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Financial Toll of Untreated Perinatal Mood and Anxiety Disorders Among 2017 Births in the United States

The authors developed a mathematical model based on a cost-of-illness approach to estimate the impacts of exposure to untreated PMADs on mothers and children.




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COVID-19 Data Primer from Mathematica

Mathematica continues to partner with our clients and groups like the National Association of Health Data Organizations (NAHDO) to respond to the evolving COVID-19 pandemic, particularly in the area of data analytics.




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Effects of Medicaid Expansion on Access, Treatment, and Outcomes for Patients with Acute Myocardial Infarction

Uninsured patients have decreased access to care, lower rates of percutaneous coronary intervention (PCI), and worse outcomes after acute myocardial infarction (AMI).




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Mathematica to Lead Transitional Program Office to Expand Graduate Medical Education in California

The California Health Care Foundation is funding a transitional graduate medical education program office in California to help address physician shortages.




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Challenges and Successes of Pregnancy Assistance Fund Programs Supporting Young Fathers

Since 2010, the Office of Population Affairs (formerly the Office of Adolescent Health) has offered funding to support expectant and parenting youth through the Pregnancy Assistance Fund (PAF).




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Supporting Child Welfare Agencies During COVID-19

Before the COVID-19 pandemic changed our daily lives, resource-constrained child welfare agencies across the country already faced challenges with implementing parts of the new Family First Prevention Services Act (FFPSA) of 2018.




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A COVID-19 Primer: Analyzing Health Care Claims, Administrative Data, and Public Use Files

This primer is designed to help researchers, data scientists, and others who analyze health care claims or administrative data (herein referred to as “claims”) quickly join the effort to better understand, track, and contain COVID-19.




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Oakland’s Sugar-Sweetened Beverage Tax: Impacts on Prices, Purchases and Consumption by Adults and Children (Journal Article)

In this paper, we estimate the impact of the tax on retail prices, product availability, purchases, and child and adult consumption of taxed beverages in Oakland, as well as of potential substitute beverages.




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Collective #595

Variable Fonts Primer * Cannon-es and use-cannon * Faux Code Generator * Learn Box Alignment

Collective #595 was written by Mary Lou and published on Codrops.




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Collective #596

Using Redux with React * Utopia * Midori * Pure CSS Landscape * Why Svelte * Snapfont

Collective #596 was written by Pedro Botelho and published on Codrops.




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Collective #597

Creative Coding Essentials * Accessible SVGs * The CSS Podcast * RedwoodJS * Sketch Dark Mode Plugin

Collective #597 was written by Pedro Botelho and published on Codrops.




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Collective #598

Backstage * Currying in CSS? * ‘CSS X’ * Tabler Icons * Building with Friction

Collective #598 was written by Pedro Botelho and published on Codrops.




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Collective #599

Embracing modern image formats * Emergency Website Kit * Pencil Effect in SVG * Vincent * IMAP API

Collective #599 was written by Pedro Botelho and published on Codrops.




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Collective #600

Fix an overloaded server * New use-cannon features * Ash's Smooth Scroll * Animockup

Collective #600 was written by Pedro Botelho and published on Codrops.




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Collective #601

LCH colors in CSS * Frontend Mentor * Responsive Images the Simple Way * Button?Design * Interactive Timetable

Collective #601 was written by Pedro Botelho and published on Codrops.




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Collective #602

Watched Box * Generative Data Visualization * Writing an Emulator in JavaScript * Stacks * Meanderer

Collective #602 was written by Pedro Botelho and published on Codrops.




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Collective #603

Gallery * Responsive CSS Motion Path * Spacing in CSS * pattern.css * The Cost of JavaScript Frameworks

Collective #603 was written by Pedro Botelho and published on Codrops.




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Collective #604

The Open Web is Dying * Are you using SVG favicons yet? * Immersive Section Transition * Trails * What is a resilient website?

Collective #604 was written by Pedro Botelho and published on Codrops.




