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The synthesis of tetraarylethylene-based conjugated polymers for the application of fluorescence sensing towards nitroaromatics

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Polym. Chem., 2024, 15,4221-4230
DOI: 10.1039/D4PY00821A, Paper
Rentuya Wu, Xiaosong Sun, Wenyue Dong, Yanwei Li, Qian Duan, Teng Fei
Two tetraarylethylene-based conjugated polymers were synthesized and they exhibit high sensitivity and selectivity towards 2,4,6-trinitrophenol sensing.
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Tetrazine-based inverse-electron-demand Diels–Alder reaction: a powerful tool for fabrication and functionalization of polymeric materials

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Polym. Chem., 2024, 15,4173-4195
DOI: 10.1039/D4PY00912F, Review Article
Open Access
Mehmet Arslan, Aysun Degirmenci, Rana Sanyal, Amitav Sanyal
The IEDDA click reaction plays an important role in the fabrication and functionalization of polymeric materials.
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Vinylene-linked fully conjugated porous organic polymers based on difluoroboron β-diketonate complexes for green and efficient photocatalysis

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Polym. Chem., 2024, 15,4281-4287
DOI: 10.1039/D4PY00947A, Paper
Wenshuo Xu, Zehao Zhao, Yiqiong Liu, Dongxin Yang, Weitao Gong
Two distinct vinylene-linked fully conjugated POPs were achieved by reacting difluoroboron β-diketonate complexes with reactive methyl groups and a carbazole-bearing aldehyde.
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Synthesis of furan-based conjugated polymers with tunable bandgaps via direct C–H arylation of oligofurans

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Polym. Chem., 2024, 15,4339-4348
DOI: 10.1039/D4PY00834K, Paper
Hui Guo, Dayong Jiang, Yufan Gu, Ruixin Wang, Luoyi Wang, Xu-Hui Jin
Using long oligofurans as synthetic building blocks has been found to enable the efficient synthesis of conjugated furan-based polymers through direct C–H arylation, which exhibit excellent antimicrobial activity.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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An efficient and economical degradation strategy for epoxy thermoset based on low cost transesterification catalyst

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01137F, Paper
Zhijun Yang, Shuhan Zhang, Huan Liang, Enjian He, Yixuan Wang, Ting Lei, Zhicheng Wu, Qiulin Chen, Fusheng Zhou, Yen Wei, Yan Ji
Epoxy thermoset materials are widely used in the field of electrical engineering, including gas-insulated enclosed switches and drytype transformers. It is a challenge to degrade and recycle traditional epoxy thermoset,...
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[Ru]-Catalyzed Olefin Metathesis and Ethenolysis for the Synthesis and Recycling of Bio-Based Polycarbonates and Polycyanurates

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00940A, Paper
Dana M. Pinson, Francesca D. Eckstrom, Gregory S. Ostrom, K. Randall McClain, Lawrence Baldwin, Benjamin Grant Harvey
Eugenol, an abundant, naturally occurring phenolic compound, was converted into a thermoplastic polycarbonate by olefin metathesis followed by interfacial polymerization with triphosghene. This resulted in polymers with Mn ranging from...
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Polyols from cashew nut shell liquid (CNSL): corner-stone building blocks for cutting-edge bio-based additives and polymers

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Polym. Chem., 2024, 15,4375-4415
DOI: 10.1039/D4PY00851K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Emilie Rojtman, Maxinne Denis, Camille Sirvent, Vincent Lapinte, Sylvain Caillol, Benoit Briou
From CNSL to polyols.
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Enhanced mechanical properties of acrylate and 5-vinyl-2-norbornene-based ethylene terpolymers: rational design and synthesis using remotely modulated phosphine–sulfonate palladium complexes

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00722K, Paper
Yong-Qing Li, Gui-Ping Cao, Yu-Cai Cao
From a practical perspective, it is important to maintain or increase the mechanical properties of functional ethylene copolymers to those of nonpolar polyethylene (PE).
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Fully Bio-Based Acetal Diepoxy Monomers: High Modulus, Good Thermal Stability and Readily Degradability

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01038H, Paper
Zidie Song, Li Liu, Pengbo Zhang, Kangle Xue, Zibo Hua, Tao You, Yiqi Wu, Hong Cui, Zhen Hu, Yudong Huang
Degradable epoxy resins are designed to address the environmental pollution caused by traditional epoxy resins. However, incorporating the degradability of dynamic covalent bonds in the design of degradable resins often...
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Single-ion quasi-solid-state electrolytes based on sulfonimide-functionalized covalent organic framework

