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Rapid prototyping of biomaterials: techniques in additive manufacturing / edited by Roger Narayan

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Computational bioengineering and bioinformatics: computer modelling in bioengineering / Nenad Filipovic, editor

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Biofibers and biopolymers for biocomposites: synthesis, characterization and properties / Anish Khan, Sanjay Mavinkere Rangappa, Suchart Siengchin, Abdullah M. Asiri, editors

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Molecular nanomagnets: fundamental understanding / Heike C. Herper, Barbara Brena, Carla Puglia, Sumanta Bhandary, Heiko Wende, Olle Eriksson, Biplab Sanyal

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Unsymmetric 2-phenylpyridine (ppy)-type cyclometalated Ir(III) complexes bearing both 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene and phenylsulfonyl groups for tuning optoelectronic properties and electroluminescence abilities

Inorg. Chem. Front., 2020, 7,1651-1666
DOI: 10.1039/C9QI01388A, Research Article
Yindi Zhang, Xi Chen, Dongdong Song, Daokun Zhong, Xiaolong Yang, Yuanhui Sun, Boao Liu, Guijiang Zhou, Zhaoxin Wu
Unsymmetric Ir(III) complexes with 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene and phenylsulfonyl groups showing high EL efficiencies.
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Highly dispersed redox-active polyoxometalates’ periodic deposition on multi-walled carbon nanotubes for boosting electrocatalytic triiodide reduction in dye-sensitized solar cells

Inorg. Chem. Front., 2020, 7,1676-1684
DOI: 10.1039/C9QI01486A, Research Article
Ting Wang, Ming Xu, Xiaohong Li, Chunlei Wang, Weilin Chen
Highly dispersed POM nanoparticles as functional components have been deposited on CNTs to produce periodic functionalized CNTs. The obtained Co4PW9/CNTs CE exhibits the best photovoltaic performance with a PCE of 7.60%, higher than both pure CNTs and Pt CE.
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Semi-sacrificial template synthesis of single-atom Ni sites supported on hollow carbon nanospheres for efficient and stable electrochemical CO2 reduction

Inorg. Chem. Front., 2020, 7,1719-1725
DOI: 10.1039/C9QI01688K, Research Article
Cheng-Zong Yuan, Li-Yuan Zhan, Shou-Jie Liu, Feng Chen, Hongjun Lin, Xi-Lin Wu, Jianrong Chen
Atomically dispersed Ni species on nitrogen-doped hollow carbon spheres (SA-Ni/N-CS) were synthesized via a semi-sacrificial template assisted strategy for an efficient and stable CO2RR.
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Arranging strategies for A-site cations: impact on the stability and carrier migration of hybrid perovskite materials

Inorg. Chem. Front., 2020, 7,1741-1749
DOI: 10.1039/D0QI00102C, Research Article
Wei Jian, Ran Jia, Hong-Xing Zhang, Fu-Quan Bai
An essential understanding is obtained from the cation engineering process into the expected excited-state properties of hybrid perovskite materials.
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The effects of Zr-doping on improving the sensitivity and selectivity of a one-dimensional α-MoO3-based xylene gas sensor

Inorg. Chem. Front., 2020, 7,1704-1712
DOI: 10.1039/D0QI00019A, Research Article
Xin Li, Dingsheng Jiang, Yizhuo Fan, Nan Zhang, Caixia Liu, Samira Adimi, Jingran Zhou, Shanpeng Wen, Shengping Ruan
One dimensional Zr-doped α-MoO3 nanobelts were synthesized, and the influence of Zr doping on xylene sensing properties was studied.
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Anisotropic proton conduction realized by a layered vanadium selenite single crystal

Inorg. Chem. Front., 2020, 7,1699-1703
DOI: 10.1039/D0QI00040J, Research Article
Hai-Yan Sun, Shi-Hao Sun, Bing Hu, Liao-Kuo Gong, Yan-Min Zou, Ji-Long Li, Mei-Ling Feng, Xiao-Ying Huang
A new layered vanadium selenite single crystal exhibits anisotropic proton conductivities along the [100] and [001] directions with the Grotthuss and Vehicle mechanisms, respectively.
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High-efficiency photocatalytic water splitting by a N-doped porous g-C3N4 nanosheet polymer photocatalyst derived from urea and N,N-dimethylformamide

Inorg. Chem. Front., 2020, 7,1770-1779
DOI: 10.1039/D0QI00117A, Research Article
Feng Guo, Lijing Wang, Haoran Sun, Mingyang Li, Weilong Shi
N-Doped porous g-C3N4 nanosheets for high-efficiency photocatalytic water splitting were prepared by mixing the precursor of N,N-dimethylformamide and urea through a simple one-step thermal copolymerization method.
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Unraveling the complexation mechanism of actinide(III) and lanthanide(III) with a new tetradentate phenanthroline-derived phosphonate ligand

Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article
Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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[NH2CHNH2]3Sb2I9: a lead-free and low-toxicity organic–inorganic hybrid ferroelectric based on antimony(III) as a potential semiconducting absorber

