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Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening

Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article
Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Naphthalene diimide-based crystalline hybrid photochromic materials: Structural types, photochromic mechanism, and applications

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02653E, Review Article
Li Li, Jian-Ge Zeng, Ning-Ning Zhang, Yu Yang-Tao, Shu-Hao Li, Yang Hua
The multifunctional stimuli-responsive photochromic materials significantly expand their application fields, including molecular switching, information storage and encryption, detection and sensing, etc. 1,4,5,8-naphthalenediimides (NDIs) have been widely used for the construction...
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A non-equivalent Ni doped La-MOF for enhanced photocatalytic CO2 reduction through oxygen vacancy regulation and electronic structure optimization

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02143F, Research Article
Tongzheng Zhang, Zhaohui Huang, Guanshun Xie, Le Liao, Changqiang Yu, Xiuqiang Xie, Nan Zhang
La/Ni-MOF with oxygen vacancies and regulated electronic structures is prepared and exhibits enhanced visible-light photocatalytic activity for CO2-to-CO conversion.
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Dual-functional Applications of Photochromic BiNbO4: Er3+ Ceramics Based on Reversible Upconversion Luminescence Modulation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02440K, Research Article
ASAD ULLAH, Imran Khan, Yangke Cun, Yue Liu, Zhiguo Song, Jianbei Qiu, Tatiana Grigorievna Cherkasova, Anjun Huang, Asif Ali Haider, Zhengwen Yang
Photochromic luminescent phosphor has attracted considerable attention owing to its excellent optical properties, which face the problem of limited applications. Herein, the reversible photochromic and photo-/thermal bleaching phenomenon of BiNbO4...
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The use of single metal atoms-based photocatalysts for the production of ammonia through photocatalytic nitrogen fixation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article
Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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Deciphering fibroblast-induced drug resistance in non-small cell lung carcinoma through patient-derived organoids in agarose microwells

Lab Chip, 2024, 24,2025-2038
DOI: 10.1039/D3LC01044A, Paper
Qiyue Luan, Ines Pulido, Angelique Isagirre, Julian Carretero, Jian Zhou, Takeshi Shimamura, Ian Papautsky
Agarose microwell platform for modeling lung carcinoma using patient-derived tissues to decipher cancer associated fibroblast-induced drug resistance.
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Droplet microfluidic system for high throughput and passive selection of bacteria producing biosurfactants

Lab Chip, 2024, 24,1947-1956
DOI: 10.1039/D3LC00656E, Paper
Open Access
Klaudia Staskiewicz, Maria Dabrowska-Zawada, Lukasz Kozon, Zofia Olszewska, Lukasz Drewniak, Tomasz S. Kaminski
Novel microfluidic technique for functional selection of biosurfactant-producing microorganisms. Single bacterial cells are encapsulated into picoliter droplets for clonal cultivation and passively sorted at high throughput by interfacial tension.
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Evaluating thrombosis risk and patient-specific treatment strategy using an atherothrombosis-on-chip model

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00131A, Paper
Fahima Akther, Hedieh Fallahi, Jun Zhang, Nam-Trung Nguyen, Hang Thu Ta
An atherothrombosis-on-chip model to evaluate thrombosis risk and patient-specific treatment strategy.
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High-throughput viscoelastic characterization of cells in hyperbolic microchannels

Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC01061A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Felix Reichel, Ruchi Goswami, Salvatore Girardo, Jochen Guck
We use hyperbolic microchannels to create a flow field with linearly increasing velocity, leading to a constant tensile stress to probe the viscoelastic properties of cells. We verify our approach on oil droplets and polyacrylamide beads.
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Screening for Urothelial Carcinoma Cells in Urine Based on Digital Holographic Flow Cytometry through Machine Learning and Deep Learning Method

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC00854A, Paper
Lu Xin, Xi Xiao, Wen Xiao, Ran Peng, Hao Wang, Feng Pan
The incidence of urothelial carcinoma continue to rise annually, particularly among the elderly. Prompt diagnosis and treatment can significantly enhance patient survival and quality of life. Urine cytology remains a...
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High-throughput 3D microfluidic chip for generation of concentration gradients and mixture combinations