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Polym. Chem., 2024, 15,4529-4541
DOI: 10.1039/D4PY00352G, Paper
Haomin Wu, Wencan Ma, Xin Huang, Yifeng Cai, Junheng Li, Qiaobo Liao, Kai Xi, Qiuhong Zhang, Xudong Jia
The COF based SIQSSEs with a high ionic conductivity of 4.3 × 10−4 S cm−1, a high LTN of 0.90. A high initial capacity (150.3 mA h g−1), high retention (99% after 100 cycles), good cycling stability and rate performance in Li/LFP battery test.
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Catalytic copolymerization of carbon dioxide and cyclohexene oxide by a trinuclear cyclohexane-bridged tetradentate Schiff base chromium complex

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Polym. Chem., 2024, 15,4519-4528
DOI: 10.1039/D4PY00956H, Paper
Jie Huang, Boxiong Shen
The development of catalytic systems is a central area of research in carbon dioxide (CO2) and epoxy copolymerization.
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Backbone editing of oxidized polyethylene: insertion of oxygen and nitrogen atoms via hydroxyalkyl azide-mediated rearrangements

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Polym. Chem., 2024, 15,4554-4561
DOI: 10.1039/D4PY00973H, Paper
Andrew J. King, Ryan P. Sherrier, Jeffrey Aubé, Aleksandr V. Zhukhovitskiy
Hydroxyalkyl azide-mediated rearrangement modularly inserts heteroatoms and pendent functionality into oxidized polyethylene.
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Composition-dependent emission colors for biomass-based main-chain luminescent liquid crystalline copolyesters with excellent tensile properties

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00946K, Paper
Wei Wang, Jing Wang, Wenting Li, Guangjian Liao, Yuan Qiu, Guochuan Yin, Yonggui Liao, Xiaolin Xie
The emission colors of high-performance MCLCPs with biomass-based bifuran and AIE-active cyanostilbene units can be tuned by the composition from blue to cyan, and then to green. Upon UV exposure, the thin film can undergo an emission color change.
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A highly active zinc-based catalyst system for lactide homo- and copolymerization under industrially relevant conditions

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01034E, Paper
Zisheng Zhang, Yi Zhou, Shuang Liu, Baixue Li, Rui Qu, Yanan Gu, Hongyi Suo, Yusheng Qin
A guanidine-based zinc catalyst with a rigid backbone exhibited excellent activity in the ring-opening polymerization and copolymerization of lactide.
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Eugenol-based polyester and its bamboo fiber composite with enhanced mechanical and anti-ultraviolet properties

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00998C, Paper
Meiran Xie, Qiubo Wang, Xinyu Hu, Shuyao Wang, Ruyi Sun, Xiaojuan Liao
Eugenol (UG) is a sustainable allyl-substituted guaiacol that easily becomes the monomers for acyclic diene metathesis (ADMET) polymerization. Nevertheless, the ADMET polymers usually have a moderate molecular weight and poor...
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Dibenzobarrelene-Derived Pd-NHCs: Efficient Precatalysts for the Suzuki-Miyaura Polycondensations of Dichloroarenes Monomers

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01026D, Paper
Yuman Guo, Hao Wu, Meng-Jiao Zhang, Feng-Shou Liu
The Pd-catalyzed Suzuki-Miyaura polycondensations (SMPs) has emerged as a powerful method for synthesizing conjugated polymers (CPs). While numerous reports have utilized dibromoarene and diiodoarene derivatives as monomers, research on the...
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Combined and rapid detection of anti-Brucella IgG/IgM in clinical samples based on surface-enhanced Raman scattering-lateral flow immunochromatography

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J. Mater. Chem. B, 2024, 12,11012-11024
DOI: 10.1039/D4TB01367K, Paper
Yongwei Zhang, Ziyue Li, Aolin Zhu, Qian Zhang, Hao Zhou, Xuelei Zhou, Tingwei Liu, Chunyan Liu, Hefei Zha, Xin Zhang, Hui Zhao, Jiutong Li, Guodong Lü, Xinxia Li
Brucellosis is a bacterial infectious disease caused mainly by Brucella. Transmission is mainly by contact with infected domestic or wild animals or their excreta.
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Crystallization ripening and erosion of calcium oxalate under the effect of bacteria and a polymer materials surface

