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Intensivere Drittwirkung : Die mittelbare Drittwirkung der Meinungsfreiheit in Öffentlichkeiten der digitalen Gesellschaft. Eine verfassungsrechtliche, rechtsvergleichende und interdisziplinäre Analyse [Electronic book] / Amélie Heldt.

By encore.st-andrews.ac.uk
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[s.l.] : Mohr Siebeck GmbH & Co. KG, 2023.


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Implementing international environmental agreements in Russia [Electronic book] / Geir Hønneland, Anne-Kristen Jorgensen.

By encore.st-andrews.ac.uk
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Manchester : Manchester University Press, [2018]


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Green Development or Greenwashing? : Environmental Histories of Finland [Electronic book] / Viktor Pál, Tuomas Räsänen.

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[s.l.] : The White Horse Press, 2023.


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Governmentality : current issues and future challenges [Electronic book] / edited by Ulrich Bröckling, Susanne Krasmann and Thomas Lemke.

By encore.st-andrews.ac.uk
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New York : Routledge, 2011.


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Gore capitalism [Electronic book] / Sayak Valencia ; translated by John Pluecker.

By encore.st-andrews.ac.uk
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South Pasadena, California : Semiotexte/Smart Art, [2018]


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Figuras del discurso III : la violencia, el olvido y la memoria [Electronic book] / Armando Villegas Contreras, Natalia Talavera Baby, Roberto Monroy Álvarez, Laksmi A. de Mora Martínez (coordinadores).

By encore.st-andrews.ac.uk
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Ciudad de México : Bonilla Artigas Editores ; Universidad Autónoma del Estado de Morelos, 2020.


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Fathers, Pastors and Kings : Visions of episcopacy in seventeenth-century France [Electronic book] / Alison Forrestal.

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Manchester : Manchester University Press, [2010]


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The fanfiction reader : folk tales for the digital age [Electronic book] / Francesca Coppa.

By encore.st-andrews.ac.uk
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Ann Arbor : University of Michigan Press, [2017]


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Exploring Past Images in a Digital Age : Reinventing the Archive [Electronic book] / Nezih Erdogan, Ebru Kayaalp.

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[s.l.] : Amsterdam University Press, 2023.


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Environmental NGOs in world politics : linking the local and the global [Electronic book] / Thomas Princen and Matthias Finger ; with contributions by Jack P. Manno and Margaret L. Clark.

By encore.st-andrews.ac.uk
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London ; New York : Routledge, 1994.


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Digitale Sachherrschaft [Electronic book] / Konrad Duden.

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[s.l.] : Mohr Siebeck GmbH & Co. KG, 2023.


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Digital places : living with geographic information technologies [Electronic book] / Michael R. Curry.

By encore.st-andrews.ac.uk
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London ; New York : Routledge, 1998.


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CoronAsur : Asian Religions in the Covidian Age [Electronic book] / ed. by Emily Zoe Hertzman, Natalie Lang, Erica M. Larson, Carola E. Lorea.

By encore.st-andrews.ac.uk
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Honolulu : University of Hawaii Press, [2023]


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The code of capital : how the law creates wealth and inequality [Electronic book] / Katharina Pistor.

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Princeton, New Jersey : Princeton University Press, [2019]


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Becoming Global Asia : Contemporary Genres of Postcolonial Capitalism in Singapore [Electronic book] / Cheryl Narumi Naruse.

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Berkeley, CA : University of California Press, [2023]


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Anthropologies of modernity : Foucault, governmentality, and life politics [Electronic book]/ edited by Jonathan Xavier Inda.

By encore.st-andrews.ac.uk
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Malden, MA : Blackwell Publishing, 2005.


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Anglophobia in Fascist Italy [Electronic book] / Jacopo Pili.

By encore.st-andrews.ac.uk
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Manchester : Manchester University Press, [2022]


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All our relations : indigenous trauma in the shadow of colonialism [Electronic book] / Tanya Talaga.

By encore.st-andrews.ac.uk
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Melbourne ; London : Scribe, 2020.