Lab Chip, 2024, 24,2280-2286
DOI: 10.1039/D3LC00822C, Paper
Mingwei Zhao, Jing Yang, Zhenqing Li, Yuan Zeng, Chunxian Tao, Bo Dai, Dawei Zhang, Yoshinori Yamaguchi
Concentration gradient generation and mixed combinations of multiple solutions are of great value in the field of biomedical research.
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A cheaper substitute for HRP: ultra-small Cu–Au bimetallic enzyme mimics with infinitesimal steric hindrance to promote catalytic lateral flow immunodetection of clenbuterol

Lab Chip, 2024, 24,2272-2279
DOI: 10.1039/D3LC01079A, Paper
Huilan Hu, Jiaqi Tian, Rui Shu, Huihui Liu, Shaochi Wang, Xuechi Yin, Jianlong Wang, Daohong Zhang
A lateral flow immunoassay (LFIA) is developed for enzyme-catalyzed double-reading determination of clenbuterol (CLE) through the direct electrostatic adsorption of ultra-small copper–gold bimetallic enzyme mimics (USCGs) and monoclonal antibodies.
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Advanced sequencing-based high-throughput and long-read single-cell transcriptome analysis

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00105B, Critical Review
Shanqing Huang, Weixiong Shi, Shiyu Li, Qian Fan, Chaoyong Yang, Jiao Cao, Lingling Wu
Cells are the fundamental building blocks of living systems, exhibiting significant heterogeneity. The transcriptome connects the cellular genotype and phenotype, and profiling single-cell transcriptome is critical for uncovering distinct cell...
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Fabrication of black TiO2 through microwave heating for visible light-driven photocatalytic degradation of rhodamine 6G

React. Chem. Eng., 2024, 9,3003-3015
DOI: 10.1039/D4RE00202D, Paper
Riska Rachmantyo, Afif Akmal Afkauni, Ricky Reinaldo, Lei Zhang, Arramel Arramel, Muhammad Danang Birowosuto, Arie Wibowo, Hermawan Judawisastra
This study shows that a narrower band gap TiO2, namely black TiO2, can be prepared using NaBH4 as a reducing material and microwave heating, which is a faster, greener, and simpler method than the existing method using furnace heating.
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Immobilization of cationic dye on photoluminescent hydroxyapatite particles through a citric acid bonding layer

React. Chem. Eng., 2024, 9,2863-2867
DOI: 10.1039/D4RE00277F, Communication
Daichi Noda, Wanyu Shi, Aiga Yamada, Zizhen Liu, Motohiro Tagaya
Promotion of the immobilization of cationic porphyrin on Eu(III) ion-doped hydroxyapatite nanoparticles through citric acid as the bonding layer was achieved.
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Ammonia Decomposition over Low-loading Ruthenium Catalyst Achieved through “Adiabatic” Plasma Reactor

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper
Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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Pinning–depinning transition of droplets on inclined substrates with a three-dimensional topographical defect

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00081A, Paper
Ninad V. Mhatre, Satish Kumar
The influence of defect geometry on the critical inclination angle required for droplet depinning on inclined substrates is studied.
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Achieving controllable and reversible snap-through in pre-strained strips of liquid crystalline elastomers

Soft Matter, 2024, 20,3256-3270
DOI: 10.1039/D4SM00037D, Paper
Open Access
James T. Waters, Anna C. Balazs
Deformable, elastic materials that buckle in response to external stimuli can display “snap-through”, which involves a transition between different, stable buckled states.
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Interaction between stabilized droplets of different phases in the same continuous phase of an aqueous three-phase system

Soft Matter, 2024, 20,3359-3366
DOI: 10.1039/D3SM01688A, Paper
Do-Nhu-Trang Nguyen, Léa Waldmann, Valérie Ravaine, Taco Nicolai, Lazhar Benyahia
Janus-like droplets, covered with microgel, formed after the fusion of gelatin and dextran droplets in a common poly(ethylene oxide) phase.
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A self-powered photodetector through facile processing using polyethyleneimine/carbon quantum dots for highly sensitive UVC detection

RSC Adv., 2024, 14,12360-12371
DOI: 10.1039/D3RA08538D, Paper
Open Access
Vo Pham Hoang Huy, Chung Wung Bark
Ultraviolet C (UVC) photodetectors have garnered considerable attention because the detection of UVC is critical for preventing skin damage in humans, monitoring environmental conditions, and detecting power aging in military applications.
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Use of benzothiophene ring to improve the photovoltaic efficacy of cyanopyridinone-based organic chromophores: a DFT study