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Efficient bifunctional catalysts synthesized from three-dimensional Ni/Fe bimetallic organic frameworks for overall urea electrolysis

Dalton Trans., 2020, 49,5646-5652
DOI: 10.1039/D0DT00605J, Paper
Huizhu Xu, Ke Ye, Kai Zhu, Jinling Yin, Jun Yan, Guiling Wang, Dianxue Cao
MOF-Ni@MOF-Fe–S which has a structure of interwoven and folding nanosheets shows superior electrochemical performance towards urea electrolysis.
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Cage-like silsesquioxanes-based hybrid materials

Dalton Trans., 2020, 49,5396-5405
DOI: 10.1039/D0DT00587H, Perspective
Yajing Du, Hongzhi Liu
This Perspective reviews recent advances in cage-like silsesquioxanes-based hybrid materials, ranging from monomer functionalization and materials preparation to application.
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Phase transition tuning by Fe(III)/Co(III) substitution in switchable cyano-bridged perovskites: (C3H5N2)2[KFexCo1−x(CN)6]

Dalton Trans., 2020, 49,5503-5512
DOI: 10.1039/D0DT00615G, Paper
Magdalena Rok, Marcin Moskwa, Andrzej Pawlukojć, Rafał Janicki, Iga Zuba, Piotr Zieliński, Paweł Sobieszczyk, Grażyna Bator
The single-crystals of mixed (C3H5N2)2[KFexCo1−x(CN)6] crystals, with different ratios of x = 0, 0.29, 0.42, 0.51, 0.63, 0.70, 0.85, and 1, have been grown from aqueous solutions.
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High-efficiency and safe sulfur-doped iron oxides for magnetic resonance imaging-guided photothermal/magnetic hyperthermia therapy

Dalton Trans., 2020, 49,5493-5502
DOI: 10.1039/D0DT00297F, Paper
Guoqiang Guan, Bo Li, Wenlong Zhang, Zhe Cui, Shu-Ang He, Rujia Zou, Xinwu Lu, Junqing Hu
Highly efficient body-clearance sulfur-doped iron oxides were developed for magnetic resonance imaging-guided photo-magnetic hyperthermia therapy.
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Si–C(sp3) bond activation through oxidative addition at a Rh(I) centre

Dalton Trans., 2020, 49,5416-5419
DOI: 10.1039/D0DT00725K, Communication
S. Azpeitia, A. J. Martínez-Martínez, M. A. Garralda, A. S. Weller, M. A. Huertos
Rhodium promoted a fast, quantitative and room temperature Si–CH3 bond activation.
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Enhanced piezoelectric properties of (1 − x)BiFe0.98(Zn0.5Hf0.5)0.02O3-xBaTiO3 ceramics near the morphotropic phase boundary

Dalton Trans., 2020, 49,5573-5580
DOI: 10.1039/C9DT04664J, Paper
Yunjing Shi, Hairui Bai, Fei Yan, Rui Hu, Kaikai Chen, Bo Shen, Jiwei Zhai
The component with the R–T phase coexistence near MPB affords an optimal piezoelectric coefficient (d33) of 130 pC N−1.
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Hierarchical Mo-doped CoP3 interconnected nanosheet arrays on carbon cloth as an efficient bifunctional electrocatalyst for water splitting in an alkaline electrolyte

Dalton Trans., 2020, 49,5563-5572
DOI: 10.1039/D0DT00671H, Paper
Shasha Zhang, Mingjing Guo, Shuyi Song, Ke Zhan, Ya Yan, Junhe Yang, Bin Zhao
Hierarchical Mo-doped CoP3 nanosheet arrays were fabricated on carbon cloth to serve as an efficient and robust bifunctional electrocatalyst for overall water splitting in alkaline media.
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Constructing a tetraphenylethene (TPE) derivative-decorated polyvinyl alcohol (PVA)/lanthanide nanoparticle composite system for tunable luminescence

