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Sankalp Diwas rally: VHP vows to defy ban,administration talks tough

By indianexpress.com
Published On :: Tue, 15 Oct 2013 16:29:20 +0000


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Aarushi case: CBI closes arguments; says Talwars mislead agency

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Published On :: Thu, 17 Oct 2013 16:05:59 +0000


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Gangrape victim made to wait for hours in hospital

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Published On :: Sat, 22 Mar 2014 21:22:03 +0000


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Deoband, Jamiat leaders keep off peace talks, Punjab imam to step in

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Published On :: Mon, 28 Jul 2014 19:34:15 +0000


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Twist in Meerut tale: Woman had surgery for ectopic pregnancy, says state DGP

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Published On :: Tue, 05 Aug 2014 20:33:35 +0000


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Muslim religious leaders dismiss ‘love jihad’ talk

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Published On :: Mon, 25 Aug 2014 14:18:43 +0000


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Minor girl gangraped by hospital ward boys in Uttar Pradesh

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Published On :: Sat, 23 May 2015 16:26:49 +0000


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Outstanding Reviewers for Environmental Science: Nano in 2019

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90015J, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Environmental Science: Nano in 2019, as selected by the editorial team for their significant contribution to the journal.
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Critical role of water stability in metal–organic frameworks and advanced modification strategies for the extension of their applicability

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01321K, Critical Review
Botao Liu, Kumar Vikrant, Ki-Hyun Kim, Vanish Kumar, Suresh Kumar Kailasa
Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).
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The adsorption and oxidation of SO2 on MgO surface: experimental and DFT calculation studies

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Environ. Sci.: Nano, 2020, 7,1092-1101
DOI: 10.1039/C9EN01474H, Paper
Honghong Wang, Cheng Zhong, Qingxin Ma, Jinzhu Ma, Hong He
The reaction mechanisms and synergistic effects of NO2/O2 on the heterogeneous oxidation of SO2 to sulfate on a MgO surface.
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Impact of nano-TiO2 on horizontal transfer of resistance genes mediated by filamentous phage transduction

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Environ. Sci.: Nano, 2020, 7,1214-1224
DOI: 10.1039/C9EN01279F, Paper
Xue Han, Peng Lv, Lu-Guang Wang, Fei Long, Xiao-Lin Ma, Chang Liu, Yu-Jie Feng, Ming-Feng Yang, Xiang Xiao
The spread of antibiotic resistance genes (ARGs) in the environment has aroused growing concern for human health and ecological safety.
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Immobilization of mercury by nano-elemental selenium and the underlying mechanisms in hydroponic-cultured garlic plant

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Environ. Sci.: Nano, 2020, 7,1115-1125
DOI: 10.1039/C9EN01294J, Paper
Jiating Zhao, Xujun Liang, Nali Zhu, Liming Wang, Yunyun Li, Yu-Feng Li, Lirong Zheng, Zhiyong Zhang, Yuxi Gao, Zhifang Chai
Naturally and anthropogenic selenium nanoparticles highly work on mercury immobilization and inactivation in aquatic-plant systems.
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Amorphous phosphated titanium oxide with amino and hydroxyl bifunctional groups for highly efficient heavy metal removal

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Environ. Sci.: Nano, 2020, 7,1266-1274
DOI: 10.1039/C9EN01466G, Paper
Peng Wang, Du Sun, Mingxia Deng, Shaoning Zhang, Qingyuan Bi, Wei Zhao, Fuqiang Huang
FAPTO exhibits a low pHzpc value along with abundant amino and hydroxyl bifunctional groups for efficient heavy metal removal from sewage.
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Pd/TiC/Ti electrode with enhanced atomic H* generation, atomic H* adsorption and 2,4-DCBA adsorption for facilitating electrocatalytic hydrodechlorination

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00182A, Paper
Zimo Lou, Zheni Wang, Jiasheng Zhou, Chuchen Zhou, Jiang Xu, Xinhua Xu
Efficient dechlorination of a chlorinated aromatic compound was achieved with the application of a novel Pd/TiC/Ti electrode.
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Efficacy of chitosan/double-stranded RNA polyplex nanoparticles for gene silencing under variable environmental conditions

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00137F, Paper
Stuart S. Lichtenberg, Kanthi Nuti, Jason DeRouchey, Olga V. Tsyusko, Jason M. Unrine
Chitosan/dsRNA polyplex nanoparticles have shown great potential as insect biocontrol agents. Here, we show that polyplex nanoparticles have their gene silencing capacity altered by environmental variables.
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Selective recovery of Cr from electroplating nanosludge via crystal modification and dilute acid leaching