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Orbital optimisation in xTC transcorrelated methods

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00036F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Kats, Evelin Martine Corvid Christlmaier, Thomas Schraivogel, Ali Alavi
We present a combination of the bi-orthogonal orbital optimisation framework with the recently introduced xTC version of transcorrelation. This allows us to implement non-iterative perturbation based methods on top of...
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Enhancement of essential cofactors for in vivo biocatalysis

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00013G, Paper
Pattarawan Intasian, Chalermroj Sutthaphirom, Oliver Bodeit , Duangthip Trisrivirat, Ninlapan Kimprasoot, Juthamas Jaroensuk, Barbara Bakker, Edda Klipp, Pimchai Chaiyen
A scarcity of cofactors, necessary metabolites or substrates for in vivo enzymatic reactions are among the major barriers of product synthesis in metabolically engineered cells. This work compares our recently...
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Mapping inorganic crystal chemical space

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00063C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hyunsoo Park, Anthony Onwuli , Keith Butler, Aron Walsh
The combination of elements from the Periodic Table defines a vast chemical space. Only a small fraction of these combinations yields materials that occur naturally or are accessible synthetically. Here,...
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Stabilization of lithium metal in concentrated electrolytes: effects of electrode potential and solid electrolyte interphase formation

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anusha Pradhan, Shoma Nishimura, Yasuyuki Kondo, Tomoaki Kaneko, Yu Katayama, Keitaro Sodeyama, Yuki Yamada
Lithium (Li) metal negative electrodes have enticed a wide attention for high-energy-density batteries. However, its low Coulombic efficiency (CE) due to parasitic electrolyte reduction has been an alarming concern. Concentrated...
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Computation-guided engineering of distal mutations in an artificial enzyme

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00069B, Paper
Open Access
Fabrizio Casilli, Miquel Canyelles-Niño, Gerard Roelfes, Lur Alonso-Cotchico
Artificial enzymes are valuable biocatalysts able to perform new-to-nature transformations with the precision and (enantio-)selectivity of natural enzymes. Although being highly engineered biocatalysts, they often cannot reach catalytic rates akin...
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MOF-derived Co–Mo bimetallic heterostructures for the selective trapping and conversion of polysulfides in lithium–sulfur batteries

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01249F, Research Article
Rongmei Zhu, Yuxuan Jiang, Bingxin Sun, Wang Zhang, Huan Pang
Hollow CoSx/MoO3 derived from ZIF-67 shows preferred selective trapping and conversion of LiPSs as a modified separator material for LSBs.
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Amorphous MoaZr0.8Ox-500 catalyzed selective oxidation of sulfides to sulfoxides mediated by 1O2 from direct heterolytic cleavage of H2O2

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02008A, Research Article
Tong Li, Jiaheng Qin, Xueyao Zhang, Xiaoqi Tang, Mingzhe Lv, Weiwen Mao, Linkun Dong, Tongtong Fan, Yu Long, Jiantai Ma
Sulfoxides, a class of pharmaceuticals and fine chemicals of significant importance, are readily peroxidized to sulfones in the H2O2 system.
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Strategic pathway selection for photocatalytic degradation: roles of holes and radicals

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01635A, Review Article
Yixuan Li, Xu Gao, Yuxin Li
As global resources become scarce and environmental issues become increasingly severe, developing photocatalytic technology for efficiently and cleanly degrading pollutants has become a research trend.
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Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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Surface oxygen chemistry of metal oxide semiconductor for gas-sensing application

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02385D, Review Article
Jiayu Li, Ertai Na, Xudong Liang, Qihua Liang, Meihong Fan, Hui Chen, Guodong Li, Xiaoxin Zou
With the development of science and technology, the demand for reliable and efficient gas sensors in various applications, ranging from environmental monitoring to industrial safety, is increasing. In particular, MOS...
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Reversible on–off switching of a single-chain magnet via single-crystal-to- single-crystal transition- and light-induced metal-to-metal electron transfer

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01691B, Research Article
Meng-Jia Shang, Han-Han Lu, Qiang Liu, Ren-He Zhou, Hui-Ying Sun, Zhen Shao, Liang Zhao, Yin-Shan Meng, Tao Liu
The development of single-chain magnets with reversible and adjustable properties is of great significance for achieving high-density information storage and switching devices with multi-stimuli responsiveness whilst remains a challenging task....
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Boosted aluminum storage performance by d–p orbital modulation in zinc selenide with manganese element dopants

