Inorg. Chem. Front., 2020, 7,1719-1725
DOI: 10.1039/C9QI01688K, Research Article

Cheng-Zong Yuan, Li-Yuan Zhan, Shou-Jie Liu, Feng Chen, Hongjun Lin, Xi-Lin Wu, Jianrong Chen
Atomically dispersed Ni species on nitrogen-doped hollow carbon spheres (SA-Ni/N-CS) were synthesized via a semi-sacrificial template assisted strategy for an efficient and stable CO₂RR.
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Inorg. Chem. Front., 2020, 7,1750-1761
DOI: 10.1039/C9QI01701A, Research Article

Sadeeq Ullah, Ghulam Yasin, Aftab Ahmad, Lei Qin, Qipeng Yuan, Arif Ullah Khan, Usman Ali Khan, Aziz Ur Rahman, Yassine Slimani
The graphical illustration of the preparation of the SeTe@rGO composite material and its electrochemical application in Li-ion batteries.
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Inorg. Chem. Front., 2020, 7,1704-1712
DOI: 10.1039/D0QI00019A, Research Article

Xin Li, Dingsheng Jiang, Yizhuo Fan, Nan Zhang, Caixia Liu, Samira Adimi, Jingran Zhou, Shanpeng Wen, Shengping Ruan
One dimensional Zr-doped α-MoO₃ nanobelts were synthesized, and the influence of Zr doping on xylene sensing properties was studied.
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Inorg. Chem. Front., 2020, 7,1713-1718
DOI: 10.1039/D0QI00094A, Research Article

Mengyun Ren, Fangfang Chang, Ruifang Miao, Xianhong He, Lin Yang, Xiaolei Wang, Zhengyu Bai
The ability to manipulate Pt-based alloy catalysts with controllable compositions and the type of surface facet is important for advancing direct alcohol fuel cells (DAFEs).
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Inorg. Chem. Front., 2020, 7,1699-1703
DOI: 10.1039/D0QI00040J, Research Article

Hai-Yan Sun, Shi-Hao Sun, Bing Hu, Liao-Kuo Gong, Yan-Min Zou, Ji-Long Li, Mei-Ling Feng, Xiao-Ying Huang
A new layered vanadium selenite single crystal exhibits anisotropic proton conductivities along the [100] and [001] directions with the Grotthuss and Vehicle mechanisms, respectively.
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Inorg. Chem. Front., 2020, 7,1770-1779
DOI: 10.1039/D0QI00117A, Research Article

Feng Guo, Lijing Wang, Haoran Sun, Mingyang Li, Weilong Shi
N-Doped porous g-C₃N₄ nanosheets for high-efficiency photocatalytic water splitting were prepared by mixing the precursor of N,N-dimethylformamide and urea through a simple one-step thermal copolymerization method.
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Inorg. Chem. Front., 2020, 7,1667-1675
DOI: 10.1039/D0QI00099J, Research Article

Weihua Gu, Jing Zheng, Xiaohui Liang, Xiaoqing Cui, Jiabin Chen, Zhu Zhang, Guangbin Ji
Upon introducing Gibbs free energy to effectively control the final products, the as-prepared carbon-based composites show excellent absorbing ability at 1.4 mm.
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Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article

Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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Inorg. Chem. Front., 2020, 7,1780-1789
DOI: 10.1039/D0QI00137F, Research Article

Przemysław Szklarz, Ryszard Jakubas, Anna Gągor, Grażyna Bator, Jakub Cichos, Mirosław Karbowiak
A novel room-temperature ferroelectric crystal with the complex sequence of phase transitions.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00119H, Research Article

Wenna Li, Lang He, Xue Bai, Lujia Liu, Muhammad Ikram, He Lv, Mohib Ullah, Mawaz Khan, Kan Kan, Keying Shi
S-Doped biomorphic SnO₂ with active S-terminations and S–Sn–O chemical bonds has significantly improved gas sensing performance to NO₂ at room temperature.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00184H, Research Article

Su Cheol Han, Woon Bae Park, Kee-Sun Sohn, Myoungho Pyo
A new cathode material (K_0.78Fe_1.60S₂) shows mixed anion/cation redox (Fe(I) ⇆ Fe(II) ⇆ Fe(III) and 2S²⁻ ⇆ S₂²⁻) during charge/discharge for high performance electrodes in potassium ion batteries.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00208A, Research Article

Lei Qiu, Hang Yang, Zhigao Dai, Fengxu Sun, Jiarui Hao, Mengyu Guan, Peipei Dang, Chunjie Yan, Jun Lin, Guogang Li
A highly stable and efficient CsPbBr₃@SiO₂ composite phosphor is achieved by protecting the CsPbBr₃ QDs from direct exposure to the atmosphere by encapsulating CsPbBr₃ into dual-shell hollow silica nanospheres.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01478K, Research Article

Sriram Sundaresan, Jonathan A. Kitchen, Sally Brooker
Linear correlation of the hydrophobic alkyl tail length R employed in [Fe^II(L^H-OR)(NCBH₃)₂] with the spin crossover switching temperature is a very convenient method of predictably tuning the iron(II) spin state.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00023J, Research Article