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J. Mater. Chem. B, 2024, 12,10893-10901
DOI: 10.1039/D4TB01780C, Paper
Xiran Shen, Wentao Chen, Li Guo, Huayu Li, Hong Chen, Fan Liu
New insights into the role of bacteria in pathological biomineralization inspire novel anti-encrustation polymer material design for biomedical use.
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A unimolecular artificial cation channel based on cascaded hydrated acid groups

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J. Mater. Chem. B, 2024, 12,10835-10838
DOI: 10.1039/D4TB01508H, Communication
Pengyang Xin, Hailong Yuan, Long Zhang, Qiuhui Zhu, Xunpeng Ning, Yufei Song, Yuqing Shu, Yonghui Sun
Based on the cascade dehydration concept, an amphiphilic unimolecular cation channel was synthesized by attaching multiple carboxyl groups to both sides of hybrid molecule, resulting in excellent cation transport activity and pH-modulated properties.
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An in situ-activated and chemi-excited photooxygenation system based on G-poly(thioacetal) for Aβ1–42 aggregates

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J. Mater. Chem. B, 2024, 12,10850-10860
DOI: 10.1039/D4TB01147C, Communication
Shasha Liu, Yanping Li, Jinrong Yang, Lei Zhang, Jinwu Yan
BD-6-QM/NPs are chemically activated by H2O2 to produce 1O2, inhibit Aβ1–42 aggregation, promote BV2 phagocytosis of Aβ1–42, and alleviate Aβ1–42-induced neurotoxicity.
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Mitigating intubation stress, mucosa injury, and inflammatory response in nasogastric tube intubation via suppression of the NF-κB signaling pathway by engineering a hydration lubrication coating

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01171F, Paper
Xi Liao, Meng-Han Bai, Yu-Wei Liu, Yu-Qing Wei, Jun-Yang Wang, Zhi-Guo Wang, Rui Hong, Ju-Xiang Gou, Jia-Zhuang Xu, Zhong-Ming Li, Ka Li
The hydrated micelle coating, composed of hyaluronic acid and Pluronic, demonstrated superior hydrophilicity and aqueous lubricity to effectively alleviate mucosal lesions and inflammation caused by NGT insertion.
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Decellularization of caprine forestomach rumen tissue modified with silver nanowires as an antibacterial skin substitute scaffold in wound care therapeutics

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01560F, Paper
Athmana P. A., Asna Jaleel K. I., Sinduja Malarkodi Elangovan, Riza Paul, Naveen Subbaiyan, Parthiban Shanmugam, Gopal Shankar Krishnakumar
Caprine forestomach native collagen (CFNC) modified with silver nanowires (AgNWs) as a new class of biomimetic xenograft for skin regeneration with strong antimicrobial properties.
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Tailored BODIPY-based fluorogenic probes for phosgene detection: a comparative evaluation of recognition sites

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB02040E, Paper
Suay Dartar, Beraat Umur Kaya, Yanki Öncü Yayak, Ezgi Vural, Mustafa Emrullahoğlu
Rare examples of ICT-based fluorescent probes incorporating phosgene specific recognition units at the 2-position of the BODIPY core.
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Long-term leaching kinetics and solution chemistry of aqueous BaTiO3 powder suspensions: a numerical model supported experiment

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01708K, Paper
Marcus Bentzen, Vojtěch Lindauer, Pavel Mokrý, Ragnhild Elizabeth Aune, Julia Glaum
The advent of lead-free perovskite materials with favorable toxicity profiles has made them candidates for in vivo and environmental applications.
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Surface Modified Laser-Induced Graphene based Flexible Biosensor for Multiplexed Sweat Analysis

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01936A, Paper
Sudipta Choudhury, Saad Zafar, Deepak Deepak, Abhishek Panghal, Bimlesh Lochab, Susanta Sinha Roy
The growing popularity of electrochemical sensors featuring non-invasive biosensing technologies has generated significant enthusiasm for continuous monitoring of bodily fluid biomarkers, potentially aiding in the early detection of health issues...
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Efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01987C, Paper
Wan Huang, Song Zhang, Li Luo, Yalong Pan, Lijun Han, Yao Yu
Novel efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy.
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Tuning the affinity of probes with transmembrane proteins by constructing peptide-conjugated cis/trans isomers based on molecular scaffolds

