hydrogen

Synthesis of chiral α-substituted α-amino acid and amine derivatives through Ni-catalyzed asymmetric hydrogenation

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Chem. Commun., 2020, 56,4934-4937
DOI: 10.1039/D0CC01220C, Communication
Gongyi Liu, Xianghe Zhang, Heng Wang, Hengjiang Cong, Xumu Zhang, Xiu-Qin Dong
Efficient Ni-catalyzed asymmetric hydrogenation of cyclic N-sulfonyl ketimino esters and ketimines was successfully developed to prepare a series of chiral α-monosubstituted α-amino acid derivatives and amine derivatives with excellent results.
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Inter-chain double-site synergistic photocatalytic hydrogen evolution in robust cuprous coordination polymers

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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01785J, Communication
Ying Zang, Jiangwei Zhang, Rui Wang, Zhao-Di Wang, Yandi Zhu, Xiaoyan Ren, Shunfang Li, Xi-Yan Dong, Shuang-Quan Zang
We evaluate photocatalytic H2 generation of three Cu-based coordination polymers, a record-high rate of 57.64 mmol g−1 h−1 for Cu–MIM, and reveal that the excellent performances are due to the synergies of the inter-chain double-site Cu atoms.
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hydrogen

Correction: Colloidal synthesis of porous red phosphorus nanoparticles as a metal-free electrocatalyst for the hydrogen evolution reaction

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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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A metal-organic framework with in-situ generated low-coordinate binuclear Cu(I) units as the highly effective catalyst for photodriven hydrogen production

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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09589F, Communication
Pei-Qin Liao, Ningyu Huang, Hai He, Hao Li, Xiao-Ming Chen
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic...
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hydrogen

Modulation of an intermediate layer between NiCoP and Ni foam substrate in a microwire array electrode for enhancing the hydrogen-evolution reaction

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Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication
Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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hydrogen

Is breaking of a hydrogen bond enough to lead to drug resistance?

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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02164D, Communication
María José Dávila-Rodríguez, Thales Souza Freire, Erik Lindahl, Ignez Caracelli, Júlio Zukerman-Schpector, Ran Friedman
Drug resistance is a serious problem in cancer, viral, bacterial, fungal and parasitic diseases. Examination of crystal structures of protein-drug complexes is often not enough to explain why a certain...
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hydrogen

Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π(-)−π stacking

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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02671A, Communication
Shweta P. Yelgaonkar, Daniyal Kiani, Jonas Baltrusaitis, Len R MacGillivray
Salt cocrystals with components that assemble by hydrogen bonds and aromatic anion-molecule stacks (π(−)−π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and...
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hydrogen

Competitive hydrogen bonding in supramolecular polymerizations of tribenzylbenzene-1,3,5-tricarboxamides

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Mol. Syst. Des. Eng., 2020, Advance Article
DOI: 10.1039/D0ME00030B, Paper
Mathijs F. J. Mabesoone, Sinan Kardas, Héctor Soria-Carrera, Joaquín Barberá, Jesús M. de la Fuente, Anja R. A. Palmans, Mathieu Fossépré, Mathieu Surin, Rafael Martín-Rapún
By combining experiments and molecular modelling we elucidate the role of competitive hydrogen bonding on the supramolecular behavior of tris(alkoxybenzyl)benzene-1,3,5-tricarboxamides.
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Experimental and theoretical investigation on MoS2/MXene heterostructure as an efficient electrocatalyst for hydrogen evolution in both acidic and alkaline media

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00956C, Paper
Le Hu, Yuyun Sun, Shi-Jing Gong, Hui Zong, Ke Yu, Ziqiang Zhu
A composite of MoS2/Nb2CTx with MoS2 nanoflowers grown between Nb2CTx flakes for electrolysis of water in acidic and alkaline solutions.
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Iodine-Catalyzed α,β-Dehydrogenation of Ketones and Aldehydes Generating Conjugated Enones and Enals

