied as a compounding system having a chamber assembly defining a working chamber; a shaft, a sleeve assembly, and a plurality of arms. The sleeve assembly has first and second sleeve members each defining at least one arm opening and adapted to be arranged in a first configuration in which the first and second sleeve members are detached from each other and a second configuration in which the first and second sleeve members are secured together around the shaft to support the sleeve assembly on the shaft. Each of the arms is configured to be inserted partly through one of the arm openings when the sleeve assembly is in the first configuration and held in a desired configuration relative to one of the first and second sleeve members when the sleeve assembly is in the second configuration.

Provided is a gathering device for gathering plastic members. The gathering device includes a gathering portion and a tray detachably connected to the gathering portion. The gathering portion includes an outer shell, a hollow inner shell and a number of fans. The inner shell is received in the outer shell. The inner shell includes a number of vent. The fans are positioned between the outer shell and the inner shell for blowing ions into the inner shell through the vents. The tray is configured for containing the plastic members passing through the gathering portion.

Disclosed is a corrugated plastic composite spring for a vehicle suspension and an apparatus and method for manufacturing the same. The apparatus includes a corrugated extrusion part, a braiding part, and a pultrusion part. The corrugated extrusion part forms a preform having a hollow corrugated structure. The braiding part weaves a three-dimensional woven fabric on the preform. The pultrusion part impregnates the three-dimensional woven fabric with thermosetting resin.

The method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method can comprise the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. The method can include the step of comminuting the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1. The method can also include the step of adding an effective amount of a cracking catalyst to the waste plastic prior to step 2.

A styrene monomer reclamation process and system is described. The styrene monomer reclamation process includes providing a waste plastic. The waste plastic includes styrenic polymers. The waste plastic is formed into polymer particles. At least a portion of the polymer particles are dissolved in a solvent to form a polymer stream. The dissolved polymer particles are depolymerized to form a styrene monomer stream.

A method for processing plastic waste, in particular polyolefins, and a device for processing plastic waste, in particular polyolefins, are used especially in the industrial utilization of plastic waste. The method consists in that a primarily refined charge after being fed into a reactor (6) is fluidized and cracked during forced progressive-rotational movement coinciding with heating. A gas-steam fraction obtained during a utilization process is continuously guided out to a cooling system whereas impurities are periodically guided out from the reactor (6) to a waste tank (22).

Pigmented substantially crack-free casein plastic compositions containing a minor, luster-imparting quantity of coated mica platelets, wherein at least 75% of the pigment particles possess an average platelet size of below 10 μm., a thickness of about 0.1 to 0.7 μm. and a ratio of diameter to thickness of about 10 to 200.

Device for taking back empty containers, in particular plastic bottles and metal cans, with a housing which has apparatuses for processing inserted empty containers, an intake chute accessible from the outside that receives empty containers as bulk material and a bottom sloping downward in direction of intake chute. Device is provided that prevents or impedes insertion of excessively large objects into device. Device provides almost unimpeded insertion of empty containers as bulk material into intake chute, and simultaneously prevents that excessively large objects can enter into the device. The bottom of intake chute has a plurality of grooves arranged side by side and running in the intake direction, the grooves flowing into a passage opening leading to the device and whose cross-section is dimensioned in such a manner that empty containers aligned longitudinally in the intake direction can pass unimpeded through the grooves.

A filter material adapted for use as a filter element of a smoking article is provided, the filter material being in the form of a fibrous tow that includes a plurality of filaments of a degradable polyester and a plasticizer composition applied thereto, the plasticizer composition and the degradable polyester having a Relative Energy Difference calculated using Hansen Solubility Parameters of less than about 1.3. Exemplary degradable polyesters include polyglycolic acid, polylactic acid, polyhydroxyalkanoates, polycaprolactone, polybutylene succinate adipate and copolymers or blends thereof. Exemplary plasticizer compositions include one or more of dimethylisosorbide, propylene carbonate, methylbenzyl alcohol, glycerol carbonate acetate, glycerol carbonate ethyl ether, and mixtures thereof, optionally in combination with triacetin. Filter elements and smoking articles, such as cigarettes, that contain the filter material are also provided.

The invention relates to a biodegradable plastic having increased biodegradation speed. Said plastic comprises a) finely distributed particle of a biodegradable, water-soluble, organic component, and b) finely distributed particles of a water-soluble, inorganic component promoting the growth of microorganisms and comprising N, P, and/or S. Said plastic is particularly based on cellulose esters such as cellulose acetate. Preferable components A are water-soluble saccharides and/or water-soluble organic acids. Said particularly advantageous biodegradable plastic is particularly available in the form of fibers, films, injection molded items, granulate beads, and containers. Controlled-release biocides and/or fertilizers can also be included in the molded part, wherein the molded part is degraded faster in the environment as said ingredients are released. The accelerated biodegradation is based on a synergistic interaction of the components indicated.

