al Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00351A, Research ArticleFei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng ZhuLovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Cr-mediated Photocatalytic Decarboxylative Coupling of alpha-Oxo Acids with Benzylic Pyridinium Salts By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00475B, Research ArticleJia Cao, Yan Liu, Zhixiang Wang, Le LiuHerein, we report the chromium/photoredox dual catalytic synthesis of ketones using α-oxo acids with benzylic pyridinium salts. This reaction proceeded by photocatalytic generation of acyl radical from α-oxo acids and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Concise synthesis of succinimide-fused densely 1,3-cyclohexadienes via Co-catalyzed [2+2+2] cycloaddition of 1,6-diynes and maleimides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00435C, Research ArticleJinhui Cai, Kaili Cen, Ziyi Zhai, Yuan Liu, Jiahao Wei, Mixia Ouyang, Guojun He, Shuyu Huang, Feng ZhaoHerein, we report a new route towards succinimide-fused densely 1,3-cyclohexadienes through the reaction of 1,6-diynes with electron-deficient alkenes under cobalt catalysis. This method shown high efficiency, wide substrate scope, good...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Cobalt-catalysed Csp3–Csp3 cross-coupling of benzyl Katritzky pyridinium salts with Callyl–O electrophiles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00402G, Research ArticleMengyu Gao, Corinne GosminiDifferent allylbenzyl derivatives are synthesized by Co-catalyzed reductive cross-coupling from functionalized benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates in moderate to good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al NBN/BNB-doped phenalenyl homo- and heterodyads: structural uniformity but optoelectronic diversity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00468J, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander S. Scholz, Thomas Froitzheim, Michael Bolte, Hans-Wolfram Lerner, Jan-M. Mewes, Matthias WagnerPhenylene-bridged homo- and heterodyads of NBN- and BNB-phenalenyls were synthesized. The heterodyads show ambipolar redox character and aggregation-induced emission in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00280F, Research ArticleHui Yin, Siqi Jian, Xiujuan Feng, Ming Bao, Xuan ZhangA metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Copper-catalyzed oxidative sulfenylation and alkylation of indolin-2-ones for direct construction of sulfur-substituted quaternary carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00491D, Research ArticleYun-Hao Zhang, Yi-Nuo Wang, Zi-Yu Liu, Si-Han Zheng, Guang-Lin Li, Dexin Feng, Da-Zhen XuA rapid and green one-pot access to S-substituted quaternary carbon centers from commercially available feedstock chemicals has been established, providing complex molecules with high chemoselectivity by the use of air as the terminal oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Base- and metal-free visible-light driven site-selective α-C(sp3)–H functionalization reaction of glycine derivatives with hydroxamic acid derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00425F, Research ArticleShiyun He, Hongying Fan, Xue Zhang, Meiling Ye, Jian Chen, Jinyu Hou, Tianle Huang, Li Guo, Guanghui Lv, Yong WuA visible-light-mediated radical–radical cross-coupling reaction between hydroxamic acid and N-phenyl glycine derivatives under base and metal free conditions is reported. A series of unnatural amino acids and peptides were obtained in good to excellent yields with good chemo-selectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00552J, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier BourissouCycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Photochemical [2 + 2 + 1] annulation of 2-vinyloxy arylalkynes with bromomalonates via energy transfer By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00249K, Research ArticleShuo Tang, Jiupeng Liu, Min Zhang, Dan Wang, Yong Wang, Jingjing Zhao, Pan LiA transition-metal-free, oxidant-free and base-free photochemical [2 + 2 + 1] radical annulation of 2-vinyloxy arylalkynes with bromomalonates has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Catalytic Ortho C-H Methylation and Trideuteromethylation of Arylthianthrenium Salts via the Catellani Strategy By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00506F, Research ArticleChen Chen, Xiao-Xu Zhang, Zi-Yi Wang, Chunjie Ni, Bolin ZhuWe reported a Pd/NBE cooperative catalyzed ortho C−H methylation and trideuteromethylation of arylthianthrenium salts, enabling the efficient synthesis of a wide variety of (trideutero)methylated arenes in moderate to good yields....