cerium Non-classical electrostriction in calcium-doped cerium oxide ceramics By pubs.rsc.org Published On :: J. Mater. Chem. A, 2024, 12,9173-9183DOI: 10.1039/D3TA07512E, PaperAhsanul Kabir, Victor Buratto Tinti, Simone Santucci, Maxim Varenik, Samuel Griffiths, Sebastian Molin, Igor Lubomirsky, Vincenzo EspositoOxygen-defective metal oxides, e.g., acceptor-doped CeO2, demonstrate exceptionally large electrostrictive responses compared to state-of-the-art electromechanically active ceramic materials.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium A novel cerium-based metal-organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02225D, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiangdi Zeng, Zi Wang, Meng He, Wanpeng Lu, Wenyuan Huang, Bing An, Jiangnan Li, Li Mufan, Ben Spencer, Sarah Day, Floriana Tuna, Eric J L McInnes, Martin Schroder, Sihai YangPhenylacetylene is a detrimental impurity in the polymerisation of styrene, capable of poisoning catalysts even at ppm levels and significantly degrading the quality of polystyrene. The semi-hydrogenation of phenylacetylene to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium A cerium-doped tungsten trioxide-functionalized sensing platform for photoelectrochemical detection of ascorbic acid with high sensitivity By pubs.rsc.org Published On :: Analyst, 2024, 149,5206-5212DOI: 10.1039/D4AN01165A, PaperXueying Zhu, Tikai Liang, Dianping TangA highly efficient photoelectrochemical (PEC) strategy was proposed for the determination of ascorbic acid (AA).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Aluminothermic reduction of CeO2: mechanism of an economical route to aluminum–cerium alloys By pubs.rsc.org Published On :: Mater. Horiz., 2024, Advance ArticleDOI: 10.1039/D4MH00087K, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alfred Amon, Emily E. Moore, Hunter B. Henderson, Jibril Shittu, Martin Kunz, Shane Kastamo, Nikolai Huotari, Adam Loukus, Ryan Ott, David Weiss, Scott K. McCallTime-resolved X-ray diffraction enabled mechanistic insight into the aluminothermic reduction of CeO2. The environmentally friendly process enables a direct route to Al–Ce alloy production and a high-value use for excess Ce from rare earth mining.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2355-2364DOI: 10.1039/D4QI00339J, Research ArticleDexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin XuanTwo gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium A grain-like cerium oxide nanostructure: synthesis and uric acid sensing application By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17794-17802DOI: 10.1039/D4DT02056A, PaperRafiq Ahmad, Sakeena Masrat, Md. Tabish Rehman, Mohamed F. AlAjmi, Shamshad Alam, Prabhash Mishra, Byeong-Il LeeHydrothermally prepared grain-like CeO2 nanostructures were useful for creating a high-performance and non-enzymatic sensor for uric acid detection.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, 14,6513-6523DOI: 10.1039/D4CY00702F, PaperNiladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. JaseerHeteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Bioactivity of cerium dioxide nanoparticles as a function of size and surface features By pubs.rsc.org Published On :: Biomater. Sci., 2024, Advance ArticleDOI: 10.1039/D3BM01900D, PaperVeronika Sarnatskaya, Yuliia Shlapa, Denis Kolesnik, Olexandra Lykhova, Dmytro Klymchuk, Serhii Solopan, Svitlana Lyubchyk, Iuliia Golovynska, Junle Qu, Yurii Stepanov, Anatolii BelousNano-dispersed cerium dioxide is promising for use in medicine due to its unique physicochemical properties, low toxicity, the safety of in vivo usage, active participation in different redox processes occurring in living cells, and its regenerative potential.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Cerium photocatalysis conquers light hydrocarbon chemistry By cen.acs.org Published On :: 29 Jul 2018 12:51:17 +0000 Method turns challenging gaseous alkanes into liquid products Full Article
cerium Cerium containing nanoparticles prepared in non-polar solvent By www.freepatentsonline.com Published On :: Tue, 17 Mar 2015 08:00:00 EDT A method of making cerium-containing metal oxide nanoparticles in non-polar solvent eliminates the need for solvent shifting steps. The direct synthesis method involves: (a) forming a reaction mixture of a source of cerous ion and a carboxylic acid, and optionally, a hydrocarbon solvent; and optionally further comprises a non-cerous metal ion; (b) heating the reaction mixture to oxidize cerous ion to ceric ion; and (c) recovering a nanoparticle of either cerium oxide or a mixed metal oxide comprising cerium. The cerium-containing oxide nanoparticles thus obtained have cubic fluorite crystal structure and a geometric diameter in the range of about 1 nanometer to about 20 nanometers. Dispersions of cerium-containing oxide nanoparticles prepared by this method can be used as a component of a fuel or lubricant additive. Full Article
cerium Oxidative cyclization of thiosemicarbazide: chemo-dosimetric approach for highly selective fluorescence detection of cerium(IV) By feeds.rsc.org Published On :: New J. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0NJ01100B, PaperAhad Shaikh, Pallabi Mukherjee, Sabyasachi Ta, Arun Bhattacharyya, Abhijit Ghosh, Debasis DasA simple thiosemicarbazide based chemodosimeter detects Ce4+ ion through turn-on fluorescence. The sensing mechanism is based on oxidative cyclyzation. The chemodosimeter shows exceptional selectivity for Ce4+ that allows to detect...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes By feeds.rsc.org Published On :: Dalton Trans., 2020, 49,5420-5423DOI: 10.1039/D0DT00842G, CommunicationLuis M. Aguirre Quintana, Ningxin Jiang, John Bacsa, Henry S. La PierreThe synthesis of coinage metal tris(dialkylamido)imidophosphorane complexes is reported, and the use of the silver(I) salt as an oxidative transmetallation reagent for the formation of a cerium(IV) complex is described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium New findings and current controversies in the reaction of ruthenium red and ammonium cerium(IV) nitrate: focus on the precipitated compound By feeds.rsc.org Published On :: Catal. Sci. Technol., 2020, 10,2491-2502DOI: 10.1039/C9CY02499A, PaperBahram Sarvi, Seyedeh Maedeh Hosseini, Bahareh Deljoo, Abdelhamid El-Sawy, Alireza Shirazi Amin, Mark Aindow, Steven L. Suib, Mohammad Mahdi NajafpourDuring water-oxidation reaction in the presence of RuR and CAN, a heterogeneous nano-sized Ru-Ce compound is detected, which is formed by the interaction of [(NH3)5RuORu(NH3)4ORu(NH3)5],6+/7+ nitrate ions, and the products of the reduction of CAN.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cerium Cerium photocatalysis conquers light hydrocarbon chemistry By feedproxy.google.com Published On :: 29 Jul 2018 12:51:17 +0000 Method turns challenging gaseous alkanes into liquid products Full Article