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01244K, Letter
Yuanjie Cao, Long Liu, Tianzeng Huang, Tieqiao Chen
A transition metal-free α,β-dehydrogenation of ketones and aldehydes was developed. This reaction was conducted in a facile I2/KI/DMSO system to produce the corresponding unsaturated compounds in good to high yields....
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hydrogen

A facile synthesis of Ru/N–C as an efficient and cost-effective electrocatalyst for hydrogen evolution

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01227K, Paper
Zichuang Li, Yu Pei, Qiangjian Ju, Beibei Guo, Yifan Hu, Qian Liu, Yufang Zhu, Jiacheng Wang
This work provides a HER catalyst synthesis strategy with performance comparable to commercial Pt/C at a cost of only 0.6%.
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Hydrogenation of CO2 to LPG over CuZnZr/MeSAPO-34 Catalyst

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00907E, Paper
Peng Lu, Tong Mingliang, Emmerson Hondo, Linet Gapu Chizema, Ce Du, Qingxiang Ma, Shuting Mo, Chengxue Lu, Noritatsu Tsubaki
The utilization of CO2 to synthesize environmentally begnin liquid fuels offers a solution to replacing depleting petroleum resources. Herein, a ternary CuZnZr (CZZ) metal oxide catalyst and a SAPO-34 zeolite...
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Fabrication of a 3D self-supporting Ni–P/Ni2P/CC composite and its robust hydrogen evolution reaction properties in alkaline solution

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00727G, Paper
Fan Yang, Shuqin Yang, Qianqian Niu, Siyue Huo, Zimo Song, Laizhou Song
The Ni–P/Ni2P/CC composite exhibits excellent alkaline HER properties derived from Ni–P filling the sites on the CC not occupied by Ni2P nanosheets.
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Catalytic transfer hydrogenation of biomass-derived levulinic acid to γ-valerolactone over Sn/Al-SBA-15 catalysts

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01288B, Paper
Sakthivel Kumaravel, Sivakumar Thiripuranthagan, Mani Durai, Elangovan Erusappan, Thanigaivel Vembuli
The synthesized inexpensive catalysts show high catalytic transfer hydrogenation activity at ambient N2 pressure under non-corrosive conditions. The Sn/Al-SBA-15 (25) catalyst exhibited the highest catalytic activity with 99% conversion of levulinic acid and 100% selectivity towards GVL.
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hydrogen

Proton conduction in two Cu/Zn dimer-based hydrogen-bonded supramolecular frameworks from imidazole multi-carboxylate

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01189D, Paper
Qingxu Wang, Zhejun Ye, Guoqing Shi, Kaimeng Guo, Gang Li
At 98% RH and 100 °C, two dimer-based HSFs show the best σ values of 3.13 × 10−4 S cm−1 for 1 and 0.55 × 10−4 S cm−1 for 2, which can be compared to the values of reported HSFs.
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hydrogen

Iron and chromium MOFs as sustainable catalysts for transfer hydrogenation of carbonyl compounds and biomass conversions

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00552E, Paper
Punitharaj Vasanthakumar, Dharmalingam Sindhuja, Duraisamy Senthil Raja, Chia-Her Lin, Ramasamy Karvembu
Fe and Cr based MOFs (MIL-88B) act as efficient and reusable catalysts for transfer hydrogenation of carbonyl compounds including bio-derived substrates.
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hydrogen

Conjugated nanoporous polycarbazole bearing a cobalt complex for efficient visible-light driven hydrogen evolution

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01534B, Paper
Bin Guo, Hai-Yan Li, Jianying Chen, David James Young, Jian-Ping Lang, Hong-Xi Li
A conjugated nanoporous polycarbazole (CNP) cross-linked by pyridine and coordinated to Co(III) displays high catalytic performance for visible light-driven H2 generation. The hydrogen evolution rate was up to 410 μmol·g-1·h-1....
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hydrogen

[ASAP] Target-Based Design of Promysalin Analogues Identifies a New Putative Binding Cleft in Succinate Dehydrogenase

