dysprosium

Pentagonal-bipyramidal Dysprosium(III) complexes with two apical phosphine oxide ligands and equatorial pentadentate N3O2 Schiff-base ligands: Breakdown of the apical magnetic axiality by strong equatorial crystal field†

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article
Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(LCH3)(Cy3PO)2]ClO4∙CH3CN (1), [Dy(L2(t-Bu))(Ph3PO)2]ClO4∙0.63C2H5OH (2), [Dy(LOCH3)(Ph3PO)2]ClO4∙2H2O (3) including various chelating pentadentate ligands with a [N3O2]2− binding node in the equatorial plane,...
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dysprosium

Copper and dysprosium are critical metals in growth of the German wind energy sector

The German Renewable Energy Sources Act was introduced in 2001 to encourage an increase in renewable energy supply. Since then, supply has increased from 7% (in 2001) to 37% (in 2017. Wind energy is an important part of Germany’s renewable energy production — but deploying sufficient turbines to achieve the climate goals requires a large amount of raw materials, many of which are metals in limited supply. This study found copper and dysprosium to be the most critical of these metals, as they could face future bottlenecks and are essential elements in present and future turbine design.




dysprosium

Synergetic magnetic and luminescence switching via solid state phase transitions of the dysprosium–dianthracene complex

J. Mater. Chem. C, 2020, Advance Article
DOI: 10.1039/D0TC01111H, Paper
Jing-Cui Liu, Xin-Da Huang, Qian Zou, Song-Song Bao, Xi-Zhang Wang, Jing-Yuan Ma, Li-Min Zheng
A dinuclear complex Dy2L2(depma2)Cl2 containing a pre-photodimerized dianthracene phosphonate ligand (depma2) undergoes consecutive two-step structural transformation upon heating depma2, accompanied by a synergetic switching of the photoluminescence and magnetic dynamics.
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dysprosium

The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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