Dalton Trans., 2020, 49,5539-5546
DOI: 10.1039/D0DT00473A, Paper
Songyang Huang, Jianbin Wu, Jiale Li, Lirong Yu, Xi Wang, Ming Bai
It is found for the first time that TPEBA-modified PVA ligand-coated lanthanide nanoparticles display tunable luminescent properties due to the established energy transfer from the TPE-based ligand (donor) to the lanthanide nanoparticles (acceptor).
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Responsive ruthenium complex probe for phosphorescence and time-gated luminescence detection of bisulfite

Dalton Trans., 2020, 49,5531-5538
DOI: 10.1039/C9DT04614C, Paper
Wenzhu Zhang, Xiuyan Xi, Yong-Lei Wang, Zhongbo Du, Chaolong Liu, Jianping Liu, Bo Song, Jingli Yuan, Run Zhang
We report the design, synthesis, and characterization of a responsive Ru(II) complex probe for background-free time-gated luminescence detection of bisulfite.
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Facile synthesis of porous Co3O4 nanoflakes as an interlayer for high performance lithium–sulfur batteries

Dalton Trans., 2020, 49,5677-5683
DOI: 10.1039/D0DT00429D, Paper
Xiao-Xiao Zheng, Shi-Xi Zhao, Jin-Lin Yang, Yi-Ming Lu, Qi-Long Wu, Xiang-Tian Zeng
Co3O4 nanoflakes were fabricated using oil bath and calcination methods. Lithium–sulfur batteries with Co3O4–super P interlayer exhibited better performance attributed to the synergistic effects of Co3O4–super P.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced photoluminescence and ferro/piezoelectric performance in piezo-luminescent materials with outstanding water resistance and thermal stability

Dalton Trans., 2020, 49,5581-5589
DOI: 10.1039/D0DT00577K, Paper
Chunlin Ma, Xingyu Wang, Weishi Tan, Weiping Zhou, Xiaoxiong Wang, Zhenzhi Cheng, Guibin Chen, Zhangyin Zhai
(1 − x)Na0.5Bi0.5TiO3-xCaTiO3:Sm3+ multifunctional materials were prepared, which exhibit enhanced ferro/piezoelectric performance and photoluminescence, with outstanding water resistance and thermal stability.
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Reversible luminescent humidity chromism of organic–inorganic hybrid PEA2MnBr4 single crystals

Dalton Trans., 2020, 49,5662-5668
DOI: 10.1039/D0DT00514B, Paper
Wanru Gao, Meiying Leng, Zhixiang Hu, Junze Li, Dehui Li, Huan Liu, Liang Gao, Guangda Niu, Jiang Tang
Reversible luminescent humidity chromism was found on PEA2MnBr4 between green emission and pink emission through water adsorption and desorption.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced conductivity and structure stability of BiPO4@void@C/CNT particles for high-performance bismuth-based batteries

Dalton Trans., 2020, 49,5636-5645
DOI: 10.1039/D0DT00480D, Paper
Ping Feng, Shu-Ang He, Zhe Cui, Qian Liu, Rujia Zou
By homogeneously confining Bi nanoparticles in Li3PO4 matrix nanorods, an anode based on BiPO4@void@C/CNT composite exhibits a reversible capacity of ∼347.0 mA h g−1 at a high current density of 1000 mA g−1 after 530 cycles.
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Three metal–organic framework isomers of different pore sizes for selective CO2 adsorption and isomerization studies

Dalton Trans., 2020, 49,5618-5624
DOI: 10.1039/D0DT00793E, Paper
Rui Zhang, Ju-Hua Huang, De-Xian Meng, Fa-Yuan Ge, Li-Fei Wang, Yong-Kai Xu, Xing-Gui Liu, Mei-Mei Meng, Zhen-Zhong Lu, He-Gen Zheng, Wei Huang
Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbazole-based green and blue-BODIPY dyads and triads as donors for bulk heterojunction organic solar cells