By dx.doi.org
Published On :: Tue, 14 Apr 2020 04:00:00 GMT

ACS Infectious Diseases
DOI: 10.1021/acsinfecdis.0c00024


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hydrogen

Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication
Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.
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hydrogen

Stabilization of hydrogen peroxide by hydrogen bonding in the crystal structure of 2-aminobenzimidazole perhydrate

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CrystEngComm, 2020, 22,2866-2872
DOI: 10.1039/D0CE00096E, Paper
Andrei V. Churakov, Dmitry A. Grishanov, Alexander G. Medvedev, Alexey A. Mikhaylov, Mikhail V. Vener, Mger A. Navasardyan, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V. Prikhodchenko
2-Aminobenzimidazole peroxosolvate – the third H2O2 crystalline adduct stabilized with the maximum possible number of hydrogen bonds formed by one hydrogen peroxide molecule.
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hydrogen

A theoretical insight on the rigid hydrogen-bonded network in the solid state structure of two zinc(II) complexes and their strong fluorescence behaviors

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CrystEngComm, 2020, 22,3005-3019
DOI: 10.1039/D0CE00125B, Paper
Ipsita Mondal, Tanmoy Basak, Snehasis Banerjee, Shouvik Chattopadhyay
A reduced Schiff base used as a fluorescence chemo-sensor for selective detection of zinc(II). Strong fluorescence behaviors of two zinc(II) complexes are correlated with the presence of a rigid hydrogen-bonded network in their solid state structure.
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hydrogen

Conductive zigzag Pd(III)–Br chain complex realized by multiple-hydrogen-bond approach

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00332H, Paper
Mohammad Rasel Mian, Unjila Afrin, Hiroaki Iguchi, Shinya Takaishi, Takefumi Yoshida, Tatsuya Miyamoto, Hiroshi Okamoto, Hisaaki Tanaka, Shin-ichi Kuroda, Masahiro Yamashita
Coexistence of zigzag structure and uncommon Pd(III) oxidation state in quasi-1D halogen-bridged metal complexes was realized in a conductive Br-bridged Pd chain complex, [Pd(dabdOH)2Br]SO4·3H2O (2), for the first time. Intra-...
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hydrogen

N-H···O Hydrogen Bonding to the Alkoxy Oxygen of a Carboxylic Ester Group: Crystal Structures of Methyl 2,6-Diaminobenzoate and Its Derivatives.

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00495B, Paper
John D. Wallis, Alun Christopher Garner, Songjie Yang
Methyl 2,6-diaminobenzoate and its bis-triphenylboron complex show hydrogen bonding from NH2 groups to both oxygen atoms of the carboxylic ester, and there is little difference in the lengths of these...
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hydrogen

Repurposing of the anti-HIV drug Emtricitabine as a hydrogen-bonded cleft for bipyridines via cocrystallization

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00474J, Communication
Gonzalo Campillo-Alvarado, Elizabeth Keene, Dale C. Swenson, Len R MacGillivray
We report supramolecular repurposing of Emtricitabine (FTC, trade name: Emtriva®), a blockbuster FDA-approved anti-HIV agent. FTC is revealed to act as a hydrogen-bonded cleft for bipyridine recognition. The supramolecular repurposing...
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hydrogen

Aldehyde Dehydrogenases: From Alcohol Metabolism to Human Health and Precision Medicine / Jun Ren, Yingmei Zhang, Junbo Ge, editors

By library.mit.edu
Published On :: Sun, 1 Sep 2019 09:33:23 EDT

Online Resource


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hydrogen

Hydrogenosomes and mitosomes: mitochondria of anaerobic eukaryotes / Jan Tachezy, editor

By library.mit.edu
Published On :: Sun, 15 Sep 2019 09:28:50 EDT

Online Resource


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hydrogen

High-yield electrochemical hydrogen peroxide production from an enhanced two-electron oxygen reduction pathway by mesoporous nitrogen-doped carbon and manganese hybrid electrocatalysts