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01801J, Paper
Jing-Jing Hu, Juliang Yang, Yiheng Liu, Guangwen Lu, Zujin Zhao, Fan Xia, Xiaoding Lou
Peptide-conjugated cis/trans isomers were designed. cis-RTP interacts more stably with cell membranes than trans-RTP, and it has shown more excellent properties in inhibiting cell migration and killing cells.
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Electronic band structure modulation for sonodynamic therapy

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01679C, Review Article
Yafang Shi, Chengzhilin Li, Linquan Li, Qingbin He, Qingyi Zhu, Ziang Xu, Yanzi Liu, Nianlei Zhang, Meng Zhang, Jianwei Jiao, Runxiao Zheng
Sonodynamic therapy (SDT) is a burgeoning and newfangled therapy modality with great application potential. Sonosensitizers are most essential factors to ensure the effectiveness of SDT. For the past few years,...
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Evaluation of Alkyl Chain Length and Photocatalytic Antibacterial Performance of Cation g-C3N4

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01118J, Paper
Junling Leng, Xuanwei Liu, Yin Xu, shien zhu, Yuefei Zhang, Zhongbing Tan, Xiaofei Yang, Jia-En Jin, YuFeng Shi, Fan Hongying, Yi Yang, Hang Yao, Yu Zhang, Hui Chong, Chengyin Wang
Several cation graphite carbon nitrides (g-C3N4-(CH2)n-ImI+) were synthesized by chemically attaching imidazolium appended alkane chains with different lengths (n = 2, 4, 8, 12 and 16) to g-C3N4. Introduction of...
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One-pot rapid preparation of long-term antioxidant and antibacterial biomedical gels based on lipoic acid and eugenol for accelerating cutaneous wound healing

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01844C, Paper
Yungang Feng, Fangrui Xie, Rui Ding, Qingrong Zhang, Youzhi Zeng, Li Li, Lianbin Wu, Yunlong Yu, Linxuan Fang
A medical antibacterial gel with long term and high antioxidant activity prepared from eugenol and lipoic acid showed good tissue repair and regeneration for burns and trauma.
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Photoresponsive prodrug-based liposomes for controllable release of the anticancer drug chlorambucil

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01620C, Paper
Xiaoting Wang, Guangtian Suo, Shinan Ma, Chunxi Yang, Chunyan Bao
A photoresponsive lipid prodrug was designed to form nanomedicines for accurate and controllable drug release in response to light irradiation.
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Sodium lanthanide tungstate-based nanoparticles as bimodal contrast agents for in vivo high-field MRI and CT imaging

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J. Mater. Chem. B, 2024, 12,11123-11133
DOI: 10.1039/D4TB01157K, Paper
Open Access
Elisabet Gómez-González, Carlos Caro, Nuria O. Núñez, Daniel González-Mancebo, Jesús D. Urbano-Gámez, Maria L. García-Martín, Manuel Ocaña
NaLn(WO4)2 (Ln = Dy or Ho) nanoparticles functionalized with polyacrylic acid exhibit excellent performance as bimodal contrast agents for high-field MRI and X-ray computed tomography bioimaging and show tumor targeting ability through the EPR effect.
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A near-infrared superoxide generator based on a biocompatible indene-bearing heptamethine cyanine dye

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J. Mater. Chem. B, 2024, 12,11202-11209
DOI: 10.1039/D4TB01663G, Paper
Nikita Bel’ko, Anna Mal’tanova, Anastasiya Bahdanava, Anatol Lugovski, Sviatlana Fatykhava, Polina Shabunya, Adam Smaliakou, Sergey Poznyak, Tatsiana Kulahava, Michael Samtsov
A heptamethine cyanine dye with an indene moiety and 4-meso-chloride generates superoxide inside cells upon near-infrared photoactivation, inducing cell death.
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A guanidiniocarbonyl-pyrrole functionalized cucurbit[7]uril derivative as a cytomembrane disruptor for synergistic antibacterial therapy

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J. Mater. Chem. B, 2024, 12,11105-11109
DOI: 10.1039/D4TB01840K, Communication
Ruixue Han, Kehan Du, Shengke Li, Minzan Zuo, Ponmani Jeyakkumar, Hao Jiang, Leyong Wang, Xiao-Yu Hu
A guanidiniocarbonyl-pyrrole functionalized cucurbit[7]uril derivative as a cytomembrane disruptor has been successfully constructed for synergistic antibacterial therapy.
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Unravelling the molecular mechanobiology by DNA-Based fluorogenic tension sensor