Dalton Trans., 2020, 49,5606-5617
DOI: 10.1039/D0DT00637H, Paper
Jian Yang, Charles H. Devillers, Paul Fleurat-Lessard, Hao Jiang, Shifa Wang, Claude P. Gros, Gaurav Gupta, Ganesh D. Sharma, Haijun Xu
Two BODIPY derivatives with one (B2) and two (B3) carbazole moieties were synthesized and applied as electron-donor materials in organic photovoltaic cells (OPV), showing an overall PCE of 6.41% and 7.47%, respectively.
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Bulky bis(aryl)triazenides: just aspiring amidinates? A structural and spectroscopic study

Dalton Trans., 2020, 49,5653-5661
DOI: 10.1039/D0DT00285B, Paper
Matthew R. Gyton, Anthony R. Leverett, Marcus L. Cole, Alasdair I. McKay
The triazenide ligand is compared to the isoelectronic formamidinate with regards donor capacity, coordination chemistry and capacity to stabilise reactive main group species.
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Phosphacycloalkyldiones: synthesis and coordinative behaviour of 6- and 7-member cyclic diketophosphanyls

Dalton Trans., 2020, 49,5482-5492
DOI: 10.1039/D0DT00864H, Paper
Kyle G. Pearce, Vladimir Simenok, Ian R. Crossley
Condensation of glutaryl and adipoyl chlorides with bis(silyl)phosphanes RP(SiMe3)2 (R = Me, nBu, tBu, Ph, Mes) affords the conformationally fluxional phosphacycloalkyldiones (CH2)n(CO)2PR (n = 3, 4); their coordination behaviour is explored.
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Redox active Ni–Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni22−xPd20+x(CO)48]6− (x = 0.62), [Ni29−xPd6+x(CO)42]6− (x = 0.09) and [Ni29+xPd6−x(CO)42]6− (x = 0.27)

Dalton Trans., 2020, 49,5513-5522
DOI: 10.1039/D0DT00337A, Paper
Beatrice Berti, Cristiana Cesari, Cristina Femoni, Tiziana Funaioli, Maria Carmela Iapalucci, Stefano Zacchini
Redox active molecular Ni–Pd alloy nanoclusters were obtained by redox condensation, their total structures and metal distribution were determined by X-ray crystallography, and their electron-sink behavior was ascertained by electrochemical studies.
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Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution

Dalton Trans., 2020, 49,5625-5635
DOI: 10.1039/D0DT00741B, Paper
Ilya V. Chuchelkin, Konstantin N. Gavrilov, Nataliya E. Borisova, Alexander M. Perepukhov, Alexander V. Maximychev, Sergey V. Zheglov, Vladislav K. Gavrilov, Ilya D. Firsin, Vladislav S. Zimarev, Igor S. Mikhel, Victor A. Tafeenko, Elena V. Murashova, Vladimir V. Chernyshev, Nataliya S. Goulioukina
Novel diamidophosphites based on β-hydroxyamides were prepared, and their individual and in situ formed complexes were tested in Pd-mediated allylations.
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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

Dalton Trans., 2020, 49,5420-5423
DOI: 10.1039/D0DT00842G, Communication
Luis M. Aguirre Quintana, Ningxin Jiang, John Bacsa, Henry S. La Pierre
The synthesis of coinage metal tris(dialkylamido)imidophosphorane complexes is reported, and the use of the silver(I) salt as an oxidative transmetallation reagent for the formation of a cerium(IV) complex is described.
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Prediction of ternary fluorooxoborates with coplanar triangular units [BOxF3−x]x− from first-principles

Dalton Trans., 2020, 49,5424-5428
DOI: 10.1039/D0DT00160K, Communication
Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan
From first-principles prediction, we got all the basic structural units of fluorooxoborates, namely, tetrahedral elements [BOxF4−x] (x = 1,2,3) like [BO4] and triangular elements [BOxF3−x] (x = 1,2) like [BO3].
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Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
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Coordination chemistry of [Y(pypa)]− and comparison immuno-PET imaging of [44Sc]Sc- and [86Y]Y-pypa-phenyl-TRC105