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Nanoscale Horiz., 2020, 5,832-838
DOI: 10.1039/C9NH00783K, Communication
Ayeong Byeon, Jinwon Cho, Jong Min Kim, Keun Hwa Chae, Hee-Young Park, Seok Won Hong, Hyung Chul Ham, Seung Woo Lee, Ki Ro Yoon, Jin Young Kim
A selective and efficient electrocatalyst composed of MnO and Mn–Nx co-doped carbon nanostructures is developed for electrochemical hydrogen peroxide generation.
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hydrogen

Spatially separated bimetallic cocatalysts on hollow-structured TiO2 for photocatalytic hydrogen generation

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00042F, Research Article
Ping She, Jun-sheng Qin, Heng Rao, Buyuan Guan, Jihong Yu
A hollow-structured TiO2 decorated with spatially separated bimetallic cocatalysts (Pd@TiO2@Au) was obtained, which exhibited superior photo-induced charge separation by combining the SPR effect of Au NPs and the smaller size effect of Pd NPs.
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hydrogen

Highly active hydrogen evolution catalysis on oxygen-deficient double-perovskite oxide PrBaCo2O6−δ

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Mater. Chem. Front., 2020, 4,1519-1529
DOI: 10.1039/D0QM00056F, Research Article
Hayato Togano, Kaisei Asai, Seiji Oda, Hidekazu Ikeno, Shogo Kawaguchi, Kengo Oka, Kouhei Wada, Shunsuke Yagi, Ikuya Yamada
Oxygen-deficient double perovskite oxides PrBaCo2O6−δ exhibit highly active hydrogen evolution reaction catalysis, which is associated with multiple factors: oxygen deficiency, high Co valence, and A-site cation ordering.
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hydrogen

NixRh1−x bimetallic alloy nanofibers as a pH-universal electrocatalyst for the hydrogen evolution reaction: the synthetic strategy and fascinating electroactivity

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J. Mater. Chem. A, 2020, 8,8629-8637
DOI: 10.1039/D0TA02005B, Paper
Dasol Jin, Areum Yu, Youngmi Lee, Myung Hwa Kim, Chongmok Lee
NixRh1–x bimetallic alloy nanofibers synthesized by H2-reduction of NiRh2O4 exhibited outstanding pH-universal HER electrocatalytic activity with high stability.
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hydrogen

Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light

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J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02833A, Paper
Hongxia Liu, Meng Wang, Jiantai Ma, Gongxuan Lu
New high active low-cost Pd-Sn alloy catalyst for hydrogen evolution from toxic formaldehyde driven by visible light was developed via alloying of Pd with abundance element Sn.
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hydrogen

In Situ Confinement of Pt within Three-Dimensional MoO2@Porous Carbon for Efficient Hydrogen Evolution

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J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02507K, Paper
Yimin Jiang, Miao Yang, Meijiao Qu, Yi Wang, Zhouchunyu Yang, Qingliang Feng, Xia Deng, Wei Shen, Ming Li, Rongxing He
Promoting the industrialization and widespread application of Pt-based catalysts is essential to electrochemical water-splitting systems. However, the development of cost-effective Pt-based catalysts still remains a high challenge. Here we report...
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hydrogen

[ASAP] Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex

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Published On :: Mon, 04 May 2020 04:00:00 GMT

Organic Letters
DOI: 10.1021/acs.orglett.0c01273


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hydrogen

[ASAP] Benzo- and Thieno-Annulated Tetracenes: A One-Pot Synthesis via Cross-Dehydrogenative Annulation

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Published On :: Fri, 08 May 2020 04:00:00 GMT

Organic Letters
DOI: 10.1021/acs.orglett.0c01244


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hydrogen

[ASAP] 100th Anniversary of Macromolecular Science Viewpoint: Modeling and Simulation of Macromolecules with Hydrogen Bonds: Challenges, Successes, and Opportunities

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Published On :: Fri, 17 Apr 2020 04:00:00 GMT

ACS Macro Letters
DOI: 10.1021/acsmacrolett.0c00134


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hydrogen

Enantioconvergent and enantiodivergent catalytic hydrogenation of isomeric olefins