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02173H, Research Article
Han Wang, Rongkai Kang, Boya Zhang, Xingchang Zhang, Guowen Chen, Yiqun Du, Jianxin Zhang
By modulating the band center, Mn-ion doping strategy enhances electronic conductivity and improves interaction with solvent groups, thereby achieving high capacity, enhanced kinetics, and long-term cycling in rechargeable aluminum batteries.
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A novel cerium-based metal-organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02225D, Research Article
Open Access
Xiangdi Zeng, Zi Wang, Meng He, Wanpeng Lu, Wenyuan Huang, Bing An, Jiangnan Li, Li Mufan, Ben Spencer, Sarah Day, Floriana Tuna, Eric J L McInnes, Martin Schroder, Sihai Yang
Phenylacetylene is a detrimental impurity in the polymerisation of styrene, capable of poisoning catalysts even at ppm levels and significantly degrading the quality of polystyrene. The semi-hydrogenation of phenylacetylene to...
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Strontium doping RuO2 electrocatalyst with abundant oxygen vacancies for boosting OER performance

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02070G, Research Article
Bei An, Xiaoqian Li, Yuan Lin, Fanfan Shang, Huijie He, Hairui Cai, Xiaoxiao Zeng, Weitong Wang, Shengchun Yang, Bin Wang
Oxygen evolution reaction (OER) plays a crucial role as the anode reaction of electrolytic water in various applications. To date, it is still a great challenge to develop highly active...
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Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article
Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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Three-dimensional porous rhodium–copper alloy nanoflowers stereoassembled on Ti3C2Tx MXene as highly-efficient methanol oxidation electrocatalysts

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02182G, Research Article
Haiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie Huang
An in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti3C2Tx lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.
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A highly active and durable NiMoCuCo catalyst with moderated hydroxide adsorption energy for efficient hydrogen evolution reaction

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01947D, Research Article
Hyeonggeun Choi, Seunghwan Jo, Ki Hoon Shin, HeeYoung Lim, Liting Zhang, Keon Beom Lee, Young-Woo Lee, Jung Inn Sohn
A charge valence state and surface-electronegativity-modulated NiMoCuCo composite is proposed as an active and durable alkaline hydrogen evolution reaction electrocatalyst with moderated hydroxide adsorption energy.
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Reconstruction and immobilization of polymolybdate induced by metal-organic coordination units for enhanced electrocatalytic hydrogen generation

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02311K, Research Article
Jingyi Ma, Zhihan Chang, Xue Xi, Juju Liang, Yuchun Lin, Yaling Zhu, Xiuli Wang
Electrocatalytic water cracking for hydrogen evolution has drawn the concern from researchers owing to its high efficiency. Polymolybdate has excellent redox behaviors and O-rich surface, becoming attractive electrocatalytic materials. In...
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Facet-engineered CeO2 with Cu single atom drives photocatalytic selective oxidation of 5-hydroxymethylfurfural

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02230K, Research Article
Yifei Li, Senyao Meng, Ping Wang, Miao He, Jiasai Yao, Cheng Yang, Fangzhou Mo, Jiang Li, Zhenxing Li
The crystal facet of CeO2 is crucial in governing the catalytic performance. However, studies on the relationship between the photocatalytic oxidation performance of CeO2 and its crystal facets are scarce....
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Effects of metal–metal bonding in photosensitizers: red-shifted absorption and oscillator strength enhancement

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Inorg. Chem. Front., 2024, 11,7812-7821
DOI: 10.1039/D4QI02131B, Research Article
Oshan J. Jinarathne, Malkanthi K. Karunananda
Metal–metal bonds facilitate a red-shift in the maximum absorption wavelength and an enhancement of the oscillator strength in photosensitizers.
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Exchange of equatorial ligands in protein-bound paddlewheel Ru25+ complexes: new insights from X-ray crystallography and quantum chemistry

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Inorg. Chem. Front., 2024, 11,7803-7811
DOI: 10.1039/D4QI01846J, Research Article
Open Access
Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
The reactivity of [Ru2Cl(D-p-CNPhF)(O2CCH3)3]n (D-p-CNPhF− = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.
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Al-alkyl borate salt cocatalysts for olefin polymerization: exploration of N-donor ligand variations

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Inorg. Chem. Front., 2024, 11,7872-7885
DOI: 10.1039/D4QI01874E, Research Article
Open Access
Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo Busico
The stability and reactivity of {[iBu2(L)Al]2(μ-H)}+[B(C6F5)4]− (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).
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Atomically precise Ag25(SR)18 nanoclusters: a stable photosensitizer for photocatalysis