A method of dyeing a plastic lens including applying a sublimation dye to a dyeing substrate, holding the dyeing substrate on a holding member, holding a plastic lens on the holding member at a position above the dyeing substrate, evacuating a vacuum vessel which accommodates the holding member, transferring the dyeing substrate from the holding member to a heating device provided in the vacuum vessel, so that the dyeing substrate is held to be heatable by the heating device, by vertically moving at least one of the holding member and the heating device, bringing the plastic lens in close proximity to the dyeing substrate by vertically moving at least one of the holding member and the heating device which holds the dyeing substrate, and dyeing the target surface of the plastic lens with the sublimation dye by sublimating the sublimation dye by heating the dyeing substrate using the heating device.

A securing device for mechanical components that is comprised of the securing device is designed as a longitudinal plastic strip comprised of a first complementary tab and a second complementary tab. The first complementary tab and the second complementary tab interlock together and rest flush against one another in a manner that lines up the hole of the first complementary tab with the hole of the second complementary tab. The securing device may be surrounded by a cushion to improve the securing functionality of the device.

The present invention provides a roll-to-roll continuous manufacturing process for producing a thermoplastic composite laminate comprising extruding a thermoplastic resin into a film article, surface treating a fiber material with a special sizing and laminating at least one layer of thermoplastic film and at least one layer of the surfaced treated fiber material into a composite sheet at a temperature above the melting or softening point of the thermoplastic film and under pressure applied by nipping rolls or nipping belts.

A plastic soft composition is formed of soft base material constantly provided with plasticity, porous fine particles for polishing contained in the base material, and the like, and a polishing process and a coating process are performed to a painted surface and the like using the plastic soft composition. The fine particles for polishing are impregnated with a coating agent (a surface protective agent) added with an activator which is emulsified by contact with water, and the coating agent is held in concave portions formed in the fine particles. Both polishing work and coating work are achieved by sliding the plastic soft composition on a painted surface by a palm pressure of a user.

The invention provides a high strength stone plastic floor and manufacturing method thereof. The stone plastic floor comprises a PVC substrate and a surface layer on a surface of the PVC substrate. Compositions of PVC substrate comprise: PVC powder from 20 to 35 weight percent, calcium carbonate from 60 to 70 weight percent, stabilizer from 1 to 3 weight percent, flexibilizer from 1 to 3 weight percent, lubricants from 0.4 to 1 weight percent, and colorant from 0.4 to 1 weight percent. The high strength stone plastic floor does not contain plasticizer so environmental risks are completely avoided. The contractility is good. The high strength stone plastic floor is resistant to high temperature and direct sunlight. Compared with conventional stone plastic floor, lifespan of the present invention is prolonged. The PVC substrate of the floor can be combined with different layers and can integrate different advantages of other floors.

An assembly including a joining element and an object, the object having a first outer layer, a second outer layer, and a middle layer between the first and second outer layers. The object has an opening that extends through the first outer layer and the middle layer, and the joining element is anchored in the opening. The joining element includes a proximal end, a distal end, a contact face in the area of the proximal end, a wall anchoring portion, and a tubular portion. The contact face is engaged by a vibrating tool that applies mechanical vibration and axial force to the joining element. The joining element includes a thermoplastic material at least at the circumferential surface of the wall anchoring portion and at the distal end to anchor the joining element to the first and second outer layers, respectively.

Methods are provided for production of a composite layer comprising a plastic foil and a layer deposited directly thereon. A method for production of a composite layer comprising a plastic foil and at least one layer deposited directly onto the plastic foil by means of chemical gas-phase deposition within a vacuum chamber may be provided, wherein the plastic foil has a proportion of at least 20 percent by mass of a metal element or of a semiconductor element, wherein during the layer deposition, at least one monomer is supplied into the vacuum chamber and a plasma is formed within the vacuum chamber. After completed deposition of the layer, at least one surface region of the layer is exposed to accelerated electrons.

A fluid activatable adhesive for a liner-free label and methods of using are described. Preferably, the adhesive composition includes a polymer, such as an emulsion polymer formed from monomers selected from the group consisting of butyl acrylate, 2-ethylhexyl acrylate, methyl acrylate, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), a salt of AMPS, such as its sodium salt, styrene, and combinations thereof. The adhesive composition adheres to the liner-free label to the surface of a substrate that is at room temperature, at room temperature and wet, cold, or cold and wet. In preferred embodiments, the substrate is glass or plastic, such as polyethylene terephthalate.