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00196A, Paper
Jiayi Zheng, Jiaxin Lv, Weizhen Liu, Zongren Dai, Huizhong Liao, Hong Deng, Zhang Lin
Amorphous nanosized particles in electroplating sludge are modified for selective extraction of heavy metals.
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Retraction: Mutual effect of Cs(I) and Sr(II) sorption on nano-talc investigated by EXAFS, modeling and theoretical calculations

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90021D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Wencheng Song, Yang Liu, Tasawar Hayat, Ahmed Alsaedi, Yuejie Ai, Virender K. Sharma, Xiangke Wang
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Retraction: Plasma-grafted amidoxime/metal–organic framework composites for the selective sequestration of U(VI)

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90017F, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fengbo Li, Xiaoyu Li, Pu Cui, Yubing Sun
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2019 Best Papers published in the Environmental Science journals of the Royal Society of Chemistry

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90016H, Editorial
Kristopher McNeill, Paige J. Novak, Peter J. Vikesland
The Editors-in-Chief of the Environmental Science journals introduce the Best Papers of 2019.
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A tribo-positive Fe@MoS2 piezocatalyst for durably degradation of tetracycline: Degradation mechanism and toxicity assessment

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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00284D, Paper
Fanqing Meng, wei Ma, Yinglong Wang, Zhaoyou Zhu, zhen chen, gung Lu
The elimination of antibiotics by piezo-catalysis method has recently drawn great attention for its benefits in engineering application. However, the risk assessment of the target antibiotics and its degradation intermediates...
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Sulfidation attenuates the adverse impacts of metallic nanoparticles on anammox from the perspective of chronic exposure

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper
Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
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Environmental fate of sulfidated nZVI particles: the interplay of nanoparticle corrosion and toxicity during aging

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00075B, Paper
Jaroslav Semerád, Jan Filip, Alena Ševců, Miroslav Brumovský, Nhung H. A. Nguyen, Jiří Mikšíček, Tomáš Lederer, Alena Filipová, Jana Boháčková, Tomáš Cajthaml
This work describes an important, environmentally relevant phenomenon of metal nanoparticle aging in relation to the toxicity of nanomaterials; in this case, sulfidated nanoscale zero-valent materials intended for remediation purposes.
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Chalcone single crystals with red emission and photodimerization-triggered hopping behavior: the substituent effect and molecular packing effect

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00404A, Communication
Xinrui He, Jian Zhao, Zeqing Tan, Jiaxin Zhao, Xiao Cheng, Chuanjian Zhou
Chalcone single crystals with distinctively different emission color and photoinduced mechanical response are designed and fabricated via fine-tuning the donor substituents.
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Existence of untypical halogen-involving interactions in crystal packings: a statistical and first-principles study

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CrystEngComm, 2020, 22,2756-2765
DOI: 10.1039/C9CE01885A, Paper
Yaser Balmohammadi, Hamid Reza Khavasi, S. Shahab Naghavi
There is a common perception by the scientific community that a halogen-involving interaction forms when the distance between the donor atom and the acceptor atom is less than the sum of their van der Waals (vdW) radii.
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Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication
Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.
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Lilac flower-shaped ZnCo2O4 electrocatalyst for efficient methanol oxidation and oxygen reduction reactions in an alkaline medium

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CrystEngComm, 2020, 22,2849-2858
DOI: 10.1039/D0CE00024H, Paper
T. V. M. Sreekanth, P. C. Nagajyothi, K. C. Devarayapalli, J. Shim, K. Yoo
A ZnCo2O4 electrocatalyst for the efficient MOR and ORR.
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Defective crystal plane-oriented induced lattice polarization for the photocatalytic enhancement of ZnO

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CrystEngComm, 2020, 22,2709-2717
DOI: 10.1039/C9CE01966A, Paper
Xiaojuan Bai, Boxuan Sun, Xuyu Wang, Tianshuo Zhang, Qiang Hao, Bing-Jie Ni, Ruilong Zong, Ziyang Zhang, Xiaoran Zhang, Haiyan Li
The mechanism of the photocatalytic reaction of defective ZnO systems was determined.
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Stabilization of hydrogen peroxide by hydrogen bonding in the crystal structure of 2-aminobenzimidazole perhydrate

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CrystEngComm, 2020, 22,2866-2872
DOI: 10.1039/D0CE00096E, Paper
Andrei V. Churakov, Dmitry A. Grishanov, Alexander G. Medvedev, Alexey A. Mikhaylov, Mikhail V. Vener, Mger A. Navasardyan, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V. Prikhodchenko
2-Aminobenzimidazole peroxosolvate – the third H2O2 crystalline adduct stabilized with the maximum possible number of hydrogen bonds formed by one hydrogen peroxide molecule.
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Heterobimetallic complexes from 0D clusters to 3D networks based on various polycyanometallates and [Cu(dmpn)2]2+ (dmpn = 2,2-dimethyl-1,3-diaminopropane): synthesis, crystal structures and magnetic properties