RSC Adv., 2024, 14,12841-12852
DOI: 10.1039/D3RA06817J, Paper
Open Access
Iqra Shafiq, Muhammad Khalid, Gul Maria, Nadeem Raza, Ataualpa A. C. Braga, Saifullah Bullo, Mohamed Khairy
The benzothiophene based chromophores (A1D1–A1D5) with A–π–A configuration were designed via end-capped tailoring with benzothiophene type acceptors using reference compound (A1R).
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Carbon dots–cadmium sulfide quantum dots nanocomposite for ‘on–off’ fluorescence sensing of chromium(VI) ions

RSC Adv., 2024, 14,12923-12934
DOI: 10.1039/D4RA00436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anisha B. Patil, Pooja L. Chaudhary, Parag V. Adhyapak
This work involves fluorescent probe which is composed of carbon dots (CD) and cadmium sulfide quantum dots (CdS QD) for the sensitive and selective fluorescence detection of chromium(VI) ions.
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Dispersive micro solid phase extraction of glibenclamide from plasma, urine, and wastewater using a magnetic molecularly imprinted polymer followed by its determination by a high-performance liquid chromatography-photodiode array detector

RSC Adv., 2024, 14,13168-13179
DOI: 10.1039/D4RA00452C, Paper
Open Access
Najmeh Sabbaghi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani, Majid Farsadrooh
The present study describes the development of a simple and selective analytical method for dispersive micro solid phase extraction and determination of glibenclamide (GLB) using magnetic molecularly imprinted polymer (MMIP) as a sorbent.
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Designing biphenanthridine-based singlet fission materials using computational chemistry

Mol. Syst. Des. Eng., 2024, 9,423-435
DOI: 10.1039/D3ME00181D, Paper
Keighlynn A. Veilleux, Georg Schreckenbach, David E. Herbert
A systematic search for novel singlet fission materials based on the recently synthesized 6,6'-biphenanthridine (biphe) framework is reported, utilizing a straightforward computational approach.
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Augmentation of inductive effects through short range intramolecular hydrogen bonds for the improvement of cooperativity of trimeric rosettes

Mol. Syst. Des. Eng., 2024, 9,345-351
DOI: 10.1039/D4ME00008K, Paper
Andre Nicolai Petelski, Tamara Bundrea, Nélida María Peruchena
Three key design elements improve the binding strength of trimeric rosettes: the direction of hydrogen bonds, the addition of groups with inductive effects, and the presence of ambifunctional intramolecular hydrogen bonds between the substituents.
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Design and engineering of an artificial disulfide bond in human cytochrome c to regulate the protein structure and function

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00196B, Paper
Yan-Yan Li, Yu Feng, Lu Yu, Shuang-Shuang Long, Shu-Qin Gao, Ying-Wu Lin
An artificial disulfide bond was rationally constructed in human cytochrome c (hCyt c) via double mutations (A51C/G77C), which weakened the coordination of Met80 to the heme iron and enhanced the peroxidase activity of hCyt c.
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When ‘Uncle Godhri’ comes calling

A retired school teacher brings colour and comfort to hospital patients by stitching blankets for them




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Three cheers for the ‘cheer pheasant’ project

The village of Seri in Himachal Pradesh is going all out to protect the endangered bird species




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Rejuvenating land through agro-forestry

Telangana cotton farmers take up mango plantation to diversify crops, check soil erosion




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Picking up the threads in Punjab

Project Trinjan has helped resurrect the concept of women’s collectives to revive traditional crafts




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A true digital revolution or ‘exclusion through technology’?