Dalton Trans., 2020, 49,5547-5562
DOI: 10.1039/D0DT00437E, Paper
Lily Li, María de Guadalupe Jaraquemada-Peláez, Eduardo Aluicio-Sarduy, Xiaozhu Wang, Todd E. Barnhart, Weibo Cai, Valery Radchenko, Paul Schaffer, Jonathan W. Engle, Chris Orvig
H4pypa was conjugated to an antibody via a newly synthesized H4pypa-phenyl-NCS; promising immuno-PET imaging with 44Sc was demonstrated.
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Trinuclear Mn2+/Zn2+ based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids

Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper
Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
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Hollow-structure engineering of a silicon–carbon anode for ultra-stable lithium-ion batteries

Dalton Trans., 2020, 49,5669-5676
DOI: 10.1039/D0DT00566E, Paper
Hongbin Liu, Yun Chen, Bo Jiang, Yue Zhao, Xiaolin Guo, Tingli Ma
Hollow silicon nanotubes were successfully synthesized in situ on a carbon substrate, which effectively accommodate the volume expansion of silicon and exhibit ultra-stable performance as the anode of lithium-ion batteries.
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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
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Templated syntheses of heterometal tungsten–cobalt–sulfur clusters with different nuclearities

Dalton Trans., 2020, 49,5523-5530
DOI: 10.1039/D0DT00765J, Paper
Jia-Ting Guo, Xu-Dong Chen
A series of heterometal tungsten–cobalt–sulfur clusters with different nuclearities have been synthesized rationally using a chelating template.
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Design and synthesis of photoluminescent active interpenetrating metal–organic frameworks using N-2-aryl-1,2,3-triazole ligands

Dalton Trans., 2020, 49,5429-5433
DOI: 10.1039/D0DT00933D, Communication
Jingyang Li, Ying He, Li Wang, Qinhe Pan, Zhiguang Song, Xiaodong Shi
N-2-aryl-1,2,3-triazole derivatives were synthesized as new ligand systems for the construction of photoluminescent active metal–organic frameworks (MOFs).
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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
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Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial

Dalton Trans., 2020, 49,5722-5729
DOI: 10.1039/D0DT00778A, Paper
Wan Wu, Tiantian Yao, Ye Xiang, Hao Zou, Yi Zhou
Nano-scale MOF composite materials prepared by combining inorganic semiconductors with controllable pore structures and functional active sites for the effective removal of organic dyes will exhibit more excellent adsorption activity.
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Ultrabroadband red luminescence of Mn4+ in MgAl2O4 peaking at 651 nm

Dalton Trans., 2020, 49,5711-5721
DOI: 10.1039/D0DT00931H, Paper
Haipeng Ji, Xinghui Hou, Maxim S. Molokeev, Jumpei Ueda, Setsuhisa Tanabe, Mikhail G. Brik, Zongtao Zhang, Yu Wang, Deliang Chen
Mn4+ 2Eg4A2g transition exhibits thermally robust, ultrabroadband luminescence peaking at 651 nm in MgAl2O4 under λex = 440 nm excitation.
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A bimetallic MOF@graphene oxide composite as an efficient bifunctional oxygen electrocatalyst for rechargeable Zn–air batteries

Dalton Trans., 2020, 49,5730-5735
DOI: 10.1039/D0DT00976H, Paper
Yao Xiao, Beibei Guo, Jing Zhang, Chun Hu, Ruguang Ma, Deyi Wang, Jiacheng Wang
A bimetallic ZnCo-ZIF@graphene oxide (ZnCo-ZIF@GO) composite was synthesized via an in situ growth strategy. As the air cathode of Zn–air batteries, ZnCo-ZIF@GO showed good charge/discharge performance and long-term stability.
The content of this RSS Feed (c) The Royal Society of Chemistry