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Halogen-Bond-Promoted Direct Cross-Coupling of Ethyl 3-bromo-3-alkyl-2,2-difluoropropanoate with Coumarins/Quinolinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00484A, Research ArticleGuoliang Pu, Shi-Yuan Song, Jian Yang, Peng Guo, Jia Jia, Peijun Liu, Xuefei Li, Ping Liu, Chun-Yang HeHerein, we developed a practical method for the direct cross-coupling of ethyl 3-bromo-3-alkyl-2,2-difluoropropanoate with coumarins/quinolinones, leveraging a halogen bond as the pivotal non-covalent interaction. Employing this protocol, a library of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00347K, Research ArticleZhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping HuiA novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Palladium-catalyzed and ligand-controlled divergent cycloadditions of vinylidenecyclopropane-diesters with para-quinone methides enabled by zwitterionic π-propargyl palladium species By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00368C, Research ArticleJia-Hao Shen, Yong-Jie Long, Min Shi, Yin WeiA palladium-catalyzed and ligand-controlled divergent synthesis of spiro-cyclohexadienones from p-quinone methides and VDCP-diesters was realized via zwitterionic π-propargyl palladium species and the mechanism was clarified by DFT calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Selective nickel-catalyzed disulfuration of alkyl halides with di/trithiosulfonates By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00411F, Research ArticleLulu Liu, Jiaqi Hou, Yingying Ma, Hongwei Wang, Yu Zhong, Fangcan Liang, Luyao Wang, Qingling Wang, Ji-Quan Liu, Wen-Hua Xu, Dianhu ZhuSelective reductive disulfuration of alkyl halides with di/trithiosulfonate reagents was developed through ligand regulation, with key features of broad substrate scope, good tolerance and excellent selectivity to disulfides over trisulfides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00481G, Research ArticleJia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin LiaoThree typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Iridium-catalyzed asymmetric hydrogenation of 5-hydroxypicolinate pyridinium salts under batch and flow: stereodefined access to cis-configurated hydroxypiperidine esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00322E, Research ArticleZhi Yang, Shangxian Luan, Linxi Wan, Jingxi Chen, Xiaofang Wei, Pei Tang, Fen-Er ChenAn iridium-catalyzed asymmetric hydrogenation of 2-esteryl-5-hydroxypyridinium salts is reported, providing chiral cis-5-hydroxypiperidine-2-carboxylates in excellent yields with high levels of enantioselectivities and diastereoselectivities.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Thiourea as a precatalyst for the electron donor–acceptor complex photoactivation platform of oxime esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00424H, Research ArticleHaichen Mao, Yuting Zhang, Hengrong Cao, Qianqian Shi, Yu Lan, Junbiao Chang, Bo ZhuA novel electron donor–acceptor (EDA) complex catalysis strategy has been developed using thiourea as a precatalyst under blue LED irradiation. Using 2–5 mol% of thiourea, various nitrogen-containing compounds were successfully synthesized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Integrating continuous flow reaction and work-up: chiral amine resolution, separation and purification using a novel coalescing filter system By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Accepted ManuscriptDOI: 10.1039/D4RE00442F, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bethan May Rowley, Lisa Alice Thompson, Luke Power, James Daglish, Emma Parks, James Birbeck, Stephen P Marsden, Nikil Kapur, John BlackerTo maximize the benefits of a continuous flow reaction, a continuous work-up is also needed. Herein, we present a process design and novel equipment for a continuous amine resolution reaction,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al A Hierarchical Surrogate Approach to Biomass Ethanolysis Reaction Kinetic Modelling By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Accepted ManuscriptDOI: 10.1039/D4RE00378K, PaperAilís O'Shea, Conall McNamara, Prajwal Rao, Mícheál Séamus Howard, Mohammad Reza Ghaani, Stephen DooleyThe reaction mechanism and kinetics of the sulfuric acid catalysed ethanolysis of glucose, cellulose, xylan, and corncob was investigated using a combination of experiments and empirical reaction mechanism modelling. The...