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Chem. Soc. Rev., 2020, 49,2504-2522
DOI: 10.1039/C9CS00138G, Review Article
Open Access
Luca Massaro, Jia Zheng, Cristiana Margarita, Pher G. Andersson
In the asymmetric hydrogenation of olefins the enantiodivergent outcome is predominant. However, the less common enantioconvergent phenomenon affords significant practical advantages, such as the possibility to hydrogenate mixtures of E/Z alkenes.
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hydrogen

[ASAP] New Chiral Hydrogen-Bonded Organic Framework Based on Substituted Diarylacetylene Dicarboxylic Acid

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Published On :: Fri, 01 May 2020 04:00:00 GMT

Crystal Growth & Design
DOI: 10.1021/acs.cgd.9b01713


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hydrogen

[ASAP] Hydrogen Plasma-Assisted Growth of Gold Nanowires

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Published On :: Fri, 01 May 2020 04:00:00 GMT

Crystal Growth & Design
DOI: 10.1021/acs.cgd.0c00480


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hydrogen

[ASAP] Hydrogen-Bonded Framework Isomers Based on Zr-Metal Organic Cage: Connectivity, Stability, and Porosity

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Published On :: Fri, 08 May 2020 04:00:00 GMT

Crystal Growth & Design
DOI: 10.1021/acs.cgd.0c00407


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hydrogen

[ASAP] Effect of Hydrogen Bonding between Ions of Like Charge on the Boundary Layer Friction of Hydroxy-Functionalized Ionic Liquids

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Published On :: Mon, 04 May 2020 04:00:00 GMT

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.0c00689


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hydrogen

[ASAP] Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis

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Published On :: Wed, 12 Feb 2020 05:00:00 GMT

Chemical Reviews
DOI: 10.1021/acs.chemrev.9b00723


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hydrogen

[ASAP] Hydrogen Evolution Catalyzed by a Metal-Free Corrole: An Experimental and Theoretical Mechanistic Study

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Published On :: Tue, 05 May 2020 04:00:00 GMT

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.9b10957


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hydrogen

[ASAP] Catalytic Dehydrogenation of Ethane over Doped Perovskite via the Mars–van Krevelen Mechanism

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Published On :: Tue, 05 May 2020 04:00:00 GMT

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.0c00138


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hydrogen

[ASAP] Amorphous Catalysis: Machine Learning Driven High-Throughput Screening of Superior Active Site for Hydrogen Evolution Reaction

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Published On :: Tue, 05 May 2020 04:00:00 GMT

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.0c00406


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hydrogen

[ASAP] Ru Nanoparticles Decorated on 2D MoO<sub>2</sub> Nanosheets as Efficient and Durable Electrocatalysts for the Hydrogen Evolution Reaction in a Wide pH Range

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Published On :: Thu, 07 May 2020 04:00:00 GMT

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.0c01117


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hydrogen

[ASAP] Formation and Transport Mechanisms of Hydrogenous Species in Mayenite

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Published On :: Thu, 07 May 2020 04:00:00 GMT

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.0c00988


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hydrogen

Hydrogen bond: a bond for life / Aloys Hüttermann

By library.mit.edu
Published On :: Sun, 22 Sep 2019 08:00:11 EDT

Hayden Library - QP517.H93 H88 2019


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hydrogen

Heterocycles Via Cross Dehydrogenative Coupling: Synthesis and Functionalization / Ananya Srivastava, Chandan K. Jana, editors

By library.mit.edu
Published On :: Sun, 6 Oct 2019 07:44:56 EDT

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hydrogen

Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2020, 7,1845-1850
DOI: 10.1039/C9QI01431D, Research Article
Jonghoon Choi, Yunho Lee
Catalytic hydrogenation of CO2 occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.
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hydrogen

An In situ Raman study of intermediate adsorption engineering by high-index facet control during the hydrogen evolution reaction

By pubs.rsc.org
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Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article
Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO2 nanosheets.
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