Lack of smartphones and poor connectivity have severely cramped internet outreach in Manipur during the ongoing pandemic




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The CF3TMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes

Polym. Chem., 2024, 15,4312-4318
DOI: 10.1039/D4PY01002G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kim Jiayi Wu, John M. Tobin, Anli Ji, Yang Shi, Chunchun Ye, Gary S. Nichol, Alessio Fuoco, Mariagiulia Longo, Johannes C. Jansen, Neil B. McKeown
The CF3TMS adduct of anthraquinone reacts with diphenyl ether via a superacid-catalysed step-growth polymerisation to give a polymer (BTFMA-DPE) with promise for making gas separation membranes.
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Expanding the poly(2-oxazoline) block copolymer possibilities through nitroxide mediated polymerisation

Polym. Chem., 2024, 15,4416-4424
DOI: 10.1039/D4PY00887A, Paper
Open Access
James Lefley, C. Remzi Becer
In recent years, poly(2-oxazoline)s (POx) have become a sought-after biomaterial to replace PEG. Endcapping POx with BlocBuilder MA enables copolymerization with a variety of vinylic monomers, producing unique POx-vinyl block copolymer combinations.
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Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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Mesomorphic and photochromic luminescent behaviour of side-chain liquid crystalline polymers containing di-substituted cyanostilbene groups with the different number of alkyl tail chain

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00889H, Paper
Juan Luo, Juan Wang, Junde Zhang, Huizi Cao, Xiaofang Chen
In this work, side-chain luminescent liquid crystalline polymers (SCLLCPs) that contain di-substituted cyanostilbene (CS) groups with the different substituted number of terminal alkyl chain, which are PNB-Z-4, PNB-Z-34, and PNB-Z-345,...
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Catalytic copolymerization of carbon dioxide and cyclohexene oxide by a trinuclear cyclohexane-bridged tetradentate Schiff base chromium complex

Polym. Chem., 2024, 15,4519-4528
DOI: 10.1039/D4PY00956H, Paper
Jie Huang, Boxiong Shen
The development of catalytic systems is a central area of research in carbon dioxide (CO2) and epoxy copolymerization.
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Increasingly threaded polypseudorotaxanes with reduced enthalpies of melting

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01006J, Communication
He Sun, Sean R. Gitter, Kiana A. Treaster, Joshua D. Marquez, Brent S. Sumerlin, Kenneth B. Wagener, Austin M. Evans
We used acyclic diene metathesis (ADMET) chemistry to prepare variably threaded pseudopolyrotaxanes. We find that the melting enthalpy decreases as the number density of macrocycles is increased.
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Synthesis of degradable polyester with high molecular weight and excellent mechanical properties through copolymerization modification of poly(butylene succinate)

Polym. Chem., 2024, 15,4570-4579
DOI: 10.1039/D4PY01050G, Paper
Hongji Wang, Xiaojun Ma, Hanyu Yao, Haohao Chang, Yin Lv, Zhong Wei
The degradable copolymer of polybutylene succinate (PBS) modified with tricyclodecane dimethanol (TCD) presented significantly enhanced tensile strength and elongation at break.
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Development of substrate-independent heparin coating to mitigate surface-induced thrombogenesis: efficacy and mechanism

J. Mater. Chem. B, 2024, 12,10994-11011
DOI: 10.1039/D4TB01779J, Paper
Shengjun Cheng, Haifeng Ji, Tao Xu, Xianda Liu, Lin Xu, Weifeng Zhao, Changsheng Zhao
A facile and substrate independent heparin-based coating was developed in this study. And the associated anticoagulant mechanism of this coating was clarified.
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Combined and rapid detection of anti-Brucella IgG/IgM in clinical samples based on surface-enhanced Raman scattering-lateral flow immunochromatography

J. Mater. Chem. B, 2024, 12,11012-11024
DOI: 10.1039/D4TB01367K, Paper
Yongwei Zhang, Ziyue Li, Aolin Zhu, Qian Zhang, Hao Zhou, Xuelei Zhou, Tingwei Liu, Chunyan Liu, Hefei Zha, Xin Zhang, Hui Zhao, Jiutong Li, Guodong Lü, Xinxia Li
Brucellosis is a bacterial infectious disease caused mainly by Brucella. Transmission is mainly by contact with infected domestic or wild animals or their excreta.
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Reconfiguring the endogenous electric field of a wound through a conductive hydrogel for effective exudate management to enhance skin wound healing

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01349B, Communication
Yukun Yan, Yuanyuan Chen, Hanqing Dai, Wanlu Zhang, Ruiqian Guo
In this work, we proposed a mechanism for hydrogel-based dressings to respond to endogenous electric fields through exudate absorption and conducted a verification study using polyacrylamide and sodium alginate (PAM–SA) hydrogels.
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Multimodal layer-by-layer nanoparticles: a breakthrough in gene and drug delivery for osteosarcoma