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al A self-adsorption molecule passivated interface enables efficient and stable lithium metal batteries By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE02903H, PaperGongxun Lu, Xinru Wu, Miaofei Huang, Mengtian Zhang, Zhihong Piao, Xiongwei Zhong, Chuang Li, Yanze Song, Chengshuai Chang, Kuang Yu, Guangmin ZhouSelf-adsorbing molecules stabilize electrode interfaces and inhibit solvent decomposition to ensure high-voltage stability of lithium metal batteries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Scalable electrified cementitious materials production and recycling By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE03529A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao Kun Lu, Wenxin Zhang, Brianna N. Ruggiero, Linsey C. Seitz, Jiaqi LiOur electrochemical production uses carbon-free rocks, water electrolysis, and CO2 capture/circulation for carbon-neutral/negative cement and green H2, turning cement from the second-largest industrial CO2 emitter to a gigaton-scale CCUS enabler.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Efficient Fully Textured Perovskite Silicon Tandems with Thermally Evaporated Hole Transporting Materials By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4EE03899A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bhushan Kore, Oussama Er-raji, Oliver Fischer, Adrian Callies, Oliver Schultz-Wittmann, Patricia Samia Cerian Schulze, Martin Bivour, Stefaan De Wolf, Stefan W Glunz, Juliane BorchertFully textured perovskite silicon tandem solar cells effectively minimize the reflection losses and are compatible with industrial silicon production lines. To facilitate scalability and industrial deployment of perovskite silicon tandems...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Multifunctional zeolite film enables stable high-voltage operation of LiCoO2 cathode By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4EE04370G, PaperZezhou Lin, Yiran Ying, Zhihang Xu, Gao Chen, Xi Gong, Zehua Wang, Daqin Guan, Leqi Zhao, Mingyang Yang, Ke Fan, Tiancheng Liu, Hao LI, Honglei Zhang, Huangxu Li, Xi Zhang, Ye Zhu, Zhou-Guang Lu, Zongping Shao, Peiyu Hou, Haitao HuangIncreasing upper cut-off voltage is a useful way for enhancing specific capacity of LiCoO2 (LCO) cathode and the energy density of corresponding lithium-ion batteries (LIBs), while the main challenge is...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Contribution of an instructional module incorporating PhET simulations to Rwandan students' knowledge of chemical reactions, acids, and bases through social interactions By pubs.rsc.org Published On :: Chem. Educ. Res. Pract., 2024, Advance ArticleDOI: 10.1039/D4RP00105B, PaperJean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode Mukama, Olivier Habimana, Paulin Manirakiza, Jean Claude Dushimimana, Jean Pierre Alpha Munyaruhengeri, Samia Khan, Elizabeth LakinTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
al Germany opens doors to skilled Indians amid global visa cuts By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:00:00 +0530 The number of skilled Indian workers in Germany has increased to 1.3 lakh from 23,000 a decade ago Full Article Data
al IIT Kharagpur-led study says tropical rainforests could survive global warming By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:04:06 +0530 The study, published online in the Elsevier journal, was conducted on records of rainforests in sediments from Gujarat’s Vastan coal mines deposited in coastal lagoons around 56 million years ago Full Article Science
al CPI(M) Kerala secretary M.V. Govindan backs E.P. Jayarajan amid autobiography controversy By www.thehindu.com Published On :: Wed, 13 Nov 2024 13:19:33 +0530 Govindan says CPI(M) does not require members to seek prior permission to write a book, though he emphasised that consultation with the party should occur before publication Full Article Kerala
al Centre releases ₹266.8 crore under 15th Finance Commission grants for rural local bodies in Kerala By www.thehindu.com Published On :: Wed, 13 Nov 2024 15:53:26 +0530 Allocation represents second instalment of untied grants for 2024-25, and is meant for all eligible district panchayats, block panchayats and gram panchayats in Kerala Full Article Kerala