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CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper
Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between FeIII/CrI ion and CuII ion.
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Static disorder in a perovskite mixed-valence metal–organic framework

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CrystEngComm, 2020, 22,2859-2865
DOI: 10.1039/D0CE00119H, Paper
Ines E. Collings, Paul J. Saines, Mirko Mikolasek, Tiziana Boffa Ballaran, Michael Hanfland
Effects of A-site and M-site substitutions on the structural properties of perovskite dimethylammonium iron formate.
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New 2D layered structures with direct fluorine–metal bonds: MF(CH3COO) (M: Sr, Ba, Pb)

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CrystEngComm, 2020, 22,2772-2780
DOI: 10.1039/D0CE00287A, Paper
S. Zänker, G. Scholz, M. Heise, F. Emmerling, E. Kemnitz
New coordination polymers with 2D network structures with fluorine directly coordinated to the metal ion were prepared both via mechanochemical synthesis and fluorolytic sol–gel synthesis.
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Machine learning methods to predict the crystallization propensity of small organic molecules

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CrystEngComm, 2020, 22,2817-2826
DOI: 10.1039/D0CE00070A, Paper
Florbela Pereira
Machine learning algorithms were explored for the prediction of the crystallization propensity based on molecular descriptors and fingerprints generated from 2D chemical structures and 3D chemical structures optimized with empirical methods.
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Melting point–solubility–structure correlations in chiral and racemic model cocrystals

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CrystEngComm, 2020, 22,2766-2771
DOI: 10.1039/D0CE00014K, Paper
Ornella E. Y. Kilinkissa, Krishna K. Govender, Nikoletta B. Báthori
Comparison of chiral and racemic binary cocrystals showed that the chiral building block limits the formation of certain intermolecular interactions, decreases the packing efficiency, lowers the melting point and increases aqueous solubility.
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Synthesis of all-silica hollow zeolites by selective demetallation

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CrystEngComm, 2020, 22,2845-2848
DOI: 10.1039/D0CE00263A, Paper
Open Access
Teng Li, Frank Krumeich, Jeroen A. van Bokhoven
Exploiting the protective role of extra-framework aluminum species on the crystal rim, all-silica hollow zeolites are efficiently produced by demetallation.
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Supramolecular association of M2+⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication
Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, Pt2+; L2 = dinaphthoylmethanido−), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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Mesoporogen-free synthesis of hierarchical HZSM-5 for LDPE catalytic cracking

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00255K, Paper
Yunhao Zang, Jinying Wang, Jianfeng Gu, Jiangying Qu, Feng Gao
Herein, a mesoporogen-free, and steam-assisted route is proposed to synthesize highly crystalline hierarchical HZSM-5 using Stöber silica spheres as the precursor. The effect of crystallization time on the morphology and...
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A water-stable terbium metal-organic framework with functionalized ligands for the detection of Fe3+, Cr2O72- ions in water and picric acid in seawater

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00430H, Paper
Hai-Huan Yu, Jia-Qi Chi, Zhong-Min Su, Xiao Li, Jing Sun, Chen Zhou, Xiao-Li Hu, Qun Liu
The existence of Cr2O72- anions, excessive Fe3+ cations in water and picric acid in seawater have irreversible harm to human health and aquatic organism. Herein, a water-stable terbium metal-organic framework...
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Freezing-induced silk I crystallization of silk fibroin

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00360C, Paper
Xiufang Li, Qunmei Fan, Qiang Zhang, Shuqin Yan, Renchuan You
Thermal annealing strongly impacts the crystallization of proteins. Despite the fundamental importance for the crystallization of silk fibroin, the underlying crystallization kinetics of silk fibroin in freezing state has not...
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Crystal nucleation of salicylamide and a comparison with salicylic acid

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00168F, Paper
Shubhangi Kakkar, K. Renuka Devi, Michael Svärd, Åke Rasmuson
Nucleation behaviour of salicylamide in different solvents was determined and compared with salicylic acid, attempting to progress the rationalization of the influence of the solvent and solute on crystal nucleation of organic compounds in solution.
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A digital workflow from crystallographic structure to single crystal particle attributes for predicting the formulation properties of terbutaline sulfate

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00026D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thai T. H. Nguyen, Robert B. Hammond, Ioanna D. Styliari, Darragh Murnane, Kevin J. Roberts
A detailed inter-molecular (synthonic) analysis of terbutaline sulfate, an ionic addition salt for inhalation drug formulation, is related to its crystal morphology, the surface chemistry of the habit faces and hence to its crystal surface energy.
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The effect of deuteration-levels in solution and temperature on the segregation coefficient of deuterium content in rapid-grown K(DxH1-x)2PO4 crystals using Raman spectroscopy

