y NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00347K, Research ArticleZhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping HuiA novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Palladium-catalyzed and ligand-controlled divergent cycloadditions of vinylidenecyclopropane-diesters with para-quinone methides enabled by zwitterionic π-propargyl palladium species By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00368C, Research ArticleJia-Hao Shen, Yong-Jie Long, Min Shi, Yin WeiA palladium-catalyzed and ligand-controlled divergent synthesis of spiro-cyclohexadienones from p-quinone methides and VDCP-diesters was realized via zwitterionic π-propargyl palladium species and the mechanism was clarified by DFT calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Selective nickel-catalyzed disulfuration of alkyl halides with di/trithiosulfonates By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00411F, Research ArticleLulu Liu, Jiaqi Hou, Yingying Ma, Hongwei Wang, Yu Zhong, Fangcan Liang, Luyao Wang, Qingling Wang, Ji-Quan Liu, Wen-Hua Xu, Dianhu ZhuSelective reductive disulfuration of alkyl halides with di/trithiosulfonate reagents was developed through ligand regulation, with key features of broad substrate scope, good tolerance and excellent selectivity to disulfides over trisulfides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00412D, Research ArticleChengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling SongA deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00481G, Research ArticleJia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin LiaoThree typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Iridium-catalyzed asymmetric hydrogenation of 5-hydroxypicolinate pyridinium salts under batch and flow: stereodefined access to cis-configurated hydroxypiperidine esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00322E, Research ArticleZhi Yang, Shangxian Luan, Linxi Wan, Jingxi Chen, Xiaofang Wei, Pei Tang, Fen-Er ChenAn iridium-catalyzed asymmetric hydrogenation of 2-esteryl-5-hydroxypyridinium salts is reported, providing chiral cis-5-hydroxypiperidine-2-carboxylates in excellent yields with high levels of enantioselectivities and diastereoselectivities.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Thiourea as a precatalyst for the electron donor–acceptor complex photoactivation platform of oxime esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00424H, Research ArticleHaichen Mao, Yuting Zhang, Hengrong Cao, Qianqian Shi, Yu Lan, Junbiao Chang, Bo ZhuA novel electron donor–acceptor (EDA) complex catalysis strategy has been developed using thiourea as a precatalyst under blue LED irradiation. Using 2–5 mol% of thiourea, various nitrogen-containing compounds were successfully synthesized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Integrating continuous flow reaction and work-up: chiral amine resolution, separation and purification using a novel coalescing filter system By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Accepted ManuscriptDOI: 10.1039/D4RE00442F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bethan May Rowley, Lisa Alice Thompson, Luke Power, James Daglish, Emma Parks, James Birbeck, Stephen P Marsden, Nikil Kapur, John BlackerTo maximize the benefits of a continuous flow reaction, a continuous work-up is also needed. Herein, we present a process design and novel equipment for a continuous amine resolution reaction,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Upcycling polymethyl methacrylate to methacrylic acid By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Advance ArticleDOI: 10.1039/D4RE00341A, PaperYanfa Zhuang, Nooshin Saadatkhah, Tien-Dat Nguyen, Jacopo De Tommaso, Clive Yi Jie Ng, Chunyu Wang, Abdellah Ajji, Gregory S. PatienceUpcycling PMMA to methacrylic acid rather than methyl methacrylate is a viable economic alternative to treat end-of-life plastic.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y A Hierarchical Surrogate Approach to Biomass Ethanolysis Reaction Kinetic Modelling By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Accepted ManuscriptDOI: 10.1039/D4RE00378K, PaperAilís O'Shea, Conall McNamara, Prajwal Rao, Mícheál Séamus Howard, Mohammad Reza Ghaani, Stephen DooleyThe reaction mechanism and kinetics of the sulfuric acid catalysed ethanolysis of glucose, cellulose, xylan, and corncob was investigated using a combination of experiments and empirical reaction mechanism modelling. The...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Scalable electrified cementitious materials production and recycling By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE03529A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao Kun Lu, Wenxin Zhang, Brianna N. Ruggiero, Linsey C. Seitz, Jiaqi LiOur electrochemical production uses carbon-free rocks, water electrolysis, and CO2 capture/circulation for carbon-neutral/negative cement and green H2, turning cement from the second-largest industrial CO2 emitter to a gigaton-scale CCUS enabler.