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Inorg. Chem. Front., 2024, 11,7991-8002
DOI: 10.1039/D4QI01976H, Research Article
Linjian Zhan, Junyi Zhang, Boyuan Ning, Yunhui He, Guangcan Xiao, Zhixin Chen, Fang-Xing Xiao
Ag25(SR)18 nanocluster is utilized to couple with transition metal chalcogenides for constructing TMC/Ag25(SR)18 heterostructures, which demonstrate boosted photoactivities toward selective organic transformation and heavy metal reduction.
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Selective and catalytic conversion of hydroxymethyl cytosine into formyl cytosine using a synthetic model of TET enzymes

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Inorg. Chem. Front., 2024, 11,7930-7935
DOI: 10.1039/D4QI01965B, Research Article
Dipanwita Palit, Debasish Manna
TET enzymes play a key role in epigenetic regulation by oxidizing 5-methylcytosine, impacting gene expression and DNA methylation. Here, we report a chemical model of the TET enzyme which selectively and catalytically oxidize 5-hydroxymethylcytosine.
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Design of DyIII single-molecule magnets with molecularly installed luminescent thermometers based on bridging [PtII(CN)2(C^N)]− complexes

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Inorg. Chem. Front., 2024, 11,7966-7978
DOI: 10.1039/D4QI02373K, Research Article
Pawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorazy
Dysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.
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Realizing efficient broadband near-infrared emission under blue light excitation in Sb3+-doped zero-dimensional organic tin(IV)-based metal halides via coordination structure modulation

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Inorg. Chem. Front., 2024, 11,7979-7990
DOI: 10.1039/D4QI01904K, Research Article
Bao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou
Here, we report a new NIR emitter of Sb3+-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.
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Towards ultra-sensitive multimodal luminescent thermometers enabled by high crystal field strength of Lu2CaMg2Ge3O12:Yb3+,Nd3+,Er3+ phosphors

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,7955-7965
DOI: 10.1039/D4QI01767F, Research Article
Zhijiao Zhao, Mengmeng Dai, Kejie Li, Guiying Liang, Yanling Wei, Zuoling Fu
An effective full-spectrum thermometer covering from the visible to NIR-II band was designed based on garnet Lu2CaMg2Ge3O12:Yb3+,Er3+/Nd3+ phosphors; meanwhile, Er3+ (4I13/2) split into four Stark sublevels due to high crystal field strength.
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Unusual solvent-regulated inversion of a metal stereocenter in an enantiopure Eu2L4 helicate: a new strategy for CPL inversion

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,8093-8100
DOI: 10.1039/D4QI02276A, Research Article
Qing Ma, Sen Yin, Ziye Song, Ting Gao, Pengfei Yan, Yanyan Zhou, Hongfeng Li
The dinuclear helicate Eu2(LR)4 exhibits a solvent-regulated metal stereocenter Δ/Λ configurational inversion, independent of P/M helical conformational conversion. This reversal process is accompanied by an inversion of the CPL.
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Multicolor luminescence and afterglow from Cs2NaScCl6:Sb3+,Mn2+ crystals

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Inorg. Chem. Front., 2024, 11,8123-8129
DOI: 10.1039/D4QI02019G, Research Article
Xiaojia Wang, Wei Zheng, Xiangzhou Zhang, Xiangxiang Chen, Yuhai Zhang
Cs2NaScCl6 crystals exhibit a pure blue emission originating from self-trapped excitons, which is significantly boosted by Mn2+/Sb3+ doping. The doped crystals shows not only a PL QY up to 62.4% but also a long afterglow after X-ray excitation.
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Coordination tuning of Ni/Fe complex-based electrocatalysts for enhanced oxygen evolution

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Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article
Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)n@CNT materials effectively boost OER catalysis.
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Metal–organic framework micro-nano reactors as armour of Escherichia coli for hydrogen production in air

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Inorg. Chem. Front., 2024, 11,8070-8077
DOI: 10.1039/D4QI02119C, Research Article
Yun Fan, Junyang Yan, Siyao Zhang, Ruifa Su, Baoli Zha, Weina Zhang
The MOF shell of an E. coli@ZIF-8 micro–nano reactor, used as armour for E. coli, not only protects the internal E. coli and improves its survival rate, but also delays the transport of oxygen to enable E. coli to produce hydrogen in air.
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Linker engineering in mixed-ligand metal–organic frameworks for simultaneously enhanced benzene adsorption and benzene/cyclohexane separation

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Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article
Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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