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01541J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Eugenia Crisafulli, Annachiara Scalzone, Chiara Tonda-Turo, Joel Girón-Hernández, Piergiorgio Gentile
This study explored biodegradable nanoparticles for treating osteosarcoma. Co-delivery of miRNA-34a, doxorubicin, and resveratrol by LbL nanocoating enhanced apoptosis and cell disruption with promise to improve efficacy and reduce drug resistance.
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A dual-functional photosensitizer for mitochondria-targeting photodynamic therapy and synchronous polarity monitoring

J. Mater. Chem. B, 2024, 12,11259-11264
DOI: 10.1039/D4TB01872A, Paper
Liu Yang, Shenglong Gan, Jie Zhang, Yin Jiang, Qingxin Chen, Hongyan Sun
A dual-functional photosensitizer was developed, exhibiting potent phototoxicity and sensitivity to polarity changes.
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Drug-delivery and biological activity in colorectal cancer of a supramolecular porous material assembled from heptameric chromium-copper-adenine entities

J. Mater. Chem. B, 2024, 12,11156-11164
DOI: 10.1039/D4TB01521E, Paper
Sandra Mena-Gutiérrez, Ekain Maiza-Razkin, Jon Pascual-Colino, Marcos J. Araúzo-Bravo, Garikoitz Beobide, Oscar Castillo, Ainara Castellanos-Rubio, Daniela Gerovska, Antonio Luque, Sonia Pérez-Yáñez
Supramolecular metal-organic porous materials as drug delivery systems, modulation of the release kinetics using cholesterol as pore blocking agent and its impact on colorectal cancer cell cultures: cytotoxicity and RNA-seq transcriptomics studies.
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Nordihydroguaiaretic acid microparticles are effective in the treatment of osteoarthritis

J. Mater. Chem. B, 2024, 12,11172-11186
DOI: 10.1039/D4TB01342E, Paper
Kaamini M. Dhanabalan, Bhagyashree Padhan, Ameya A. Dravid, Smriti Agarwal, Nicholas M. Pancheri, Angela Lin, Nick J. Willet, Ashok Kumar Padmanabhan, Rachit Agarwal
Sustained delivery of NDGA via polymeric microparticles maintains therapeutic levels in joints, reduces cartilage damage, and alleviates post-traumatic osteoarthritis (PTOA) in mice through ROS modulation and autophagy induction.
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Breakthrough in cancer therapy: lutetium texaphyrin–celecoxib conjugate for immune and photodynamic treatment

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB02019G, Highlight
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qihang Ding, Yue Wang, Pengfei Zhang, Ling Mei
Kim et al. present a small-molecule photosensitizer, LuCXB, which combines a COX-2 inhibitor (celecoxib) with a near-infrared lutetium texaphyrin photocatalyst and was loaded CD133-aptamer functionalized exosome for cancer stem cells targeting.
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Nanobiopolymers in cancer therapeutics: advancing targeted drug delivery through sustainable and controlled release mechanisms

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB00599F, Review Article
Shikha Gulati, Nabeela Ansari, Yamini Moriya, Kumud Joshi, Disha Prasad, Gargi Sajwan, Shefali Shukla, Sanjay Kumar, Rajender S. Varma
Nanobiopolymers in cancer therapeutics offer sustainable and targeted drug delivery with controlled release, enhancing treatment efficacy while ensuring sustainability and biodegradability for improved patient care.
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Bioinspired programmable coacervate droplets and self-assembled fibers through pH regulation of monomers

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01550A, Paper
Satyajit Patra, Sushmitha Chandrabhas, Subi J. George
Phase separation or phase transitions pervade the biological domain, where proteins and RNA engage in liquid-liquid phase separation (LLPS), forming liquid-like membraneless organelles. The misregulation or dysfunction of these proteins...
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Micah Parsons insists he wasn't throwing "Mike McCarthy under the bus" with postgame comments

Cowboys edge rusher Micah Parsons pushed back against the perception he was taking a shot at coach Mike McCarthy in his postgame comments Sunday.