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Efficient Fully Textured Perovskite Silicon Tandems with Thermally Evaporated Hole Transporting Materials By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4EE03899A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bhushan Kore, Oussama Er-raji, Oliver Fischer, Adrian Callies, Oliver Schultz-Wittmann, Patricia Samia Cerian Schulze, Martin Bivour, Stefaan De Wolf, Stefan W Glunz, Juliane BorchertFully textured perovskite silicon tandem solar cells effectively minimize the reflection losses and are compatible with industrial silicon production lines. To facilitate scalability and industrial deployment of perovskite silicon tandems...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y New treatment option for young women with hormone-sensitive breast cancer By www.cancer.gov Published On :: 2014-06-01 00:00:00.0 A drug used for treating breast cancer, known as exemestane, is more effective than a common breast cancer prevention drug, tamoxifen, in preventing breast cancer recurrence in young women who also receive post-surgical treatment to suppress ovarian function. The combined results of the Tamoxifen and Exemestane Trial and Suppression of Ovarian Function Trial were presented at the 2014 ASCO Annual Meeting in Chicago. Full Article
y Farewell and thank you for the continued partnership, Francois Chollet! By developers.googleblog.com Published On :: Today, we're announcing that Francois Chollet, the creator of Keras and a leading figure in the AI world, is embarking on a new chapter in his career outside of Google. Full Article
y Germany opens doors to skilled Indians amid global visa cuts By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:00:00 +0530 The number of skilled Indian workers in Germany has increased to 1.3 lakh from 23,000 a decade ago Full Article Data
y Stocks that will see action today: November 14, 2024 By www.thehindubusinessline.com Published On :: Thu, 14 Nov 2024 07:39:24 +0530 Buzzing stocks: Tata Power, India Glycols, Hero MotoCorp, BDL, Firstcry, Mamaearth, MTNL, HAL, Nazara Tech, Sobha, Glenmark Pharma, GVK Power, Medi Assist, Grasim, PNB Housing Fin, Samhi Hotels, Inox Green Energy, Varun Beverages, Piccadilly Agro, Full Article Markets
y IIT Kharagpur-led study says tropical rainforests could survive global warming By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:04:06 +0530 The study, published online in the Elsevier journal, was conducted on records of rainforests in sediments from Gujarat’s Vastan coal mines deposited in coastal lagoons around 56 million years ago Full Article Science
y Let's ensure resounding victory together: Rahul Gandhi to Wayanad voters By www.thehindu.com Published On :: Wed, 13 Nov 2024 11:21:33 +0530 ‘She [Priyanka Gandhi Vadra] will be more than just a representative – she will be your sister, your daughter, and your advocate’, says Rahul Gandhi in a post on X on bypoll day Full Article India
y Row over CPI(M) leader E.P. Jayarajan’s yet to be published autobiography By www.thehindu.com Published On :: Wed, 13 Nov 2024 11:26:48 +0530 Jayarajan clarifies that though he is working on an autobiography, it remains unfinished, and no one has been authorised to publish or distribute it Full Article Kerala
y CPI(M) Kerala secretary M.V. Govindan backs E.P. Jayarajan amid autobiography controversy By www.thehindu.com Published On :: Wed, 13 Nov 2024 13:19:33 +0530 Govindan says CPI(M) does not require members to seek prior permission to write a book, though he emphasised that consultation with the party should occur before publication Full Article Kerala
y A.J. Raghavan, former ISRO scientist, passes away By www.thehindu.com Published On :: Wed, 13 Nov 2024 18:03:07 +0530 Full Article Kerala
y E.P. Jayarajan’s ‘autobiography’ row: publishing house remains tight lipped, refuses to clear the air By www.thehindu.com Published On :: Wed, 13 Nov 2024 18:10:43 +0530 Jayarajan claims that circulating excerpts from his ‘autobiography’ are baseless nonsense and asserts that he had not granted publishing rights for his autobiography to any establishment Full Article Kerala
y Wayanad bypoll turns out to be a reunion for landslides survivors By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:19:26 +0530 Their tearful reunion touches many, as they witness the heartbreak of lost connections. We celebrated the previous election, but many who participated then are no longer with us, says a survivor. District administration designated three polling stations for the survivors, two at Neelicappu and one at Meppadi Full Article Kerala
y Wayanad records voter turnout of 64.72% By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:38:01 +0530 Good polling was reported at the landslides-affected region in Chooral Mala and tribes-populated areas in the district. Full Article Kerala