al Panel to look into ‘disruption’ of Kerala School Sports & Games By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:03:50 +0530 Full Article Kerala
al Meenachil river basin project in for revival By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:21:14 +0530 Full Article Kerala
al Swami AI chatbot to improve Sabarimala pilgrimage experience By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:26:18 +0530 Full Article Kerala
al ‘Sea ranching’ launched off Thiruvananthapuram as follow-up to artificial reef project By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:39:08 +0530 Minister of State for Fisheries George Kurian launches project; 10 lakh pompano, cobia fingerlings to be deposited in 10 selected locations Full Article Kerala
al Waqf Board can initiate criminal proceedings in post-2013 Waqf land encroachment cases By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:00:07 +0530 A Single Judge of the Kerala High Court quashed the proceedings against two people in an alleged pre-2013 land encroachment case on Tuesday by noting that such acts were made punishable only through an amendment to the Waqf Act in 2013, the accused were in possession of the property even before the introduction of the amendment, and no penal acts could be given retrospective operation Full Article Kerala
al Kollam’s first Keralagro outlet inaugurated By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:01:09 +0530 Agricultural products reach Keralagro stores with FSSAI certification and currently over 3,000 value-added products are being manufactured through 10,76 Krishibhavans in the State Full Article Kerala
al Quiz competition on AI in Karunagapally By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:10:37 +0530 Full Article Kerala
al KHTC looking to resume boating in Anayirankal dam By www.thehindu.com Published On :: Wed, 13 Nov 2024 20:16:03 +0530 Agency, in an affidavit submitted in the Kerala High Court, outlines plans to make boating facility more eco-friendly Full Article Kerala
al Tata Power Renewable Energy unveils 126 MW Omkareshwar floating solar project, setting new global standards By www.thehindubusinessline.com Published On :: Thu, 14 Nov 2024 07:57:01 +0530 With this project, TPREL’s total renewable capacity reaches 10.9 GW, reinforcing its position in India’s journey towards a greener energy future. Full Article Companies
al Cambodia to deploy over 16,000 security forces for water festival this week By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:26:02 +0530 Full Article
al Coast Guard Chief S Paramesh calls on India's High Commissioner to Sri Lanka, discusses maritime security By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:04:01 +0530 Full Article
al Alix Didier Fils-Aime sworn in as new Haiti PM, as gunfire hits US flight By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:18:02 +0530 Full Article
al Germany to hold snap elections on February 23 as coalition crumbles under economic strain By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:38:02 +0530 Full Article
al India, Russia discuss economic cooperation, facilitating mobility of talent and skills By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:40:02 +0530 Full Article
al Indian Embassy in Kathmandu calls on diaspora to sign-up for Pravasi Bharatiya Divas Convention of January By www.newkerala.com Published On :: Wed, 13 Nov 2024 13:46:03 +0530 Full Article
al South Africa expects G20 summit to strengthen multilateralism By www.newkerala.com Published On :: Wed, 13 Nov 2024 16:14:01 +0530 Full Article
al S.Korea, US-developed solar coronagraph installed at International Space Station By www.newkerala.com Published On :: Wed, 13 Nov 2024 16:46:02 +0530 Full Article
al Four-day Africa Tech Festival 2024 kicks off in Cape Town By www.newkerala.com Published On :: Wed, 13 Nov 2024 18:00:02 +0530 Full Article
al South Korea, US, Japan to hold 2nd trilateral Freedom Edge exercise this week By www.newkerala.com Published On :: Wed, 13 Nov 2024 18:58:02 +0530 Full Article
al Carpet fibres used by Australian researchers to make stronger concrete By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:18:02 +0530 Full Article
al Modi honoured Marathi by giving it classical language status, Amit Shah By www.newkerala.com Published On :: Wed, 13 Nov 2024 19:54:02 +0530 Full Article