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01858C, Review Article
Kaushik Pal
Investigation of the biological system reveals many underlying principles that govern the regular life processes. Recently, the analysis of tiny mechanical forces associated with many biological processes revels their significance...
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Lactobionic acid modified cobalt coordination polymer-coated peroxymonosulfate nanoparticles generate sulfate/hydroxy dual-radicals for targeted cancer therapy

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01777C, Paper
Jiahui Li, Jiaxuan Li, Zelong Chen, Yichen Wan, Yi Wang, Zhichao Pei, Yuxin Pei
LCP NPs were prepared by forming a coordination polymer on peroxymonosulfate through the coordination between imidazole-2-carboxaldehyde and Co2+, then modified with lactobionic acid to improve the efficacy of sulfate/hydroxy dual-radical therapy.
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Research Progress of Nitroxide Radical-Based MRI Contrast Agents: From Structure Design to Application

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB02272F, Review Article
Tao Luo, Bo Wang, Runxin Chen, Qi Qi, Ruodai Wu, Shunzi Xie, Hanbing Chen, Jialei Han, Dalin Wu, Shuaishuai Cao
Magnetic resonance imaging (MRI) remains a cornerstone of diagnostic imaging, offering unparalleled insights into anatomical structures and pathological conditions. Gadolinium-based contrast agents have long been the standard in MRI enhancement,...
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Nano-Bio Interactions of Gum Arabic-Stabilized Lanthanide-based Upconverting Nanoparticles: In Vitro and In Vivo Study

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01579G, Paper
Hana Mirmajidi, Hyojin Lee, Niepukolie Nipu, Jith Thomas, Zuzana Gajdosechova, David Kennedy, Jan A. Mennigen, Eva Hemmer
Lanthanide-based nanoparticles (Ln-NPs) are highly valued for their unique optical and magnetic properties, making them useful in various scientific fields, including materials science and biomedicine. This study investigated the use...
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Nanoparticles based image-guided thermal therapy and temperature feedback

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01416B, Review Article
Carlos Jacinto, Wagner Ferreira Silva, Joel Garcia, Gelo P. Zaragosa, Carlo Nonato De Jesus Ilem, Tasso O. Sales, Harrison D. A. Santos, Blessed Isaac C. Conde, Helliomar Pereira Barbosa, Sonia Malik, Surender Kumar Sharma
Nanoparticles have emerged as versatile tools in the realm of thermal therapy, offering precise control and feedback mechanisms for targeted treatments. This review explores the intersection of nanotechnology and thermal...
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Development of a Xanthene-Based NIR Fluorescent Probe for Accurate and Sensitive Detection of γ-Glutamyl Transpeptidase in Cancer Diagnosis and Treatment

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01841A, Paper
Chia-Kai Lai, KUPPAN MAGESH, Sivan Velmathi, Shu-Pao Wu
γ-Glutamyl transpeptidase (GGT) regulates glutathione (GSH), essential for cell functions and linked to cancer. High GGT levels in tumors make it a valuable cancer biomarker. Current GGT detection methods often...
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Recent Advances in Polymer-based Thin-film Electrode for ECoG Applications

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB02090A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhengchen Xiang, Liangtao Yang, Bin Yu, Qi Zeng, Tao Huang, Shuo Shi, Hao Yu, Yi Zhang, Jinglong Wu, Meifang Zhu
Electrocorticography (ECoG) has garnered widespread attention due to its superior signal resolution compared to conventional electroencephalogram (EEG). While ECoG signal acquisition entails invasiveness, the invasive rigid electrode inevitably inflicts damage...
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Dual-functional PCN-242 (Fe2Co) MOF for sensitive bacterial endotoxin detection

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01944J, Paper
Sivasankar Kulandaivel, Yung-Kang Lu, Chia-Her Lin, Yi-Chun Yeh
This work introduces a novel bimetallic MOF with superior endotoxin detection and enhanced catalytic activity for broader diagnostic applications.
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NIR emissive probe for fluorescence turn-on based dead cell sorting and in vivo viscosity mapping in C. elegans

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01945H, Paper
Goraksha T. Sapkal, Farhan Anjum, Abdul Salam, Bodhidipra Mukherjee, Shilpa Chandra, Purabi Bala, Richa Garg, Shagun Sharma, Kush Kaushik, Chayan Kanti Nandi
An NIR emissive probe plays a pivotal role for in vitro and in vivo dead cell sorting.
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