Yao Yuan, Xiaoyu Chen, Xing Zhang, Zumin Wang, Ranbo Yu
A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00226G, Research Article

Xi-Ming Luo, Ning-Fang Li, Qing-Fang Lin, Jia-Peng Cao, Peng Yuan, Yan Xu
Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln₆₀. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00365D, Research Article

Maykon A. Lemes, Niki Mavragani, Paul Richardson, Yixin Zhang, Bulat Gabidullin, Jaclyn L. Brusso, Jani O. Moilanen, Muralee Murugesu
The first example of unique coordination induced intramolecular pancake bonding was achieved through the reduction of two bis(pyrazolyl)-tetrazine ligands.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00332H, Research Article

Jun'an Lai, Jianbei Qiu, Qi Wang, Dacheng Zhou, Zhangwen Long, yong yang, SongHan Hu, Xizheng Li, Jiacheng Pi, Jing Wang
Cr3+-doped phosphors are attracting attention for broadband near-infrared (NIR) applications. However, some mechanisms are still unclear due to the entangled crystallographic site occupancy and changeable valence of chromium in the...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00326C, Research Article

Ji-Dong Leng, Qiu-Yan Hua, Li-Shan Lin, Wei-Quan Lin, Jun-Liang Liu, Yong-Ze Pan, Yi-Bo Qiu, Ai-Ju Zhou
By using a bi-dentate phosphine oxide ligand L (L = bis(diphenylphosphino)methane dioxide), two mono-nuclear lanthanide complexes [LnL2(DMF)Cl2]Cl (Ln = Sm, 1; Dy, 2) with a D5h equatorial ligand field (LF)...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article

Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00319K, Research Article

Fabrice Pointillart, Jessica Flores-Gonzalez, Vincent Montigaud, Lorenzo Tesi, Vladimir Kuz'mich Cherkasov, Boris Le Guennic, Olivier Cador, Lahcene Ouahab, Roberta Sessoli, Viacheslav Kuropatov
The first simultaneous redox and solvato-magnetic switching was achieved. The dinuclear complex [Dy2(hfac)6(H2SQ)]CH2Cl2 (Dy2H2SQ) (where hfac = 1,1,1,5,5,5-hexafluoroacethylacetonate and H2SQ = 2,2’-benzene-1,4-diylbis(6-hydroxy-4,7-di-tert-butyl-1,3-benzodithiol-2-ylium-5-olate) was reversibly oxidized into the dinuclear complex [Dy2(hfac)6(H2O)2(Q)]...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article

Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO₂ to C₂H₄, and exhibit a maximum Faraday Efficiency 41.3%.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00276C, Research Article

Shuang Lü, Hongli Huang, Ru-Fen Zhang, Chunlin Ma, Qianli Li, Jiao He, Ting Li, jun yang, Yulong Li
In order to enrich the chemistry of the Fe/Te cluster compounds related to the active site of [FeFe]-hydrogenase, the reactions of compound Fe2(μ-TeAr)2(CO)6 with tertiary phosphines were described. Three types...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00228C, Research Article

Youngkwan Yoon, Jin Young Koo, Jongwon Oh, Soyoung Kim, Hee Cheul Choi, Seok Min Yoon
Polymorphism control of the titanyl-phthalocyanine (TiOPc) single crystals by molecule-surface interactions and their effects of crystallographic structural differences on photo-electronics.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article

Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article

Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO₂/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm⁻² for electrocatalytic water splitting.
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Inorg. Chem. Front., 2020, 7,1845-1850
DOI: 10.1039/C9QI01431D, Research Article

Jonghoon Choi, Yunho Lee
Catalytic hydrogenation of CO₂ occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.
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Inorg. Chem. Front., 2020, 7,1900-1908
DOI: 10.1039/C9QI01674K, Research Article

Xiaoxia Xu, Lingjie Li, Huiqing Chen, XiaoSong Guo, Zhonghua Zhang, Jing Liu, Changming Mao, Guicun Li
Heterostructured porous FeS₂/CuS nanospheres exhibit enhanced reaction kinetics, excellent rate capability and desirable long-term cycling stability performance.
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Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article

Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)₄]²⁻ complexes within π-acidic cavities.
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Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article

Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO₂ nanosheets.
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Inorg. Chem. Front., 2020, 7,1872-1879
DOI: 10.1039/D0QI00120A, Research Article

Yue Song, Risheng Bai, Yongcun Zou, Zhaochi Feng, Jihong Yu
A temperature-regulated method was developed to construct anatase-free hierarchical TS-1 zeolite catalysts by utilizing a two-step hydrothermal crystallization strategy with tetrabutylammonium hydroxide as the sole organic template.
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Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article

Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article

Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe₂O₄–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
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Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article

Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl₂ cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl₂ during discharging in acidic AlCl₃-based electrolyte.
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Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article

Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article

Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO₂-philic acylamide groups exhibits high performance for CO₂ capture, separation and chemical conversion.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article

Genlei Zhang, Zhenxi Zhang
Porous Ir₃Pb nanodendrites exhibit excellent activity and superior CO₂ selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article

Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article

Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article

Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo₂S₄ are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article

Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article

Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article

Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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