Inorg. Chem. Front., 2020, 7,1780-1789
DOI: 10.1039/D0QI00137F, Research Article
Przemysław Szklarz, Ryszard Jakubas, Anna Gągor, Grażyna Bator, Jakub Cichos, Mirosław Karbowiak
A novel room-temperature ferroelectric crystal with the complex sequence of phase transitions.
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Enhanced NO2 sensing performance of S-doped biomorphic SnO2 with increased active sites and charge transfer at room temperature

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00119H, Research Article
Wenna Li, Lang He, Xue Bai, Lujia Liu, Muhammad Ikram, He Lv, Mohib Ullah, Mawaz Khan, Kan Kan, Keying Shi
S-Doped biomorphic SnO2 with active S-terminations and S–Sn–O chemical bonds has significantly improved gas sensing performance to NO2 at room temperature.
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Hydrophobic tail length in spin crossover active iron(II) complexes predictably tunes T½ in solution and enables surface immobilisation

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01478K, Research Article
Sriram Sundaresan, Jonathan A. Kitchen, Sally Brooker
Linear correlation of the hydrophobic alkyl tail length R employed in [FeII(LH-OR)(NCBH3)2] with the spin crossover switching temperature is a very convenient method of predictably tuning the iron(II) spin state.
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A sponge-like small pore zeolite with great accessibility to its micropores

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00261E, Research Article
Kok-Giap Haw, Simona Moldovan, Lingxue Tang, Zhengxing Qin, Qianrong Fang, Shilun Qiu, Valentin Valtchev
The accessibility of SSZ-13 is enhanced by having a sponge-like structure after etching under neutral pH conditions.
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A single-ligand-protected Eu60−nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00226G, Research Article
Xi-Ming Luo, Ning-Fang Li, Qing-Fang Lin, Jia-Peng Cao, Peng Yuan, Yan Xu
Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln60. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.
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Unprecedented intramolecular pancake bonding in a {Dy2} single-molecule magnet

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00365D, Research Article
Maykon A. Lemes, Niki Mavragani, Paul Richardson, Yixin Zhang, Bulat Gabidullin, Jaclyn L. Brusso, Jani O. Moilanen, Muralee Murugesu
The first example of unique coordination induced intramolecular pancake bonding was achieved through the reduction of two bis(pyrazolyl)-tetrazine ligands.
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Disentangling Site Occupancy, Cation Regulation, and Oxidation State Regulation of the Broadband Near Infrared Emission in Chromium Doped SrGa4O7 Phosphor

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00332H, Research Article
Jun'an Lai, Jianbei Qiu, Qi Wang, Dacheng Zhou, Zhangwen Long, yong yang, SongHan Hu, Xizheng Li, Jiacheng Pi, Jing Wang
Cr3+-doped phosphors are attracting attention for broadband near-infrared (NIR) applications. However, some mechanisms are still unclear due to the entangled crystallographic site occupancy and changeable valence of chromium in the...
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A slowly magnetic relaxing SmIII monomer with a D5h equatorial compressed ligand field

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00326C, Research Article
Ji-Dong Leng, Qiu-Yan Hua, Li-Shan Lin, Wei-Quan Lin, Jun-Liang Liu, Yong-Ze Pan, Yi-Bo Qiu, Ai-Ju Zhou
By using a bi-dentate phosphine oxide ligand L (L = bis(diphenylphosphino)methane dioxide), two mono-nuclear lanthanide complexes [LnL2(DMF)Cl2]Cl (Ln = Sm, 1; Dy, 2) with a D5h equatorial ligand field (LF)...
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SrTaO2N co-doped with La/Zr as promising photocatalysts for water reduction under visible light illumination

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article
Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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Redox- and Solvato-Magnetic Switching in a Tetrathiafulvalene-Based Triad Single-Molecule Magnet

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00319K, Research Article
Fabrice Pointillart, Jessica Flores-Gonzalez, Vincent Montigaud, Lorenzo Tesi, Vladimir Kuz'mich Cherkasov, Boris Le Guennic, Olivier Cador, Lahcene Ouahab, Roberta Sessoli, Viacheslav Kuropatov
The first simultaneous redox and solvato-magnetic switching was achieved. The dinuclear complex [Dy2(hfac)6(H2SQ)]CH2Cl2 (Dy2H2SQ) (where hfac = 1,1,1,5,5,5-hexafluoroacethylacetonate and H2SQ = 2,2’-benzene-1,4-diylbis(6-hydroxy-4,7-di-tert-butyl-1,3-benzodithiol-2-ylium-5-olate) was reversibly oxidized into the dinuclear complex [Dy2(hfac)6(H2O)2(Q)]...
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Surface-guided polymorphism control of titanyl phthalocyanine single crystals

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00228C, Research Article
Youngkwan Yoon, Jin Young Koo, Jongwon Oh, Soyoung Kim, Hee Cheul Choi, Seok Min Yoon
Polymorphism control of the titanyl-phthalocyanine (TiOPc) single crystals by molecule-surface interactions and their effects of crystallographic structural differences on photo-electronics.
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Ni-Doped magnesium manganese oxide as a cathode and its application in aqueous magnesium-ion batteries with high rate performance