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00386G, Paper
Jinxin Huang, Zongqi Wang, Bing Teng, Hong Liu, Xixi Zheng, Shaohua Ji
A series of K(DxH1-x)2PO4 (DKDP) crystals with different saturating temperature and deuteration levels were grown by point-seed rapid growth method. The correlation between deuterium segregation coefficient and temperature and deuterium...
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Polymorph induced diversity of photomechanical motions of molecular crystals

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00311E, Paper
Lei Gao, Yunhui Hao, Xiunan Zhang, Xin Huang, Ting Wang, Hongxun Hao
Photomechanical motions of the polymorphs of trans-4,4'-azopyridine are distinct under the influence of different molecular packing and intermolecular interactions.
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Substituent effects on the crystallization mechanisms of 7-chloro-4-substituted-quinolines

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00214C, Paper
João P. P. Copetti, Paulo R. S. Salbego, Tainára Orlando, Jéssica M. L. Rosa, Gabriela F. Fiss, João P. G. de Oliveira, Mário L. A. A. Vasconcellos, Nilo Zanatta, Helio G. Bonacorso, Marcos A. P. Martins
The crystallization mechanisms of a series of fourteen 7-chloro-4-substituted-quinolines were proposed based on a retrocrystallization approach using the supramolecular cluster as demarcation.
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Study of the versatility of CuBTC@IL-derived materials for heterogeneous catalysis

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CrystEngComm, 2020, 22,2904-2913
DOI: 10.1039/C9CE01157A, Paper
Edurne S. Larrea, Roberto Fernández de Luis, Arkaitz Fidalgo-Marijuan, Eva M. Maya, Marta Iglesias, Maria I. Arriortua
The versatility of CuBTC (HKUST-1) MOF materials to be functionalized to improve their catalytic activity performance was evaluated. CuBTC@IL catalysts are selective for the cycloaddition of CO2 to epoxides, giving rise to value-added products.
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Cocrystals/salt of 1-naphthaleneacetic acid and utilizing Hirshfeld surface calculations for acid–aminopyrimidine synthons

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CrystEngComm, 2020, 22,2978-2989
DOI: 10.1039/D0CE00106F, Paper
Utsav Garg, Yasser Azim, Aranya Kar, Chullikkattil P. Pradeep
Revisit of acid–aminopyrimidine synthons to explore the robustness in presence of linear hetrotetramer and heterotrimer synthon.
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A new Fourier transformation method for SAXS of polymer lamellar crystals

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CrystEngComm, 2020, 22,3042-3058
DOI: 10.1039/D0CE00157K, Paper
Xiangyang Li, Jianjun Ding, Pujing Chen, Kang Zheng, Lin Chen, Xingyou Tian
The interface distribution function is composed mainly of the self-interference item of the first interface F11, the interference term of the first and the second interfaces F12, and the interference term of the first and the third interfaces F13.
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A three-in-one crystal of mixed sized cucurbit[n]uril homologues

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CrystEngComm, 2020, 22,2900-2903
DOI: 10.1039/D0CE00296H, Communication
Oksana Danylyuk, Volodymyr Sashuk
Crystallization-driven self-assembly of three macrocyclic members of the cucurbit[n]uril family is explained by the cumulative effect of multiple C–H⋯O hydrogen bonds.
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Intrinsically porous molecular building blocks for metal organic frameworks tailored by the bridging effect of counter cations

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CrystEngComm, 2020, 22,2889-2894
DOI: 10.1039/D0CE00397B, Communication
Open Access
Peng Yang, Buthainah Alshankiti, Niveen M. Khashab
Intrinsically porous molecular building blocks are used for the rational design and construction of molecular-level controlled porous materials.
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Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF4–GaPO4–ACl (A = Cs, Rb) phase space

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CrystEngComm, 2020, 22,3020-3032
DOI: 10.1039/D0CE00343C, Paper
Christian A. Juillerat, Vladislav V. Klepov, Mark D. Smith, Hans-Conrad zur Loye
The flux synthesis of a uranium gallophosphate and a uranium gallate, Cs4[UO2Ga2(PO4)4] and Cs2UO2Ga2O5, and 4 uranium phosphates, [Rb2Rb3.93Cl0.93][(UO2)5(PO4)5], Rb11[(UO2)8(PO4)9], Rb7.6[(UO2)8O8.6F0.4(PO4)2], and Rb6[(UO2)5O2(PO4)4], is reported.
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Hydrothermal synthesis and tunable up-conversion white luminescence properties of KSc(MoO4)2:Ln3+ (Ln = Yb, Er, Tm and Ho) crystals

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00253D, Paper
Yini Mao, Li Jiang, Pengfei Xian, Qiongfen Fu, Shanshan Hu, Jun Yang
Pure hexagonal phase KSc(MoO4)2 crystals with a hexagonal block shape were successfully synthesized via a one-step hydrothermal method.
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