y KFON to depend on Supplyco database to provide Internet connection to BPL families By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:48:24 +0530 Full Article Kerala
y Quiz competition on AI in Karunagapally By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:10:37 +0530 Full Article Kerala
y KHTC looking to resume boating in Anayirankal dam By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:16:03 +0530 Agency, in an affidavit submitted in the Kerala High Court, outlines plans to make boating facility more eco-friendly Full Article Kerala
y Governor lauds army’s service to the people By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:26:58 +0530 Full Article Kerala
y Chelakkara records 72.77% turnout in bypoll By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:27:31 +0530 Full Article Kerala
y PDA will defeat BJP in bypolls, says Akhilesh By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:02:42 +0530 Welcoming the Supreme Court’s direction on bulldozer ‘justice’, the SP chief says from now onwards, the bulldozer will remain parked in garage forever Full Article Uttar Pradesh
y One-fourth of people living with diabetes in India, Lancet study estimates By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:01:53 +0530 Of the 82.8 crore, India's share formed over a quarter (21.2 crore). Another 14.8 crore were in China, while 4.2 crore, 3.6 crore and 2.2 crore lived in the US, Pakistan and Brazil, respectively, the researchers found Full Article India
y Rate cut unlikely even in February, inflation to dip January onwards: SBI research By www.thehindubusinessline.com Published On :: Wed, 13 Nov 2024 09:26:02 +0530 The report adds that inflation is likely to average around 4.8 per cent to 4.9 per cent for financial year 2025, higher than the RBI target of 4.5 per cent Full Article Economy
y Tata Power Renewable Energy unveils 126 MW Omkareshwar floating solar project, setting new global standards By www.thehindubusinessline.com Published On :: Thu, 14 Nov 2024 07:57:01 +0530 With this project, TPREL’s total renewable capacity reaches 10.9 GW, reinforcing its position in India’s journey towards a greener energy future. Full Article Companies
y MRPL honoured for excellence in AI-driven process efficiency By www.thehindubusinessline.com Published On :: Thu, 14 Nov 2024 08:12:26 +0530 The award was presented at the 27th Energy Technology Meet in Bengaluru. Full Article Companies
y Cambodia to deploy over 16,000 security forces for water festival this week By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:26:02 +0530 Full Article
y Africa's elephant population declines by 70 per cent over past 50 years: study By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:34:02 +0530 Full Article
y Africa's policymakers, educators seek ways to end learning poverty on continent By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:38:02 +0530 Full Article
y 2024 on track to be hottest year on record By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:40:01 +0530 Full Article
y Coast Guard Chief S Paramesh calls on India's High Commissioner to Sri Lanka, discusses maritime security By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:04:01 +0530 Full Article
y Canada: Peel Police requests temple body to postpone event amid 'threats' By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:24:02 +0530 Full Article
y India is now Russia's second-largest economic partner, says Denis Manturov at trade session By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:28:02 +0530 Full Article
y Germany to hold snap elections on February 23 as coalition crumbles under economic strain By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:38:02 +0530 Full Article
y India, Russia discuss economic cooperation, facilitating mobility of talent and skills By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:40:02 +0530 Full Article
y Indian Embassy in Kathmandu calls on diaspora to sign-up for Pravasi Bharatiya Divas Convention of January By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:46:03 +0530 Full Article
y WFP seeks fund to help over 1 million food-insecure Kenyans By www.newkerala.com Published On :: Wed, 13 Nov 2024 16:58:02 +0530 Full Article
y Four-day Africa Tech Festival 2024 kicks off in Cape Town By www.newkerala.com Published On :: Wed, 13 Nov 2024 18:00:02 +0530 Full Article
y Government efficiency 'czar' Musk to cut a lot of waste in US govt: Mark Mobius By www.newkerala.com Published On :: Wed, 13 Nov 2024 18:32:02 +0530 Full Article
y Carpet fibres used by Australian researchers to make stronger concrete By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:18:02 +0530 Full Article
y Modi honoured Marathi by giving it classical language status, Amit Shah By www.newkerala.com Published On :: Wed, 13 Nov 2024 19:54:02 +0530 Full Article
y Principal Secretary to PM highlights mitigating risks associated with glacial lakes to ensure safer future By www.newkerala.com Published On :: Wed, 13 Nov 2024 19:56:02 +0530 Full Article