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article
Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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Highly efficient water splitting over a RuO2/F-doped graphene electrocatalyst with ultra-low ruthenium content

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article
Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO2/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm−2 for electrocatalytic water splitting.
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Synthesis of dual emitting iodocuprates: can solvents switch the reaction outcome?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article
Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Enabling high performance n-type metal oxide semiconductors at low temperatures for thin film transistors

Inorg. Chem. Front., 2020, 7,1822-1844
DOI: 10.1039/D0QI00038H, Review Article
Nidhi Tiwari, Amoolya Nirmal, Mohit Rameshchandra Kulkarni, Rohit Abraham John, Nripan Mathews
The review highlights low temperature activation processes for high performance n-type metal oxide semiconductors for TFTs.
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Constructing heterostructured FeS2/CuS nanospheres as high rate performance lithium ion battery anodes

Inorg. Chem. Front., 2020, 7,1900-1908
DOI: 10.1039/C9QI01674K, Research Article
Xiaoxia Xu, Lingjie Li, Huiqing Chen, XiaoSong Guo, Zhonghua Zhang, Jing Liu, Changming Mao, Guicun Li
Heterostructured porous FeS2/CuS nanospheres exhibit enhanced reaction kinetics, excellent rate capability and desirable long-term cycling stability performance.
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An In situ Raman study of intermediate adsorption engineering by high-index facet control during the hydrogen evolution reaction

Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article
Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO2 nanosheets.
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Ligand substitution induced single-crystal-to-single-crystal transformations in two Ni(II) coordination compounds displaying consequential changes in proton conductivity

Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article
Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Coral-like ZnFe2O4–ZnO mesoporous heterojunction architectures: synthesis and enhanced sensing properties for triethylamine

Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article
Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe2O4–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
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Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Restricted active space simulations of the metal L-edge X-ray absorption spectra and resonant inelastic X-ray scattering: revisiting [CoII/III(bpy)3]2+/3+ complexes

Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article
Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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Mitochondrial DNA targeting and impairment by a dinuclear Ir–Pt complex that overcomes cisplatin resistance

Inorg. Chem. Front., 2020, 7,1864-1871
DOI: 10.1039/D0QI00224K, Research Article
Cheng Zhang, Ruilin Guan, Xinxing Liao, Cheng Ouyang, Jiangping Liu, Liangnian Ji, Hui Chao
A dinuclear complex [(ppy)Ir(tpy)PtCl]2+ (Ir–Pt) can exhibit strong antitumor activity towards cisplatin-resistant cancer cells and induce cell necrosis via mtDNA damage and mitochondrial dysfunction.
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π-Type halogen bonding enhanced the long-lasting room temperature phosphorescence of Zn(II) coordination polymers for photoelectron response applications

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article
Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Mechanism of oxygen vacancy assisted water-splitting of LaMnO3: Inorganic perovskite prediction for fast solar thermochemical H2 production

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article
Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Cyclometalated Ir(III) Complexes Towards Blue-Emissive Dopant for Organic Light-Emitting Diodes: Fundamentals of Photophysics and Designing Strategies

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article
Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

1 videodisc (101 min.) : sound, color ; 4 3/4 in




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Roxanne [videorecording] / Columbia Pictures presents a Daniel Melnick Indieprod & LA Films production ; screenplay by Steve Martin ; produced by Michael Rachmil & Daniel Melnick ; directed by Fred Schepisi

1 videodisc (approximately 107 min.) : sound, color ; 4 3/4 in




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Crimson tide [videorecording] / Hollywood Pictures presents a Don Simpson/Jerry Bruckheimer production ; produced by Don Simpson, Jerry Bruckheimer ; story by Michael Schiffer and Richard P. Henrick ; screenplay by Michael Schiffer ; directed by Tony Scot

1 videodisc (116 min.) sound, color; 4 3/4 in




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Professor Marston and the Wonder Women [videorecording]/ Annapurna Pictures presents in association with Stage 6 Films ; a Topple Pictures & Boxspring Entertainment production ; produced by Terry Leonard, Amy Redford ; written and directed by Angela R

1 videodisc (approximately 108 minutes) : sound, color ; 4 3/4 in




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Wonder Woman [videorecording] / directed by Patty Jenkins ; screenplay by Allan Heinberg ; story by Zack Snyder & Allan Heinberg and Jason Fuchs ; produced by Charles Roven, Deborah Snyder, Zack Snyder, Richard Suckle ; a Warner Bros. Pictures present

2 videodiscs (141 min.) : sound, color ; 4 3/4 in




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It's no more just about Real or Barca breaking records: La Liga India head

Jose Antonio Cachaza, MD, LaLiga India, dwells on his team's digital strategy to reach fans in remote villages that even courier companies don't reach




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Will consider raising duties on fuel and liquor: Manpreet Badal, Punjab FM

Punjab would like to help the Centre in any way possible to deal with the coronavirus disease (Covid-19) pandemic, said state Finance Minister Manpreet Singh Badal




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India could use 3-5% of GDP stabilising economy: World Bank economists

The lockdown of economies around the world causes a much sharper decline in economic activity than in normal recessions, says World Bank chief economist south Asia region, Hans Timmer