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Phosphacycloalkyldiones: synthesis and coordinative behaviour of 6- and 7-member cyclic diketophosphanyls

Dalton Trans., 2020, 49,5482-5492
DOI: 10.1039/D0DT00864H, Paper
Kyle G. Pearce, Vladimir Simenok, Ian R. Crossley
Condensation of glutaryl and adipoyl chlorides with bis(silyl)phosphanes RP(SiMe3)2 (R = Me, nBu, tBu, Ph, Mes) affords the conformationally fluxional phosphacycloalkyldiones (CH2)n(CO)2PR (n = 3, 4); their coordination behaviour is explored.
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Identification of diverse alphacoronaviruses and genomic characterization of a novel Severe Acute Respiratory Syndrome-Like coronavirus from bats in China